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91.
Bergenia species (Saxifragaceae) are important sources of herbal medicines in Asia, mainly in Russia. Various plant parts are valued for their antibacterial, anti-inflammatory, antioxidant sand adaptogenic effect, and used for the dissolution of kidney and bladder stones. In this study a rapid reversed phase liquid chromatography (RP-HPLC) method has been developed for rapid screening and identifying of the main active components in leaf samples of Bergenia accessions. The main goal of this study was to develop an efficient method for the simultaneous identification and detection of arbutin, bergenin and gallic acid from Bergenia leaf samples, which were extracted with a methanolic solvent mixture [methanol:water = 1:1 (v/v)]. Chromatographic separations were performed on a reversed phase Luna C18(2)-HST HPLC column. This chromatographic system provided increased speed and efficiency for separations, without the need for ultra-high pressures. Reversed phase HPLC coupled with diode array detector method was used for the analysis. The method was validated using ICH guidelines. The level of gallic acid was significantly higher in Bergenia crassifolia samples compared to Bergenia cordifolia. However, the samples of the two Bergenia species did not differ substantially regarding the concentrations of arbutin and bergenin. The novel method proved to be fast and allowed sufficient separation and quantification of arbutin, bergenin and gallic acid, the most important bioactive compounds of Bergenia leaves; thus facilitating rapid screening and quality assessment of Bergenia samples of various botanical and geographical origins.  相似文献   
92.
Recently, the 6-(substituted amino)-3-pyridazinyl-hydrazines2–4 and their hydrazones1 became important as peripheral antihypertensive agents. These compounds have been synthesized from 3,6-dichloropyridazine (1) by introducing to the molecule firstly the substituted amine and then the hydrazine moiety2–4. This process has some disadvantages. It is known that one chlorine atom of 1 can be easily replaced by nucleophilic substitution. The subsequent replacement of the other chlorine atom in 1 is, however, rather difficult5. For example, 2 silosequent substitution with hydrazine should be uarried out with agreat excess of hydrazine at elevated temperatures and the product formed is liable to decompose in this basic medium. As a consequence, overail yield of this process is low ana in general, the final product nas to be purifiea tnroilgh its benzylidene derivative. Tnerefore, according to our experiments, this process does not seem to be useful for large-scale operations.  相似文献   
93.
We characterize permanence of planar S-systems. Further, we construct a planar S-system with three limit cycles.  相似文献   
94.
The construction of a specific multiadditive function leads to a structure theorem on the set of vectors with algebraically dependent components. A counterexample in the theory of quadratic functions is also obtained.  相似文献   
95.
We present a rational version of the classical Landen transformation for elliptic integrals. This is employed to obtain explicit closed-form expressions for a large class of integrals of even rational functions and to develop an algorithm for numerical integration of these functions.

  相似文献   

96.
The residual-free bubble method (RFB) is a parameter-free stable finite element method that has been successfully applied to a wide range of boundary-value problems exhibiting multiple-scale behaviour. If some local features of the solution are known a priori, the approximation properties of the RFB finite element space can be improved by enriching it on selected edges of the partition by edge-bubbles that are supported on pairs of neighbouring elements. Motivated by this idea, we define and analyse an enhanced residual-free bubble method for the solution of convection-dominated convection-diffusion problems in 2-D. Our a priori analysis highlights the limitations of the RFB method and the improved global approximation properties of the new method. The theoretical results are supported by detailed numerical experiments.  相似文献   
97.
The IR, 1H and 13C NMR spectra of six esters of 1-aryl-4-methyl-3- and 5-pyrazolecarboxylic acids are reported. On the basis of their spectra the 3- or 5-position of the substituent in such structural isomeric pairs can be established without recourse to the spectrum of the other member of the pair. The spectral data also give information on the conformation, which depends on the relative position and size of the hetero ring substituents.  相似文献   
98.
We discuss results obtained jointly with Van Vu on the length of arithmetic progressions in \(\ell \)-fold sumsets of the form
$$\begin{aligned} \ell \mathcal {A}=\{a_1+\dots +a_\ell ~|~a_i\in \mathcal {A}\} \end{aligned}$$
and
$$\begin{aligned} \ell \mathcal {A}=\{a_1+\dots +a_\ell ~|~a_i\in \mathcal {A}\text { all distinct}\}, \end{aligned}$$
where \(\mathcal {A}\) is a set of integers. Applications are also discussed.
  相似文献   
99.
Aqua ligands can undergo rapid internal rotation about the M−O bond. For magnetic resonance contrast agents, this rotation results in diminished relaxivity. Herein, we show that an intramolecular hydrogen bond to the aqua ligand can reduce this internal rotation and increase relaxivity. Molecular modeling was used to design a series of four Gd complexes capable of forming an intramolecular H-bond to the coordinated water ligand, and these complexes had anomalously high relaxivities compared to similar complexes lacking a H-bond acceptor. Molecular dynamics simulations supported the formation of a stable intramolecular H-bond, while alternative hypotheses that could explain the higher relaxivity were systematically ruled out. Intramolecular H-bonding represents a useful strategy to limit internal water rotational motion and increase relaxivity of Gd complexes.  相似文献   
100.
Learning from examples is a frequently arising challenge, with a large number of algorithms proposed in the classification, data mining and machine learning literature. The evaluation of the quality of such algorithms is frequently carried out ex post, on an experimental basis: their performance is measured either by cross validation on benchmark data sets, or by clinical trials. Few of these approaches evaluate the learning process ex ante, on its own merits. In this paper, we discuss a property of rule-based classifiers which we call “justifiability”, and which focuses on the type of information extracted from the given training set in order to classify new observations. We investigate some interesting mathematical properties of justifiable classifiers. In particular, we establish the existence of justifiable classifiers, and we show that several well-known learning approaches, such as decision trees or nearest neighbor based methods, automatically provide justifiable classifiers. We also identify maximal subsets of observations which must be classified in the same way by every justifiable classifiers. Finally, we illustrate by a numerical example that using classifiers based on “most justifiable” rules does not seem to lead to overfitting, even though it involves an element of optimization.  相似文献   
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