Coincidence Doppler shift lifetime measurements in 73,74Se and 74Br using the EUROBALL Cluster cube array

Subpicosecond lifetimes of high spin states in the rotational nuclei ⁷³Se, ⁷⁴Se and ⁷⁴Br have been measured using the ⁵⁸Ni +¹⁹F compound reaction and the Doppler Shift Attenuation method. Six EUROBALL Cluster detectors arranged in cube geometry allowed us to select the relevant transitions in γγ coincidence mode. The high counting statistics achieved in this setup also facilitated the determination of average sidefeeding times, which were found to agree rather well with the results of Monte-Carlo calculations of the particle and γ-ray evaporation process. The deduced quadrupole strengths and deformations are compared with the results of previous measurements and the predictions of Cranked Shell Model calculations. In ⁷⁴Br, a large and constant prolate deformation of β₂= 0.37(1) was found for the presumed 4⁺ and 3⁻ two-quasiparticle bands. Received: 2 July 1999     

Monte Carlo hyper-heuristics for examination timetabling

Automating the neighbourhood selection process in an iterative approach that uses multiple heuristics is not a trivial task. Hyper-heuristics are search methodologies that not only aim to provide a general framework for solving problem instances at different difficulty levels in a given domain, but a key goal is also to extend the level of generality so that different problems from different domains can also be solved. Indeed, a major challenge is to explore how the heuristic design process might be automated. Almost all existing iterative selection hyper-heuristics performing single point search contain two successive stages; heuristic selection and move acceptance. Different operators can be used in either of the stages. Recent studies explore ways of introducing learning mechanisms into the search process for improving the performance of hyper-heuristics. In this study, a broad empirical analysis is performed comparing Monte Carlo based hyper-heuristics for solving capacitated examination timetabling problems. One of these hyper-heuristics is an approach that overlaps two stages and presents them in a single algorithmic body. A learning heuristic selection method (L) operates in harmony with a simulated annealing move acceptance method using reheating (SA) based on some shared variables. Yet, the heuristic selection and move acceptance methods can be separated as the proposed approach respects the common selection hyper-heuristic framework. The experimental results show that simulated annealing with reheating as a hyper-heuristic move acceptance method has significant potential. On the other hand, the learning hyper-heuristic using simulated annealing with reheating move acceptance (L?CSA) performs poorly due to certain weaknesses, such as the choice of rewarding mechanism and the evaluation of utility values for heuristic selection as compared to some other hyper-heuristics in examination timetabling. Trials with other heuristic selection methods confirm that the best alternative for the simulated annealing with reheating move acceptance for examination timetabling is a previously proposed strategy known as the choice function.     

The practice and theory of automated timetabling (2016)

Annals of Operations Research -     

Hyper-heuristics: a survey of the state of the art

Hyper-heuristics comprise a set of approaches that are motivated (at least in part) by the goal of automating the design of heuristic methods to solve hard computational search problems. An underlying strategic research challenge is to develop more generally applicable search methodologies. The term hyper-heuristic is relatively new; it was first used in 2000 to describe heuristics to choose heuristics in the context of combinatorial optimisation. However, the idea of automating the design of heuristics is not new; it can be traced back to the 1960s. The definition of hyper-heuristics has been recently extended to refer to a search method or learning mechanism for selecting or generating heuristics to solve computational search problems. Two main hyper-heuristic categories can be considered: heuristic selection and heuristic generation. The distinguishing feature of hyper-heuristics is that they operate on a search space of heuristics (or heuristic components) rather than directly on the search space of solutions to the underlying problem that is being addressed. This paper presents a critical discussion of the scientific literature on hyper-heuristics including their origin and intellectual roots, a detailed account of the main types of approaches, and an overview of some related areas. Current research trends and directions for future research are also discussed.     

Construction of the collision integral kernel for the nonlinear Boltzmann equation from its matrix elements

The methods for constructing the kernels of collision integrals emerging in the expansion of the non-linear Boltzmann kinetic equation in spherical harmonics are investigated. The techniques developed for calculating the kernel from the known matrix elements of the collision integral using the averaging over a number of computational parameters make it possible to substantially improve the accuracy of the proposed algorithm. In kernel calculations, Maxwell molecules were simulated using the asymptotic technique. This makes it possible to approximate the analytic expression of the kernel known in this case to a high degree of accuracy.     

Matrix elements and kernels of the collision integral in the Boltzmann equation

This article elaborates upon our previous work in which some general properties of the matrix elements and kernels of the gain and loss terms of the collision integral were found. The object of study is the loss term of the collision integral, since related analytical expressions are simple. Formulas to calculate the matrix elements are derived. The kernels of power-law interaction potentials are completely investigated and constructed using analytical and numerical approaches.     

Voltammetric and spectroscopic analysis of interactions of pyridine mono-carboxylic acid isomers with cysteine at physiological pH

The interactions of pyridine mono-carboxylic acid isomers (PCAIs) (nicotinic acid (NA), isonicotinic acid (INA) and picolinic acid (PA)) with cysteine (RSH) at physiological pH (7.40) have been investigated by square-wave and cyclic voltammetry (SWV and CV), and UV-Vis and infrared spectroscopy. By the addition of isomeric pyridine mono-carboxylic acids, the reduction peak current of mercurous cysteine thiolate could be decreased and also its peak potential E _p was shifted to more positive values. Also, the significant changes in formal potential E ⁰′, electron transfer coefficient α and electrode reaction standard rate constant k _s of mercurous cysteine thiolate (Hg₂(SR)₂) in the presence and absence of PCAIs were observed. The results of voltammetric measurements indicated that binding reactions were occurred between PCAIs and RSH and new electroactive molecular complexes were formed, which resulted in the decrease of free cysteine concentration and the decrease of the reduction peak current of mercurous cysteine thiolate. The logarithmic values of binding constants of NA, INA and PA were calculated as 13.4, 17.7 and 18.9, respectively. The binding ratios for NA-RSH, INA-RSH and PA-RSH complexes were determined as 1: 3, 1: 4 and 1: 4, respectively. Both UV-Vis and FTIR studies also confirmed these interaction reactions.     

A brief survey on the copper‐catalyzed allylation of alkylzinc and Grignard reagents under Barbier conditions

The same regioselectivity can be obtained in the CuI catalyzed allylic coupling of n‐butylzinc reagents prepared by either pre‐transmetallation or in situ transmetallation of Grignard reagents in the presence of allylic partner and catalyst. n‐Butylzinc bromide and di‐n‐butylzinc undergo γ‐selective allylation whereas tri‐n‐butylzincate gives preferential α‐selectivity. The regioselectivity obtained in the reaction of n‐butyl bromide and E‐crotyl chloride in the presence of Mg and CuCN is parallel to the coupling of preformed n‐butylmagnesium bromide. It is remarkable that the regiochemical outcome of copper catalyzed alkyl‐allyl coupling can be controlled by using Grignard reagents prepared under Barbier conditions and alkylzincs prepared by in situ transmetallation. Copyright © 2006 John Wiley & Sons, Ltd.