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131.
The stoichiometric reactions of trimethylaluminum with 2,6‐(MeOCH2)2C6H3OH (LH) revealed compounds L3Al ( 1 ) and L2AlMe ( 2 ). On the other hand reaction of 1 equiv. of LH with trimethylaluminum did not lead to the formation of complex LAlMe2 ( 3 ), rather 2 together with Me3Al were observed as a result of a disproportionation of 3 . Compounds 1 and 2 were characterized by elemental analysis, 1H and 13C NMR spectroscopy and in the case of 1 by X‐ray diffraction. Derivative 2 underwent transmetalation with Ph3SnOH, giving LSnPh3 ( 4 ) as the result of a migration of ligand L from the aluminum to the tin atom. The identity of 4 was established by elemental analysis, 1H, 13C and 119Sn NMR spectroscopy and 1H, 119Sn HMBC experiments. The system 2 and B(C6F5)3 in a 1:1 molar ratio was shown to be active in the polymerization of propylene oxide and ε‐caprolactone. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
132.
W. Ludorf X. Z. Wang D. Bäuerle 《Applied Physics A: Materials Science & Processing》1989,49(2):221-223
Superconducting films of Bi-Sr-Ca-Cu-O on (100) MgO substrates have been fabricated by XeCl-excimer-laser sputtering from ceramic targets of Bi2.5Sr2Ca2Cu3Oy in O2 atmosphere. The films were polycrystalline with the c-axis (30.80±0.02Å) preferably oriented normal to the substrate surface. Without post-annealing the films showed metallic resistance behavior with zero resistance temperatures of up to Tc(0) }- 79 K. The critical current density of the films had values of up to jc(50K)}- 104 A/cm2. 相似文献
133.
Daniel Král’ Jan Kratochvíl Andrzej Proskurowski Heinz-Jürgen Voss 《Discrete Applied Mathematics》2006,154(4):660-672
A mixed hypergraph is a triple (V,C,D) where V is its vertex set and C and D are families of subsets of V, called C-edges and D-edges, respectively. For a proper coloring, we require that each C-edge contains two vertices with the same color and each D-edge contains two vertices with different colors. The feasible set of a mixed hypergraph is the set of all k's for which there exists a proper coloring using exactly k colors. A hypergraph is a hypertree if there exists a tree such that the edges of the hypergraph induce connected subgraphs of the tree.We prove that feasible sets of mixed hypertrees are gap-free, i.e., intervals of integers, and we show that this is not true for precolored mixed hypertrees. The problem to decide whether a mixed hypertree can be colored by k colors is NP-complete in general; we investigate complexity of various restrictions of this problem and we characterize their complexity in most of the cases. 相似文献
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H. Hofsäss H. Feldermann R. Merk M. Sebastian C. Ronning 《Applied Physics A: Materials Science & Processing》1998,66(2):153-181
T /nS of nT rearrangements and nS atoms in the spike volume as the crucial parameter characterizing the ability of a given ion–target combination to achieve
complete rearrangement of the spike volume. nT/nS>1 is the optimum condition for diamondlike film growth. For aC films the ion energy dependence of nT/nS agrees well with the measured sp3 bond fraction. For Ar+-ion-assisted deposition of aC we find nT/nS>1 above 50 eV with no pronounced ion energy dependence. Furthermore, our model predicts optimum conditions for the formation
of cubic boron nitride between 50 eV and 3 keV.
Accepted: 14 October 1997 相似文献
137.
We prove that the congruence lattice of a Scott-domain can be characterized as a complete lattice.Presented by V. Trnkova.The research of the first author was supported by the NSERC of Canada.The research of the second author was supported by the Hungarian National Foundation for Scientific Research, under Grant No. 1903. 相似文献
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