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61.
Lezak E Kulinski Z Masirek R Piorkowska E Pracella M Gadzinowska K 《Macromolecular bioscience》2008,8(12):1190-1200
Green composites of PLA with micropowders derived from agricultural by-products such as oat husks, cocoa shells, and apple solids that remain after pressing have been prepared by melt mixing. The thermal and mechanical properties of the composites, including the effect of matrix crystallization and plasticization with poly(propylene glycol), have been studied. All fillers nucleated PLA crystallization and decreased the cold-crystallization temperature. They also affected the mechanical properties of the compositions, increasing the modulus of elasticity but decreasing the elongation at break and tensile impact strength although with few exceptions. Plasticization of the PLA matrix improved the ductility of the composites. 相似文献
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64.
Rieth LR Moore DR Lobkovsky EB Coates GW 《Journal of the American Chemical Society》2002,124(51):15239-15248
Polymerization of beta-butyrolactone (BBL) and beta-valerolactone (BVL) using the zinc alkoxide initiator (BDI-1)ZnO(i)()Pr [(BDI-1) = 2-((2,6-diisopropylphenyl)amido)-4-((2,6-diisopropylphenyl)imino)-2-pentene] proceeds very rapidly under mild conditions to produce poly(3-hydroxybutyrate) (PHB) and poly(3-hydroxyvalerate) (PHV), respectively. For the monomer-to-initiator ratio 200:1, PHB number-average molecular weights (M(n)) are proportional to conversion throughout the reaction and polydispersity indices (PDIs) are narrow, consistent with a living polymerization. Higher monomer-to-initiator ratios can be used to achieve high molecular weight PHB (M(n) > 100 000). End-group analysis verifies that the polymerization of BBL follows a coordination-insertion mechanism, where complexes of the form (BDI-1)ZnOCH(Me)CH(2)CO(2)R are the active species. Variable temperature NMR experiments show that (BDI-1)ZnO(i)()Pr is monomeric in benzene-d(6) solution. In contrast, (BDI-2)ZnO(i)()Pr [(BDI-2) = 2-((2,6-diethylphenyl)amido)-4-((2,6-diethylphenyl)imino)-2-pentene] is a poor initiator at room temperature because it prefers to form a bis-mu-isopropoxide dimer in solution. According to kinetic studies, propagation by (BDI-1)ZnO(i)()Pr is first order in both monomer as well as (BDI-1)ZnO(i)()Pr concentration. These results lead us to propose a monometallic active species. Several results suggest that elimination side reactions are slowly catalyzed by zinc alkoxides, leading to degradation of the polymer. 相似文献
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66.
Emil Žagar 《BIT Numerical Mathematics》2002,42(3):670-688
In this paper the problem of G
2 continuous interpolation of curves in
d
by polynomial splines of degree n is studied. The interpolation of the data points and two tangent directions at the boundary is considered. The case n = r + 2 = d, where r is the number of interior points interpolated by each segment of the spline curve, is studied in detail. It is shown that the problem is uniquely solvable asymptotically, e., when the data points are sampled regularly and sufficiently dense, and lie on a regular, convex parametric curve in
d
. In this case the optimal approximation order is also determined. 相似文献
67.
Petkov V Trikalitis PN Bozin ES Billinge SJ Vogt T Kanatzidis MG 《Journal of the American Chemical Society》2002,124(34):10157-10162
A long-standing issue regarding the local and long-range structure of V(2)O(5)*nH(2)O xerogel has been successfully addressed. The full three-dimensional structure of the lamellar turbostratic V(2)O(5)*nH(2)O xerogel was determined by the atomic pair distribution function technique. We show that on the atomic scale the slabs of the xerogel can be described well as almost perfect pairs (i.e., bilayers) of single V(2)O(5) layers made of square pyramidal VO(5) units. These slabs are separated by water molecules and stack along the z-axis of a monoclinic unit cell (space group C2/m) with parameters a = 11.722(3) A, b = 3.570(3) A, c = 11.520(3) A, and beta = 88.65 degrees. The stacking sequence shows signatures of turbostratic disorder and a structural coherence limited to 50 A. 相似文献
68.
The Bergman kernel function: Explicit formulas and zeroes 总被引:10,自引:0,他引:10
Harold P. Boas Siqi Fu Emil J. Straube 《Proceedings of the American Mathematical Society》1999,127(3):805-811
We show how to compute the Bergman kernel functions of some special domains in a simple way. As an application of the explicit formulas, we show that the Bergman kernel functions of some convex domains, for instance the domain in defined by the inequality , have zeroes.
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70.
It is known that under certain circumstances the point of maximum intensity in a focused aberration-free wave is not at the geometrical focus, but is closer to the focusing lens. In the present note such a focal shift is analyzed for the case of a gaussian beam, focused by a thin lens, which fills a circular aperture of any prescribed radius, the waist of the beam being assumed to be located in the aperture plane. Many previously known results follow as limiting cases of our analysis. 相似文献