全文获取类型
收费全文 | 149869篇 |
免费 | 1760篇 |
国内免费 | 1090篇 |
专业分类
化学 | 57929篇 |
晶体学 | 1986篇 |
力学 | 10779篇 |
综合类 | 45篇 |
数学 | 37744篇 |
物理学 | 44236篇 |
出版年
2022年 | 758篇 |
2021年 | 675篇 |
2020年 | 635篇 |
2019年 | 638篇 |
2018年 | 11140篇 |
2017年 | 10863篇 |
2016年 | 7216篇 |
2015年 | 1752篇 |
2014年 | 1674篇 |
2013年 | 3517篇 |
2012年 | 6924篇 |
2011年 | 14375篇 |
2010年 | 8373篇 |
2009年 | 8776篇 |
2008年 | 10031篇 |
2007年 | 11983篇 |
2006年 | 3468篇 |
2005年 | 4087篇 |
2004年 | 4027篇 |
2003年 | 4131篇 |
2002年 | 3055篇 |
2001年 | 3963篇 |
2000年 | 2893篇 |
1999年 | 2103篇 |
1998年 | 1552篇 |
1997年 | 1502篇 |
1996年 | 1339篇 |
1995年 | 1136篇 |
1994年 | 1001篇 |
1993年 | 876篇 |
1992年 | 1171篇 |
1991年 | 1156篇 |
1990年 | 1028篇 |
1989年 | 910篇 |
1988年 | 881篇 |
1987年 | 930篇 |
1986年 | 786篇 |
1985年 | 1015篇 |
1984年 | 928篇 |
1983年 | 645篇 |
1982年 | 635篇 |
1981年 | 609篇 |
1980年 | 562篇 |
1979年 | 691篇 |
1978年 | 704篇 |
1977年 | 696篇 |
1976年 | 616篇 |
1975年 | 523篇 |
1974年 | 558篇 |
1973年 | 498篇 |
排序方式: 共有10000条查询结果,搜索用时 26 毫秒
41.
C Z Shi Z Y Zhang L Z Zhuang 《Science in China. Series B, Chemistry, life sciences & earth sciences》1991,34(9):1098-1104
The effect of hormones on progesterone secretion by 6-8 week human trophoblast tissue cultured in serum-free medium has been investigated. GnRH at low concentration (10(-10)-10(-8) mol/L) stimulated progesterone secretion, while high dose (10(-6)-10(-5) mol/L) produced inhibitory effect. The progesterone secretion could be significantly decreased by addition of anti-hCG antiserum or monoclonal anti-hCG IgG in a dose- and time-dependent manner. Various concentrations of TRH, PGE2, PGF2 alpha, testosterone and estradiol were found to be ineffective. These data indicate clearly that progesterone production by human trophoblast tissue at early gestation stage is under the modulation of GnRH and hCG. 相似文献
42.
The blends composed of polyamide 6 (PA6) and polyamide 66 (PA66) were obtained using two different preparation methods, one of which was the melt‐mixing through a twin‐screw extruder and the subsequent injection molding; and the other, the in situ blending through anionic polymerization of ε‐caprolactam in the presence of PA66. For the former, there existed a remarkable improvement in toughness but a drastic drop in strength and modulus; however, for the latter, a reverse but less significant trend of mechanical properties change appeared. Various characterizations were conducted, including the analyses of crystalline morphology, crystallographic form, and crystallization and melting behaviors using polarized optical microscopy (POM), wide‐angle X‐ray diffraction (WAXD), and differential scanning calorimetry (DSC), respectively; observation of morphology of fractured surface with scanning electron microscope (SEM); measurement of glass transition through dynamic mechanical analysis (DMA); and the intermolecular interaction as well as the interchange reaction between the two components by Fourier transform infrared spectrometry (FT‐IR) and 13C solution NMR. The presence and absence of interchange reaction was verified for the in situ and melt‐mixed blends, respectively. It is believed that the transreaction resulted in a drop in glass transition temperature (Tg) for the in situ blends, contrary to an increase of Tg with increasing PA66 content for the melt‐mixed ones. And the two kinds of fabrication methods led to significant differences in the crystallographic form, spherulite size and crystalline content and perfection as well. Accordingly, it is attempted to explain the reasons for the opposite trends of changes in the mechanical properties for these two blends. © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 1176–1186, 2007 相似文献
43.
Choyal Y. Minami K. Granatstein V.L. 《IEEE transactions on plasma science. IEEE Nuclear and Plasma Sciences Society》2004,32(6):2157-2168
The linear dispersion relation of a backward-wave oscillator (BWO), derived earlier by the authors, is modified to include effects of RF surface current at the beam-vacuum interface. This modified dispersion relation results in an unstable interaction between the slow cyclotron mode (SCM) and the structure mode in addition to the conventional Cherenkov instability caused by the slow space charge mode. Numerical analysis is then carried out using parameters of a BWO experiment at University of Maryland. Fine structure of the SCM instability is elucidated. The analysis indicates that BWO radiation would not be suppressed near cyclotron absorption in an infinitely long system. 相似文献
44.
45.
The stagnation slip flow on an axially moving cylinder is studied.The NavierStokes and energy equations reduce to nonlinearordinary differential equations under a similarity transform.For large slip, the flow field decays exponentially into potentialflow. The heat transfer can be expressed as an incomplete gammafunction. In general, the heat transfer increases with slip,Prandtl number and Reynolds number. 相似文献
46.
Kobayashi H. Satou Y. Okuno Y. 《IEEE transactions on plasma science. IEEE Nuclear and Plasma Sciences Society》2002,30(6):2152-2159
In an magnetohydrodynamic (MHD) generator using a frozen inert gas plasma (FIP), the availability of a frozen argon plasma, the influence of plasma uniformity at the generator inlet on the performance, and the feasibility of a large-scale generator are numerically examined by /spl gamma/-/spl theta/ two-dimensional simulation. The FIP is produced by pre-ionizing inert gas without an alkali metal seed at the generator inlet, then the ionization degree of the plasma is kept almost constant in the whole of the channel because of considerable slow recombination of the inert gas just like frozen reaction plasma. It is found that not only helium, but also argon frozen plasma MHD generation is realized, although highly accurate control of inlet ionization degree is necessary for argon. It is important to reduce the nonuniformity of plasma properties at the generator inlet in order to raise the maximum enthalpy extraction ratio. Even for the large-scale generator with 1000-MW thermal input, the ionization degree is kept almost constant in the whole of the channel and the high performance is obtainable. This result is extremely attractive for the FIP MHD generator. 相似文献
47.
I.L. Lyubchanskii N.N. Dadoenkova M.I. Lyubchanskii E.A. Shapovalov A.E. Zabolotin K.Y. Guslienko T. Rasing 《Applied physics. B, Lasers and optics》2002,74(7-8):711-714
Nonlinear (at the second-harmonic frequency of the incident light) optical reflection by two-dimensional magnetic superstructures
is theoretically studied. A square lattice of magnetic dots and a hexagonal lattice of magnetic bubbles (cylindrical magnetic
domains) are considered. Because the periods of these structures are comparable with the wavelengths of the fundamental and
the second-harmonic radiation, it would be possible to observe diffraction at the second-harmonic frequency. A polarization
analysis of nonlinearly diffracted radiation is performed and the numbers of observable diffraction orders for the above structures
are estimated.
Received: 10 January 2002 / Published online: 11 June 2002 相似文献
48.
L. Pillier C. Moreau X. Mercier J.F. Pauwels P. Desgroux 《Applied physics. B, Lasers and optics》2002,74(4-5):427-434
Cavity ring-down spectroscopy (CRDS) is used to measure the NO mole fraction formed in the burnt gases of low-pressure premixed
flames. It is shown that the line-of-sight absorption is greatly increased by the contribution of the NO molecules surrounding
the burner. This contribution has been quantified by developing a mathematical procedure taking into account the spatial and
spectral features of the CRDS measurement. Calculations have been undertaken in the general case of a stable species not consumed
in the flame. The most sensitive parameter is the temperature both in the flame and outside the flame. Simulations allow the
selection of the best spectroscopic transitions for a given flame (i.e. a given temperature profile), ensuring the weakest
influence of the inaccuracy affecting the temperature determination. High quantum states belonging to the A–X (0–1) band of
NO have been found to be the most valuable and have led to a NO mole fraction determination with an accuracy of ±13%. NO absorption
in the flame was completely masked using the A–X (0–0) band. Finally, the prompt-NO mole fraction formed in a methane/air
flame stabilized at 33 Torr is obtained by combining CRDS and laser induced fluorescence techniques.
Received: 12 October / Revised version: 1 February 2002 / Published online: 14 March 2002 相似文献
49.
A. Jarid M. Aaid Y. Legoux J. Merini M. Loudet D. Gonbeau G. Pfister-Guillouzo 《Chemical physics》1991,150(3):353-360
The electronic and structural characteristics of CrF5, CrF4, RuF5 and RuF4 were studied. Ab initio (SCF-CI) calculations were performed with different structures and spin states for each complex. The favored conformation always corresponds to the highest multiplicity: doublet for CrF5 in D3h, triplet for CrF4 in Td, quadruplet for RuF5 in C4v and quintuplet for RuF4 in D4h symmetry. 相似文献
50.
S. G. Charati A. Y. Houde S. S. Kulkarni M. G. Kulkarni 《Journal of Polymer Science.Polymer Physics》1991,29(8):921-931
Polymer packing density can be conveniently measured by either density-based measurements (direct or estimated free volume) or wide-angle X-ray diffraction (WAXD) spectra. Previously reported diffusivity and permeability values for various polyarylates and polyimides are examined on the basis of the packing density measured by these different techniques. It is shown that in these rigid glassy polymers, the mean intersegmental distance, the d-spacing, obtained from WAXD provides a better measure of the effect of polymer packing on diffusivity than either direct density measurements or estimated free volumes. It has been possible to correlate previously reported diffusivity and sorption data for various polyarylates and polycarbonate on the basis of the WAXD investigation, using the d-spacing and the amorphous peak width, respectively. The effect of polyarylate structure on d-spacing has been studied. A series of polyarylates have been synthesized with different substituents on the bridge carbon. In this series the d-spacing remains constant while the carbonyl group density and the glass transition temperatures are varied. However, small substituents on the aromatic ring cause significant changes in the d-spacing. These results can be used to tailor polyarylates with desired intersegmental distances and chain flexibility. 相似文献