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91.
[reaction: see text] The properties of the self-assembling aziadamantane inclusion complex with two alpha-cyclodextrin molecules have been exploited to perform a chemospecific monofunctionalization of alpha-cyclodextrin. The insertion of the photochemically generated carbenes takes place chemospecifically into the cyclodextrin's C-3-OH and C-2-OH bonds in 39 and 18% yield, respectively. This model reaction surpasses conventional methods in terms of yield as well as selectivity. 相似文献
92.
Vaporization of Silver in a Stream of Oxygen Using a transport equipment the vaporization of silver at 611–721°C in a stream of oxygen has been measured. Experiments with detachable cuffs of silver or with wools of silver in a bulb made from quartzglass or silver lead to the same results. By variation of the O2-pressure and the activity of silver is observed that the vaporization happens as Ag2O,g, see “Inhaltsübersicht”. The solid was at first pure silver. During long lasting experiments, however, it is covered with a thin layer of oxygen or silver oxide, which lowers the concentration of Ag2O,g in the equilibrium gas to a smaller, yet constant value. The following measurements using N2 as carrier gas lead to the decomposition of this layer and ends with the very small vapor pressure of silver. The layer of oxygen or silver oxide on the metal could be shown after Davies [2] using mercury. 相似文献
93.
Preparation and Crystal Structure of LnAl3Br12 (Ln = La, Ce, Pr, Nd, Sm, Gd) and Thermal Decomposition to LnBr3 LnAl3Br12 (Ln = La, Ce, Pr, Nd, Sm, Gd) was prepared in crystalline form for the first time. The crystal structures of LaAl3Br12, PrAl3Br12, and NdAl3Br12 were determined on single crystals by X-ray methods. The isotypic compounds crystallize with trigonal symmetry, space group P 3112, Z = 3. A structural comparison to lanthanoide chloroaluminates of equal composition is given and thermal decomposition of LnAl3Br12 (Ln = Nd) to the corresponding lanthanoide tribromide is described. 相似文献
94.
A practicable and selective liquid chromatography-mass spectrometry assay for the determination of two cyclooxygenase-2 inhibitors, etoricoxib and valdecoxib, in human plasma is presented. The analytical technique is based on reversed-phase high-performance liquid chromatography (HPLC) coupled to atmospheric pressure chemical ionisation (APCI) mass spectrometry (Finnigan Mat LCQ ion trap). Mass analysis was performed in the positive ion mode. The ion trap was operated in the tandem MS mode (MS2) and the transitions of etoricoxib (m/z 359.2 --> 280.3) and valdecoxib (m/z 315.1 --> 235.1) were followed by selected reaction monitoring. Retention times of etoricoxib and valdecoxib were 1.05 and 1.08 min, respectively. The method was validated over a linear range 10-2500 and 5-1000 microg/L using the other substrate as internal standard. After validation, the method was used to study the pharmacokinetic pro fi le of etoricoxib or valdecoxib in a healthy volunteer after administration of a single oral dose (valdecoxib, 20 mg; etoricoxib, 90 mg). The presented method was suf fi cient to cover more than 90% of the area under the plasma concentration time curve. 相似文献
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The crystal structure of Zr3N4 is shown to crystallize in the centrosymmetric space group Pnam rather than in the noncentrosymmetric space group Pna21. 相似文献