全文获取类型
收费全文 | 1182篇 |
免费 | 40篇 |
国内免费 | 2篇 |
专业分类
化学 | 784篇 |
晶体学 | 6篇 |
力学 | 21篇 |
数学 | 98篇 |
物理学 | 315篇 |
出版年
2022年 | 7篇 |
2021年 | 17篇 |
2020年 | 10篇 |
2019年 | 17篇 |
2018年 | 10篇 |
2017年 | 11篇 |
2016年 | 30篇 |
2015年 | 25篇 |
2014年 | 31篇 |
2013年 | 72篇 |
2012年 | 54篇 |
2011年 | 82篇 |
2010年 | 50篇 |
2009年 | 38篇 |
2008年 | 73篇 |
2007年 | 63篇 |
2006年 | 75篇 |
2005年 | 67篇 |
2004年 | 42篇 |
2003年 | 38篇 |
2002年 | 36篇 |
2001年 | 15篇 |
2000年 | 23篇 |
1999年 | 17篇 |
1998年 | 13篇 |
1997年 | 13篇 |
1996年 | 16篇 |
1995年 | 11篇 |
1994年 | 14篇 |
1993年 | 15篇 |
1992年 | 20篇 |
1991年 | 12篇 |
1990年 | 20篇 |
1989年 | 16篇 |
1988年 | 15篇 |
1987年 | 16篇 |
1986年 | 13篇 |
1985年 | 13篇 |
1984年 | 10篇 |
1983年 | 4篇 |
1982年 | 12篇 |
1981年 | 8篇 |
1979年 | 5篇 |
1978年 | 6篇 |
1977年 | 12篇 |
1976年 | 4篇 |
1975年 | 5篇 |
1974年 | 5篇 |
1973年 | 7篇 |
1932年 | 3篇 |
排序方式: 共有1224条查询结果,搜索用时 0 毫秒
41.
E. Pinilla Gil L. Calvo Blazquez R. M. Garcia-Monco Carra A. Sanchez Misiego 《Fresenius' Journal of Analytical Chemistry》1989,335(8):1002-1004
Summary A differential pulse polarographic method for the determination of oxytetracycline in urine and human serum in acid media (HClO4 of pH 2) is proposed. The effects of the amount of sample taken and the concentration of HClO4 present were investigated. The detection limit was 5.5×10–6 mol/l. The standard deviation of the determination of 5.5×10–5 mol/l of oxytetracycline in 2 ml of urine was 1.7×10–6 mol/l and that of the determination of 5.5×10–5 mol/l of oxytetracycline in 2 ml of human serum was 1.9×10–6 mol/l.
Bestimmung von Oxytetracyclin in Urin und Humanserum durch Differential-Pulspolarography相似文献
42.
Mohamed M. El-Kerdawy Ali A. El-Emam Hussein I. El-Subbagh Elie Abushanab 《Monatshefte für Chemie / Chemical Monthly》1990,121(1):45-50
Summary A new series of thiophenic isosters of thioxanthones, namely: 2-substituted-4H-thieno[2,3-b][1]benzothiopyran-4-ones and 5-substituted-2-nitro-8-methyl-4H-thieno[2,3-b][1]benzothiopyran-4-ones were synthesized as potential schistosomicidal agents. The synthesized compounds were characterized by their1H-NMR data.
Synthese von substituierten 4H-Thieno[2,3-b][1]benzothiopyran-4-onen als mögliche schistosomicide Wirkstoffe
Zusammenfassung Es wurde eine neue Serie von thiophenischen Isosteren des Thioxanthons, nämlich 2-substituierte 4H-Thieno[2,3-b][1]benzothiopyran-4-one und 5-substituierte 2-Nitro-8-methyl-4H-thieno[2,3-b][1]benzothiopyran-4-one als potentielle schistosomicide Wirkstoffe synthetisiert. Die synthetisierten Verbindungen wurden mittels ihrer1H-NMR Daten charakterisiert.相似文献
43.
Braulio Insuasty M
Nica Ramos Jairo Quiroga Adolfo Sanchez Manuel Nogueras Norbert Hanold Herbert Meier 《Journal of heterocyclic chemistry》1994,31(1):61-64
The reaction of 4,5-diamino-1,6-dihydropyrimidin-6-ones 1 with one equivalent of the chalcones 2 leads in an acidic medium to the formation of the 2,4-diaryl-2,3,6,7-tetrahydro-1H-pyrimido[4,5-b][1,4]diazepin-6-ones 3a-m . The structure elucidation of the products is based on detailed nmr investigations including selective 13C[1H] decoupling experiments. 相似文献
44.
1-Ethyl-6-fluoro-1,4-dihydro-7-methyl-4-oxo-1,8-naphthyridine-3-carboxylic acid ( 8 ) has been prepared in large quantities by a highly efficient process. It has in turn been degraded to give 7-chloro-1-ethyl-6-fluoro-1,4-dihydro-4-oxo-1,8-naphthyridine-3-carboxylic acid ( 11 ). This intermediate has been reacted with piperazine to give the known antibacterial agent, enoxacin ( 12 ). 相似文献
45.
Bonhommeau S Bréfuel N Pálfi VK Molnár G Zwick A Salmon L Tuchagues JP Sanchez Costa J Létard JF Paulsen H Bousseksou A 《Physical chemistry chemical physics : PCCP》2005,7(15):2909-2914
A quasi-quantitative photo-induced low-spin (LS)-->high-spin (HS) conversion of FeII ions has been observed in the [Fe(TRIM)2]Cl2 complex by irradiating the sample with blue light (488 nm) at 10 K. The time dependence of the HS-->LS relaxation has been studied between 10 K and 44 K by means of magnetic susceptibility measurements. These relaxation curves could be satisfactorily fitted by mono-exponential decays including tunnelling effect except for temperatures below 30 K. The introduction of a distribution of vibrational frequencies into this model improved significantly the fits in the low-temperature range and gave a good agreement with the experimental data in the whole temperature range suggesting a multi-rate relaxation process in this complex. 相似文献
46.
J. Martinez Calatayud S. Navasquillo Sarrion A. Sanchez Sampedro C. Gomez Benito 《Microchemical Journal》1992,45(2)
A flow injection analysis procedure for the turbidimetric determination of promethazine is proposed. The sample solution is injected directly into the carrier reagent stream, which is composed of 1.16 × 10−3M bromophenol blue at pH 1.20. The calibration graph is linear over the range 25–197 ppm of promethazine. The influence of some foreign substances was also investigated. The method is applied to promethazine determination in a pharmaceutical formulation. 相似文献
47.
48.
1,5-Bis[(2-pyridyl)-3-sulphophenyl methylene] thiocarbonohydrazide (PSTH) immobilized on an anion-exchange resin (Dowex) has been used for the on-line preconcentration of mercury from biological samples and waters prior to its determination by inductively coupled plasma atomic emission spectroscopy. The metal was eluted from the column using a solution of 2 M HNO(3) and mixed on-line with SnCl(2). The optimum experimental conditions were evaluated for the continuous preconcentration of Hg, the direct generation of mercury vapour and the final determination of this element by ICP-AES. The enrichment, together with low blank levels of the optimized procedure, allow the simple determination of this toxic element at concentrations down to a few nanograms per milliliter. The proposed method has a linear calibration range 5-1000 ng ml(-1) of mercury, with a detection limit of 4 ng ml(-1) (S/N=3) and a sampling rate of 40 h(-1), investigated with a 9 ml sample volume. The precision of the method (evaluated as the relative standard deviation obtained after analyzing ten series of ten replicates) was +/-3.6% at the 10 ng ml(-1) level of Hg(II) and +/-1.3% at the 100 ng ml(-1) level. The accuracy of the method was examined by the analysis of certified reference materials. 相似文献
49.
K. C. Chang Luis Sanchez P. Rabinowitz 《Mathematical Methods in the Applied Sciences》1982,4(1):194-205
We consider the existence of a nontrivial solution of the following equation: where g is a nondecreasing function defined on R1, satisfies g(O) = O, and some other additional conditions. Our results and methods are quite similar to those associated with recent work on the nonlinear wave equation [1]-[8]: . 相似文献
50.
C. Cruces Blanco F. Garcia Sanchez 《International journal of environmental analytical chemistry》2013,93(4):513-523
Abstract A simple kinetic-spectrophotometric method for the analysis of the organophosphate insecticide methyl parathien is presented. The method is based on the alkaline hydrolysis of the insecticide into its main metabolite p-nitrophenol. The influence of reaction variables (pH and temperature), and the effect of other pesticides, are discussed. The calibration graphs (initial rate, fixed time, fixed absorbance) were linear from 2 to 30μg/ml. The precision was calculated for the different methods applied, the relative standard deviation being 6.25% for 4μg/ml. The proposed kinetic method can be applied directly to synthetic mixtures, commercial formulations and different aqueous environment, with recoveries close to 100%. 相似文献