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81.
S. A. Salem 《Czechoslovak Journal of Physics》2006,56(6):601-617
In this paper, we determined a numerical solution of the Navier-Stokes equations for the flow of incompressible fluid inside
the contraction geometry. The governing equations are written in the vorticity-stream function formulations. The numerical
solution is based on a technique of automatic numerical generation of a curvilinear coordinate system by transforming the
governing equation into the computational plane. The transformed equations are approximated using central differences and
solved simultaneously by the alternating direction implicit method and successive over relaxation iteration method. 相似文献
82.
A bead-injection system is proposed for total mercury determination in river-water samples. The procedure is based on the introduction of a defined quantity of a resin suspension in the flow system. The selected beads are packed inside of a flow cell and the formed resin mini-column constitutes the optical path. The sample volume is then selected, and its passage by the mini-column allows retention of the mercury ions on the surfaces of the beads. The introduction of a spectrophotometric reagent in the flow system leads to the formation of a colored Hg-dithizone complex on the surface of the bead, which is spectrophotometricaly monitored. The spent beads are directed to waste, allowing the system to become ready to process another sample. The proposed system handles about 20 measurements per hour, consuming 1000 microl of the sample, 1 mg of Chelex 100 resin and 1.25 microg of Dithizone per determination. When 1000 microl of the sample is injected, a linear analytical curve is obtained (A = 0.0052[Hg] + 0.1028, from 0 up to 30 microg l(-1), R2 = 0.995); the detection limit is estimated to be 0.9 microg l(-1). The results are precise, r.s.d. < 9%; spiked sample recoveries within 91.2 and 109% are found. 相似文献
83.
Stereoscopic imaging and reconstruction technique is introduced to reconstruct the flame structures that are subject to acoustic excitation. The laminar diffusion flame under investigation was created in a cylindrical tube and excited by a loudspeaker. Stereo images were taken at a shutter speed of 1/10000th second using a ‘stereo camera’ and the depth cue of the flame structures along the camera viewing direction were then computed using machine vision methodology. By visualizing the computed three-dimensional flame models, as well as judging the corresponding attribute such as surface gradient, the understanding of the flame and acoustic wave interaction could be improved. 相似文献
84.
85.
The analysis of data concerning the deterioration of pavement over time yielded a problem of aggregating the data in a manner that preserved independence of the aggregated data points and maximized the number of points. We show that this problem can be modeled as a maximum cardinality vertex packing problem on a proper internal graph and thus can be solved very efficiently by a greedy algorithm. 相似文献
86.
The two emission lines, Kα1α3h and Kα2α3h resulting from the two-electron transitions and were resolved for elemental nickel. Their measured energies agree well with calculations. Their relative intensity and their intensity relative to that of the Kα diagram lines is about 10?4. This is some 104 times larger than both theoretical results and the results of ion-atom collision experiments. 相似文献
87.
The tetradentate Schiff-base ligands, N,N′-bis(salicylidene)-ethylenediamine (Salen), N,N′-bis(salicylidene) butylenediamine (Salbut), and N,N′-bis(salicylidene)-o–phenylenediamine, (sal-o-phen) are very strongly sorbed by cation exchange resin (Dowex-50W) with Fe2+ ions as a counter ion, forming stable complexes. The kinetics of the catalytic decomposition of H2O2 using these complexes was studied in ethanolic medium. The reaction was first-order with salen and sal-o-phen and second-order with salbut with respect to [H2O2]. The rate of the H2O2 decomposition increased either from salen to salbut or from salen to sal-o-phen. Also, the k (per g dry resin) values decreased with increasing both the particle size and the degree of resin cross-linkage. The active species formed at the beginning of the reaction, had an inhibiting effect on the reaction rate. The corresponding activation parameters were calculated from a least-squares fit of the temperature dependence of the rate constant. A reaction mechanism is proposed. © 1994 John Wiley & Sons, Inc. 相似文献
88.
J. Stephanidou-Stephanatou N. E. Alexandrou G. Salem A. Terzis 《Journal of heterocyclic chemistry》1985,22(3):673-675
The crystal and molecular structure of the title compound, derived by lead tetraacetate oxidation of the bis-p-methoxybenzoylhydrazone of 3,3-dimethylpentane-2,4-dione, is studied by an X-ray crystallographic analysis. 相似文献
89.
90.
Electrical conductivity measurements of 2,4-dinitrosoresorcinol (DNR) and its complexes were measured in the temperature range 20–115°C to give faint semiconducting behaviour for these systems. The conductivity values of the bis Co, Ni, Cu and Zn systems indicated that the metal ion forms a bridge between the two ligands facilitating the transfer of current carriers with some degree of delocalization in the excited state. As the iron content in the complexes increased, a gradual increase of electrical conductivity occurred, that might be due to lattice imperfections. 相似文献