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排序方式: 共有75条查询结果,搜索用时 140 毫秒
31.
Yardim Y Levent A Ekin S Keskin E Oto G Senturk Z 《Combinatorial chemistry & high throughput screening》2012,15(5):418-426
A number of polycyclic aromatic hydrocarbons (PAHs) have been shown to be toxicants, and induce carcinogenic and immunotoxic effects. As a model PAH agent, 7,12-dimethylbenz[a]anthracene (DMBA) was the strongest one tested in terms of its biological activities and biotransformation. A new and simple high-performance liquid chromatographic (HPLC) method with diode-array detection at 290 nm was developed and validated for monitoring of DMBA in different matrices (serum, liver and kidney) of rats orally treated with DMBA. Furthermore, the applicability of adsorptive transfer stripping voltammetry (AdTSV) on the pencil-lead graphite electrode to these samples was illustrated using our previously reported data for bulk aqueous solutions of DMBA. HPLC and AdTSV methods, which were compatible with each other, allowed DMBA to be detected down to the levels of 3.82x10-9 M (0.98 ppb) and 6.73x10-9 M (1.73 ppb), respectively. Olive oil solutions of DMBA in dose 50 mg/kg were orally administered. 60 days after a single dose of DMBA, its concentrations in these biological samples from rats were measured by means of both methods. Because of rapid biotransformation, DMBA could not be detected in serum. Only low levels of the compounds were deposited unchanged in kidney whereas its levels were considerably higher in liver. These methods were also applied to the assay whether there is an influence of the intake of aqueous extracts of Hypericum Perforatum L. plant on the parent DMBA levels accumulated in rat tissues. 相似文献
32.
Free vibration characteristics of filament wound anisotropic shells of revolution are investigated by using multisegment numerical integration technique in combination with a modified frequency trial method. The applicability of multisegment numerical integration technique is extended to the solution of free vibration problem of anisotropic composite shells of revolution through the use of finite exponential Fourier transform of the fundamental shell equations. The governing shell equations comprise the full anisotropic form of the constitutive relations, including first-order transverse shear deformation, and all components of translatory and rotary inertia. The variation of the stiffness coefficients along the axis of the shell is also incorporated into the solution method. Filaments are assumed to be placed along the geodesic fiber path on the shell of revolution resulting in the variation of the stiffness coefficients along the axis of the composite shell of revolution with general meridional curvature. Sample solutions have been performed on the effect of the variation of the stiffness coefficients on the free vibration behavior of filament wound truncated conical and spherical shells of revolution. 相似文献
33.
Relativistic effects are employed to describe the weakly bound nuclei of \({}^{17}\)F and \({}^{11}\)Be. In order to calculate the energy levels of the ground state and the excited states of these nuclei, we solved the Dirac equation with pseudospin symmetry in the shell model by using the basic concept of supersymmetric shape invariance method. The results obtained from this approach are compared with a non-relativistic approach and experiment. It was then seen that the relativistic approach matches more with the experimental results. 相似文献
34.
Investigation of the spectral properties of a fourth order differential operator with finite transmission conditions
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Ekin Uğurlu 《Mathematical Methods in the Applied Sciences》2016,39(6):1298-1310
In this paper, the spectral analysis of a singular dissipative fourth order differential operator in lim‐4 case with finite transmission conditions is investigated. For this purpose, the inverse operator with explicit form is used. Finally, with the help of Liv?ic's theorem, it is proved that all root vectors of the fourth order dissipative operator in lim‐4 case with finite transmission conditions are complete in the Hilbert space. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
35.
36.
Ramazan Koçak Dilan Yıldız Uğur Bozkaya Arif Daştan Özgür Altan Bozdemir 《Tetrahedron letters》2017,58(30):2981-2985
Highly fluorescent, novel dihydropyridazine-appended dibenzosuberenone type dye molecules were obtained in a single step from simple compounds using Diels-Alder chemistry. This new fluorophore structure can be used for the construction of fluorescent chemosensors, as exemplified by selective and sensitive fluoride ion sensing. The –N–H protons in these structures are acidic enough to allow for fluoride-induced deprotonation, leading to a significant color change as well as a concomitant fluorescence quenching. These fluorophores possess large Stokes shifts, high quantum yields, and long fluorescence lifetimes; therefore, this study potentially paves the way for the construction of novel dye molecules for use in fluorescent dye applications. 相似文献
37.
Let us consider the differential expression $$\ell (y)=-y^{\prime \prime }+q(x)y,\quad x\in I:=[0,c)\cup (c,\infty ),$$ where c is a transmission point and is regular for the differential expression ?(y). We assume that Weyl’s limit-circle case holds for the differential expression ?(y) on I. In this paper, using Krein’s theorems, we investigate the completeness of the root vectors of a singular dissipative boundary value transmission problem generated by ?(y). 相似文献
38.
Despite an increasing interest in modelling skeletal muscles adaptation, models that address the phenomena within a continuum-mechanical framework using muscle-specific material models are rare in literature. This work focuses on modelling one form of skeletal musle adaptation, namely sarcomerogenesis. Sarcomerogenesis occurs when a given stretch is sustained over a period of time and the number of basic contractile units, which are the sarcomeres, increase. To model sarcomerogenesis within a continuum-mechanical setting, the growth framework based on a multiplicative split of the total deformation gradient is employed. An evolution equation that describes sarcomerogenesis is used and incorporated in a transversally isotropic material model that accounts for a skeletal muscle's active force production capabilities. The material tangent modulus is derived and implemented within the finite-element analysis software. Using this model, one sees that increased number of sarcomeres results in a decreased force response of the muscle tissue over time. (© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
39.
A Collection of Fullerenes for Synthetic Access Toward Oriented Charge‐Transfer Cascades in Triple‐Channel Photosystems
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Dr. Altan Bolag Javier López‐Andarias Santiago Lascano Saeideh Soleimanpour Dr. Carmen Atienza Dr. Naomi Sakai Prof. Nazario Martín Prof. Stefan Matile 《Angewandte Chemie (International ed. in English)》2014,53(19):4890-4895
The development of synthetic methods to build complex functional systems is a central and current challenge in organic chemistry. This goal is important because supramolecular architectures of highest sophistication account for function in nature, and synthetic organic chemistry, contrary to high standards with small molecules, fails to deliver functional systems of similar complexity. In this report, we introduce a collection of fullerenes that is compatible with the construction of multicomponent charge‐transfer cascades and can be placed in triple‐channel architectures next to stacks of oligothiophenes and naphthalenediimides. For the creation of this collection, modern fullerene chemistry—methanofullerenes and 1,4‐diarylfullerenes—is combined with classical Nierengarten–Diederich–Bingel approaches. 相似文献
40.
In this paper a singular dissipative impulsive boundary value problem with $n$ -impulsive points is investigated. In particular, using the Lidski?’s theorem it is proved that all eigen and associated functions of this problem is complete in the Hilbert space. 相似文献