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111.
Vlad V. Travkin Georgy L. Pakhomov Ekaterina E. Terukova 《Molecular Crystals and Liquid Crystals》2014,589(1):154-161
We analyze the current-vs-voltage (J-V) characteristics of ITO/C60/Al sandwich cells, where ITO is the double indium tin oxide, C60 is the buckminsterfullerene and Al is the thermally evaporated top aluminum electrode. These cells were obtained on either glass/ITO or polyethyleneterephthalate/ITO substrates (or, optionally, on glass/ZnO substrates) in a parallel process under identical conditions. However, the J-V dependences in each series behave very differently. The results are discussed in terms of the migration of admixtures from a bulk substrate material toward the top metallic electrode, thus modifying the photovoltaic properties of cells. 相似文献
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Domino Staudinger/aza‐Wittig/Mannich Reaction: An Approach to Diversity of Di‐ and Tetrahydropyrrole Scaffolds 下载免费PDF全文
Dr. Anna S. Pavlova Dr. Olga A. Ivanova Dr. Alexey O. Chagarovskiy Nikolay S. Stebunov Dr. Nikolay V. Orlov Dr. Alexey N. Shumsky Dr. Ekaterina M. Budynina Dr. Victor B. Rybakov Prof. Dr. Igor V. Trushkov 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(50):17967-17971
A highly efficient and selective domino reaction producing valuable di‐ and tetrahydropyrrole‐based skeletons from azidoethyl‐substituted CH‐acids and (thio)carbonyl compounds has been developed. By involving the additional functional groups in starting compounds into the domino reaction or postmodification of the primary reaction products, the simple construction of the pharmaceutically relevant three‐ and polycyclic azaheterocyclic scaffolds was demonstrated. 相似文献
114.
Yushina Irina D. Pikhulya D. G. Bartashevich Ekaterina V. 《Journal of Thermal Analysis and Calorimetry》2020,139(2):1017-1023
Journal of Thermal Analysis and Calorimetry - A series of crystalline thiazoloquinolinium iodides has been studied using a combination of thermal analysis, mass and Raman spectroscopy techniques.... 相似文献
115.
Dr. Ekaterina Y. Chernikova Dr. Daria V. Berdnikova Dr. Alexander S. Peregudov Prof. Olga A. Fedorova Dr. Yuri V. Fedorov 《Chemphyschem》2020,21(5):442-449
The photochemical isomerization of a styrylpyridinium dye ( SP ) bearing an unsymmetrically attached benzo-15-crown-5 ether has been studied in aqueous solution in the absence and presence of cucurbit[7]uril (CB[7]). The detailed analysis of the UV/Vis and NMR spectra showes that the isomeric composition of the photostationary mixtures of SP can be modulated by the host-guest complexation with CB[7]. It was found that steric hindrance caused by encapsulation of SP in the host cavity induces the exclusive formation of the anti conformer of Z- SP in contrast with the mixture of both anti and syn conformers obtained during photoisomerization of the dye without CB[7]. Remarkably, the displacement of anti Z- SP from CB[7] does not lead to the transformation of the anti Z-isomer into the syn Z-isomer pointing out the conformational memory of the system. The results provide an interesting example of the supramolecular stereorecognition by the achiral CB[7] host. 相似文献
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Ekaterina Chainikova Sergey Khursan Alfia Yusupova Alexander Lobov Marat Abdullin Rustam Safiullin 《Tetrahedron letters》2018,59(34):3267-3271
During the photooxidation of aromatic azides containing a secondary N–H bond at the para-position, a sequence of intramolecular transformations of nitroso oxides led to the formation of heterocyclic oximes along with the corresponding nitroso and nitro compounds. 相似文献
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Stack the Bowls: Tailoring the Electronic Structure of Corannulene‐Integrated Crystalline Materials 下载免费PDF全文
Allison M. Rice Ekaterina A. Dolgopolova Brandon J. Yarbrough Gabrielle A. Leith Corey R. Martin Kenneth S. Stephenson Rebecca A. Heugh Amy J. Brandt Prof. Dr. Donna A. Chen Dr. Stavros G. Karakalos Dr. Mark D. Smith Prof. Dr. Kelsey B. Hatzell Dr. Perry J. Pellechia Prof. Dr. Sophya Garashchuk Prof. Dr. Natalia B. Shustova 《Angewandte Chemie (International ed. in English)》2018,57(35):11310-11315
We report the first examples of purely organic donor–acceptor materials with integrated π‐bowls (πBs) that combine not only crystallinity and high surface areas but also exhibit tunable electronic properties, resulting in a four‐orders‐of‐magnitude conductivity enhancement in comparison with the parent framework. In addition to the first report of alkyne–azide cycloaddition utilized for corannulene immobilization in the solid state, we also probed the charge transfer rate within the Marcus theory as a function of mutual πB orientation for the first time, as well as shed light on the density of states near the Fermi edge. These studies could foreshadow new avenues for πB utilization for the development of optoelectronic devices or a route for highly efficient porous electrodes. 相似文献