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91.
Vincenza Maria Coiro Edoardo Giglio Fernando Mazza Nicolae Viorel Pavel 《Journal of inclusion phenomena and macrocyclic chemistry》1984,1(4):329-337
The 2:1 inclusion compound formed between deoxycholic acid (C24H40O4,M
r=392.58) and quadricyclane (C7H8,M
r=92.14) crystallizes in space groupP212121 witha=27.150(7),b=13.359(3),c=14.161(4) Å,Z=4. The structure was refined toR=0.086 andR
w=0.088 for 2079 observed reflections withI>2.5(I). The crystal packing is very similar to that found in the norbornadiene-deoxycholic acid inclusion compound and is characterized by an assembly of antiparallel pleated bilayers, formed by molecules of deoxycholic acid held together through hydrogen bonds. Quadricyclane occupies approximately the same position of norbornadiene and its atoms give rise to good van der Waals interactions with some methyl groups of deoxycholic acid.
Supplementary Data relating to the article are deposited with the British Library as Supplementary Publication No. SUP 82006 (14) pages. To obtain copies, see page ii of this issue. 相似文献
92.
Edoardo Cesarotti Maria Grassi Laura Prati
Francesco Demartin
《Journal of organometallic chemistry》1989,370(1-3):407-419The DANTE technique and NOESY two-dimensional method have been employed to observe the isomerization of the chiral cationic complex [Pd(η3-CH2CMeCH2(P-P′)]+ (1a), where P-P′ = the chiral chelating ligand (S)(N-diphenylphosphino)(2-diphenylphosphinoxymethyl)pyrrolidine. The rate constant was found to be 0.5 s−1 in CHCl3 at 295 K and 1.50 s−1 in the presence of added free ligand. In the latter case the epimerization proceeds by a π-σ-π mechanism via the intermediacy of a primary η1-allylpalladium complex. Although the intermediate was not detected, the NMR findings reveal that it has the allylic terminus η1-bonded to palladium. The structure of 1a in its PF6− salt has been determined. The compound crystallizes in the orthorhombic space group P212121 with a 10.029(4) b 19.203(8) c 36.115(6) Å, Z = 8, R = 0.0572 and Rw = 0.0712 for 3716 observed reflections with I > 3σ(I). 相似文献
93.
94.
Edoardo Ballico 《Rendiconti del Circolo Matematico di Palermo》2001,50(1):209-212
Let X be a smooth curve of genus g with two pencils, sayg
k
1
andg
m
1
. Here we show that, in general, dim|rg
k
1
+ug
m
1
| has the expected dimension and construct examples in which dim |rg
k
1
+ug
m
1
| has a prescribed value. 相似文献
95.
Edoardo Ballico Elizabeth Gasparim Thomas Köppe 《Central European Journal of Mathematics》2009,7(4):623-628
In a recent paper, Gallego, González and Purnaprajna showed that rational 3-ropes can be smoothed. We generalise their proof, and obtain smoothability of rational m-ropes for m ≥ 3. 相似文献
96.
Ugo Amaldi 《Annali di Matematica Pura ed Applicata》1938,17(1):1-21
Commemorazione letta davanti alla Classe di Scienze fisiche, matematiche e naturali della Reale Accademia Nazionale dei Lincei
nell'adunanza del 5 dicembre 1937-XVI. 相似文献
97.
98.
99.
Edoardo Ballico 《代数通讯》2013,41(9):3895-3901
We discuss two conjectures by Francesco Severi and Joe Harris about the irreducibility and the dimension of the Hilbert scheme parameterizing smooth projective curves of given degree and genus. 相似文献
100.
Prof. Carlos O. Areán Dr. Sachin Chavan Carlos P. Cabello Prof. Edoardo Garrone Dr. Gemma T. Palomino 《Chemphyschem》2010,11(15):3237-3242
Interaction between adsorbed hydrogen and the coordinatively unsaturated Mg2+ and Co2+ cationic centres in Mg‐MOF‐74 and Co‐MOF‐74, respectively, was studied by means of variable‐temperature infrared (VTIR) spectroscopy. Perturbation of the H2 molecule by the cationic adsorbing centre renders the H? H stretching mode IR‐active at 4088 and 4043 cm?1 for Mg‐MOF‐74 and Co‐MOF‐74, respectively. Simultaneous measurement of integrated IR absorbance and hydrogen equilibrium pressure for spectra taken over the temperature range of 79–95 K allowed standard adsorption enthalpy and entropy to be determined. Mg‐MOF‐74 showed ΔH0=?9.4 kJ mol?1 and ΔS0=?120 J mol?1 K?1, whereas for Co‐MOF‐74 the corresponding values of ΔH0=?11.2 kJ mol?1 and ΔS0=?130 J mol?1 K?1 were obtained. The observed positive correlation between standard adsorption enthalpy and entropy is discussed in the broader context of corresponding data for hydrogen adsorption on cation‐exchanged zeolites, with a focus on the resulting implications for hydrogen storage and delivering. 相似文献