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141.
142.
Mauro Angiolini Silvia Araneo Laura Belvisi Edoardo Cesarotti Anna Checchia Luca Crippa Leonardo Manzoni Carlo Scolastico 《European journal of organic chemistry》2000,2000(14):2571-2581
In an effort to design dipeptide structural mimics of protein and peptide reverse-turns, a series of 5,5-, 6,5-, and 7,5-fused 2-oxo-1-azabicycloalkane amino acids has been synthesized. A new and convenient synthetic route utilizing a Horner−Emmons reaction followed by double-bond reduction has been used to prepare the bicyclic lactams in high yields. 相似文献
143.
Matteo Grattieri Sofia Babanova Carlo Santoro Edoardo Guerrini Stefano PM Trasatti Pierangela Cristiani Massimiliano Bestetti Plamen Atanassov 《Electroanalysis》2015,27(2):327-335
A selective oxygen biosensor based on bilirubin oxidase (BOx) was developed. The sensor was used for determining oxygen profiles in a membraneless, single‐chamber microbial fuel cell (SCMFC), fed with raw wastewater. The linear response of the sensor was optimized by a diffusion layer of silica gel. A computer‐controlled stage was used to obtain accurate and precise measurements. Oxygen concentration in biofilms covering electrodes was measured, showing 3 mg L?1 of O2 in the bulk solution, decreasing to 0 mg L?1 in the cathodic biofilm. The MFC generated power in the range of 0–0.08 mW, associated to the oxygen content. 相似文献
144.
This work illustrates an engineering approach for the analysis of plywood/fibreglass perforated panels, to be used for the linearisation of the frequency response of medium size rooms below 200 Hz. The sound absorption coefficient of these panels is computed, by means of coupled acoustical/structural finite element (FEM) analyses, as a function of the frequency. The comparison between the results given by a complete numerical model of the panel, and those provided by a simplified numerical model, in which only one hole and surrounding material (wood, air, and fibreglass) are described, shows that the second computational approach provides essentially the same results as the former one, at a quite reasonable cost. The FEM results allow us to understand some details about the air motion inside the panel, and to define suitable assumptions for the construction of a simplified analytical model of the panel. Both the numerical and the analytical results are finally compared to experimental data obtained by means of pressure-particle velocity measurements. 相似文献
145.
Adami G Capriglia L Barbieri P Cozzi F Lo Coco F Acquavita A Reisenhofer E 《Annali di chimica》2006,96(9-10):601-612
The following metals: Al, Cd, Cr, Cu, Fe, Mn, Ni, Pb and Zn were determined by inductively coupled plasma - atomic emission spectroscopy (ICP-AES) in fluvial sediments of Rosandra Creek, using two different, strong and mild sediment decomposition methods. The purpose was to obtain information about the contamination by metals and distribution paths of pollutants in the area crossed by Rosandra Creek: this little river is the unique epigeous watercourse in the Italian Karst and very few data can be found in literature. In this area, we can find a natural park, but also agricultural activities and an industrial district that was recently defined as "polluted site of national interest". By comparing the results of the strong and mild extraction we have obtained the percentage of extraction and enrichment factors for each metal in the different sediments of the sites R2 and R3 exposed to pollution, while the site R1 was considered as a pristine one because situated in the natural park. The computed enrichment factors are generally not very high, but copper, lead and zinc have factors that require attention. The principal component analysis (PCA) shows that the typically anthropogenic metals (as Cr, Pb, Cu and Zn) constitute the first factor, while the lithogenic metals, as Fe and Ni, constitute the second one; moreover the score plots permit to classify and distinguish the 3 sites: site R3, possibly the more exposed to contamination, has high scores both for anthropogenic and lithogenic metals. 相似文献
146.
We report the first harmonic vibrational spectra for each of the lowest lying isomers within the four major families of minima of (H2O)20, namely, the dodecahedron, fused cubes, face-sharing pentagonal prisms, and edge-sharing pentagonal prisms. These were obtained at the second-order Moller-Plesset perturbation level of theory (MP2) with the augmented correlation consistent basis set of double zeta quality (aug-cc-pVDZ) at the corresponding minimum energy geometries. The computed infrared (IR) spectra are the first ones obtained from first principles for these clusters. They were found to contain spectral features, which can be directly mapped onto the distinctive spectroscopic signatures of their constituent tetramer, pentamer, and octamer fragments. The dodecahedron spectra show the richest structure in the OH stretching region and are associated with the most redshifted OH vibrations with respect to the monomer. The lowest lying edge-sharing pentagonal prism isomer displays intense IR active vibrations that are redshifted by approximately 600 cm(-1) with respect to the water monomer. Furthermore the most redshifted, IR-active OH stretching vibrations for all four networks correspond to hydrogen bonded OH groups, which exhibit the following two common characteristics: (i) they belong to fragments which have a "free" OH stretch and (ii) they act as donors to a neighboring water molecule along a "dimerlike" (strong) hydrogen bond. The zero-point energy corrected MP2/CBS (complete basis set) limit binding energies D(0) for the four isomers are -163.1 kcal/mol (edge-sharing pentagonal prism), -160.1 kcal/mol (face-sharing pentagonal prism), -157.5 kcal/mol (fused cubes), and -148.1 kcal/mol (dodecahedron). 相似文献
147.
148.
149.
P. Abreu W. Adam T. Adye E. Agasi G. D. Aleseev P. Allen S. Almehed S. J. Alvsvaag U. Amaldi E. G. Anassontzis et al. 《Zeitschrift fur Physik C Particles and Fields》1992,56(1):63-75
The multiplicity distributions of charged particles in full phase space and in restricted rapidity intervals for events with a fixed number of jets measured by the DELPHI detector are presented. The data are well reproduced by the Lund Parton Shower model and can also be well described by fitted negative binomial distributions. The properties of these distributions in terms of the clan model are discussed. In symmetric 3-jet events the candidate gluon jet is found not to be significantly different in average multiplicity than the mean of the other two jets, thus supporting previous results of the HRS and OPAL experiments. Similar results hold for events generated according to the LUND PS and to the HERWIG models, when the jets are defined by the JADE jet finding algorithm. The method seems to be insensitive for measuring the color charge ratio between gluons and quarks. 相似文献
150.
Let X be a Fano 3-fold of the first kind with index 2. In this paper, we characterize the chern classes of rank 2 stable vector bundles on X and we find a bound for the least twist of a rank 2 reflexive sheaf on X which has a global section. 相似文献