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71.
Marijana ?aković Zora Popović 《Acta Crystallographica. Section C, Structural Chemistry》2007,63(11):m507-m509
In the title compound, [Ni(N3)2(C6H6N2O)2], the NiII atom lies on an inversion centre. The distorted octahedral nickel(II) coordination environment contains two planar trans-related N,O-chelating picolinamide ligands in one plane and two monodentate azide ligands perpendicular to this plane. Molecules are linked into a three-dimensional framework by N—H...N hydrogen bonds. 相似文献
72.
NIKITIN S.; PR?TZEL-WOLTERS D. 《IMA Journal of Mathematical Control and Information》1991,8(4):431-439
In 1983 Morse proved, for unknown scalar one-dimensional linearsystems, the nonexistence of rational or polynomial universalstabilizers (UAS). In 1983, Nussbaum gave an example of an analyticUAS. In our paper, it is shown that there exist time-invariantpolynomial UAS's with multidimensional gain adaptation. Thedesign procedure is developed for linear, minimum-phase systemsof relative degree one. Convergence of the closed-loop systemis proved. Some numerical simulations are provided. 相似文献
73.
Ivica ?ilovi Dubravka Matkovi‐alogovi Ivan Kos Mladen Biru Milena Jadrijevi‐Mladar Taka
《Acta Crystallographica. Section C, Structural Chemistry》2007,63(1):o45-o47
In the crystal structures of two cyclic trihydroxamic acid derivatives containing the same substructure unit, viz. 1,3,5‐trihydroxy‐1,3,5‐triazinane‐2,4,6‐trione dihydrate, C3H3N3O6·2H2O, (I), and 1,3,5‐benzyloxy‐1,3,5‐triazinane‐2,4,6‐trione, C24H21N3O6, (II), there is no significant difference in the geometric parameters. In (I), there are 11 hydrogen bonds of the O—H⋯O type interconnecting the molecules in a three‐dimensional network, while in (II) there are only two weak C—H⋯O hydrogen bonds. The results of IR spectroscopic analysis are in good agreement with the crystallographic study. 相似文献
74.
75.
Katalin E. Kövér Dušan Uhr?&#x;n Victor J. Hruby 《Journal of magnetic resonance (San Diego, Calif. : 1997)》1998,130(2):162-168
A pulsed field gradient version of the sensitivity-enhanced 2D TOCSY experiment is proposed which yields high-quality spectra with improved sensitivity and a minimum of two scans pert1increment. For rapid acquisition of 1D TOCSY spectra, the 1D DPFGSE–TOCSY experiment was modified to include phase-encoded multiple-selective excitation followed by a simple spectral editing. Combination of these two building blocks is used in a sensitivity-enhanced 2D analog of the 3D TOCSY–TOCSY experiment which provides an efficient tool for resolving severely overlapped signals of oligomers in short experimental time. 相似文献
76.
超重元素(新核素)合成研究进展情况分析和展望 总被引:2,自引:0,他引:2
本文在介绍和分析国际、国内在超重元素(新核素)合成实验研究与理论研究进展情况的基础上对我国今后如何从理论与实验的结合上开展超重元素(核)合成研究工作提出一些看法和建议,提供讨论。 相似文献
77.
S. B. Edgar 《General Relativity and Gravitation》1987,19(11):1149-1150
Massa and Pagani [1] have given a neat refutal to the conjecture [2] that the Riemann tensor is derivable from a tensor potential. Their method consists of assuming such a relationship does exist and examining the resulting integrability conditions; they show that the existence of such a potential will impose nontrivial restrictions on the Riemann tensor and so conclude that, in general, such a potential cannot exist. Although Massa and Pagani posed the problem and interpreted the conclusion in ordinary tensor notation the actual derivation of the crucial constraint equation was carried out in the language of tensor-valued differential forms, and is quite involved. In this note it is shown that the crucial equation can be obtained quite naturally and easily in ordinary tensor notation. 相似文献
78.
Olga Ordeig Craig E Banks Trevor J Davies F Javier del Campo Francesc Xavier Mu?oz Richard G Compton 《Analytical sciences》2006,22(5):679-683
Gold ultra-microelectrode arrays are used to explore the electrochemical oxidation of hydroxide ions and are shown to be analytical useful. Two types of ultra-microelectrode arrays are used; the first consist of 256 individual electrodes of 5 microm in radius, 170 of which are electrochemically active in a cubic arrangement which are separated from their nearest neighbour by a distance of 100 microm. The second array compromises 2597 electrodes of 2.5 microm in radius and of which 1550 of which are electrochemically active in a hexagonal arrangement separated by the nearest neighbour by 55 microm. Well defined voltammetric waves are found with peak currents proportional to the concentration of hydroxide ions in the range 50 microM to 1 mM. Detection limits of 20 microM using the 170 ultra-microelectrode and 10 microM with the 1550 ultra-microelectrode array are shown to be possible but with a higher sensitivity of 4 mA M(-1) observed using the 1550 ultra-microelectrode array compared to 1.2 mA M(-1) with the 170 ultra-microelectrode array. 相似文献
79.
Ivan Gutman Sabina Gojak Niko Radulovi? Boris Furtula 《Monatshefte für Chemie / Chemical Monthly》2006,46(2):277-284
In a recent work it was demonstrated that in linear hexagonal chains the distribution of π-electrons into rings (as computed
by means of the Randić–Balaban method) is uniform, irrespective of the nature of the terminal fragments. We now establish that an analogous, yet somewhat
more complex, uniformity in the π-electron distribution exists also in double linear hexagonal chains, as well as in some
other benzenoid systems. 相似文献
80.
Thin films of silicon oxynitride have largely replaced pure silicon oxide films as gate and tunnel oxide films in modern technology due to their superior properties in terms of efficiency as boron barrier, resistance to electrical stress and high dielectric strength. A single chamber system for plasma enhanced chemical vapor deposition was employed to deposit different films of SiOxNyHz with 0.85 < x < 1.91. All films were previously characterized by Rutherford back-scattering and infrared spectroscopy to determine the stoichiometry and the presence of various bonding configurations of constituent atoms. We used X-ray reflectivity to determine the electron density profile across the depth, and we showed that the top layer is densified. Moreover, grazing incidence small-angle X-ray scattering was used to study inhomogeneities (clustering) in the films, and it is shown that plate-like inhomogeneities exist in the top and sphere-like particles at the bottom part of the film. Their shape and size depend on the stoichiometry of the films. 相似文献