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101.
102.
The centrosymmetric [Zn2{CH3OC6H4P(OC5H9)S2}4], features an eight‐membered Zn2S4P2 ring as a result of two bidentate bridging thiolate ligands; the remaining ligands are chelating. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   
103.
Denim trousers, commonly known as “blue jeans”, have maintained their popularity for many years. For the purpose of supporting customers’ purchasing behaviour and to address their aesthetic taste, companies have been trying in recent years to develop various techniques to improve the visual aspects of denim fabrics. These techniques mainly include printing on fabrics, embroidery and washing the final product. Especially, fraying certain areas of the fabric by sanding and stone washing to create designs is a popular technique. However, due to certain inconveniences caused by these procedures and in response to growing demands, research is underway to obtain a similar appearance by creating better quality and more advantageous manufacturing conditions.

As is known, the laser is a source of energy which can be directed on desired objects and whose power and intensity can be easily controlled. Use of the laser enables us to cut a great variety of material from metal to fabric. Starting off from this point, we thought it would be possible to transfer certain designs onto the surface of textile material by changing the dye molecules in the fabric and creating alterations in its colour quality values by directing the laser to the material at reduced intensity.

This study mainly deals with a machine specially designed for making use of laser beams to transfer pictures, figures as well as graphics of desired variety, size and intensity on all kinds of surfaces in textile manufacturing such as knitted—woven fabrics, leather, etc. at desired precision and without damaging the texture of the material.

In the designed system, computer-controlled laser beams are used to change the colour of the dye material on the textile surface by directing the laser beams at a desired wavelength and intensity onto various textile surfaces selected for application. For this purpose, a laser beam source that can reach the initial level of power and that can be controlled by means of a computer interface; reflecting mirrors that can direct this beam at two axes; a galvanometer which comprised of an optical aperture; and a computer program that can transfer images obtained in standard formats to the galvanometer control card were used.

Developing new designs by using the computer and transferring the designs that are obtained on textile surfaces will not only increase and facilitate the production in a more practical manner, but also help you to create identical designs. This means serial manufacturing of the products at a standard quality and increasing their added values. Moreover, creating textile designs using laser will also contribute to the value of the product as far as the consumer is concerned because it will not cause any wearing off and deformation in the texture of the fabric unlike the sanding and stoning processes.

Another advantage of this system is that it gives a richer look to the product by causing the textile surfaces to get wrinkled and become three-dimensional by deformation as well as enabling you to create pictures and patterns on leather and synthetic fabrics by means of heat.

As for the results of the study, the first step was to prepare 40 pairs of denim trousers, half of which were prepared manually and the other half by using laser beam. Time studies were made at every step of the production. So as to determine the abrasion degrees of the trousers in design applications, tensile strength as well as tensile extension tests were conducted for all the trousers.  相似文献   

104.
Transition Metal Chemistry - A series of 2-hydroxyethyl-substituted N-heterocyclic carbene–(NHC)PdX2PPh3 complexes have been synthesized by substitution of the pyridine or 3-chloropyridine...  相似文献   
105.
4-[2-(Phenylthio)ethoxy]phthalonitrile 3 was synthesized by nucleophilic displacement of nitro group in 4-nitrophthalonitrile with 2-(phenylthio)ethanol 1. The metal-free phthalocyanine 4 was prepared by the reaction of a dinitrile monomer with 2-(dimethylamino)ethanol. Ni(II), Co(II), Cu(I) phthalocyanines 5, 7, 8 were prepared by reaction of the dinitrile compound with the chlorides of Ni(II), Co(II), Cu(I) in DMAE. Zn(II) phthalocyanine 6, was prepared by reaction of the dinitrile compound with the acetates of Zn(II) in DMAE. Electrochemical behaviours of novel metal-free, Co(II) and Zn(II) phthalocyanines were investigated by cyclic voltammetry, potential differential pulse voltammetry techniques. The new compounds were characterized by a combination of IR, 1H NMR, 13C NMR, UV–Vis, elemental analysis and MS spectral data.  相似文献   
106.
A new surface based on the natural clay mineral sepiolite and a single-walled carbon nanotubes-modified graphite electrode was developed for the electrochemical detection of DNA, and also for anticancer drug-DNA interactions.  相似文献   
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