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31.
The hydroxyalkylation reaction has been used to condense benzocrown ethers with various aldehydes and ketones. The condensation reactions are catalyzed by triflic or sulfuric acid. The products from the reactions are bis(benzocrown ethers) and they are formed in good yields (42-98%, 13 examples). 相似文献
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33.
Previous studies of behavior and IC single units in the mouse support theoretical expectations that gaps with ramped trailing markers have reduced detectability compared to equivalent gaps with ramped leading markers. In experiment 1, detection probability and response speeds of humans listening for gaps in broadband noise were investigated by independently varying either leading marker fall-time (FT) or trailing marker rise-time (RT). Gaps with silent duration of 1, 4, or 12 ms were presented 2 s into a 3-s noise burst, with either abrupt marker onsets and offsets or linearly ramped RT/FT of 2, 4, or 8 ms durations. Addition of a nonzero RT or FT to the gap silent period increased detectability and also increased reaction speed on trials with "Yes" response, but there was no difference in detectability or response speeds between RT and FT conditions. Experiment 2 extended this finding to gaps having two, one, or no abrupt marker edges. These findings suggest that human listeners do not make use of abrupt onset or offset information to enhance gap detection, but seem to rely on the effective sound level reduction associated with the gap for detection. 相似文献
34.
Ison JR Castro J Allen P Virag TM Walton JP 《The Journal of the Acoustical Society of America》2002,112(2):740-747
The effect on gap detectability of varying noise fall time (FT) and rise time (RT) of the gap boundary ramps was examined in mice using reflex modification audiometry, measuring inhibition of acoustic startle reflexes by variously shaped gaps just preceding reflex expression. In experiment 1 (n = 12) inhibition increased up to near-asymptotic values with longer FT (0, 1, 2, 3, 5, or 10 ms) and QT (quiet time, 0 to 13 ms), with a 2:1 trade-off between FT and QT. In experiment 2 (n = 24) inhibition increased for any RT above 0 ms (2, 3, 5, or 7 ms) if QT= 1 ms, but diminished with increased RT when QT = 3 or 8 ms. Enhanced detectability for subthreshold gaps by longer ramps results from their extending the apparent gap duration. The negative effect of increased RT for threshold gaps suggests the importance for gap detection of the stronger neural responses to sharp edges at the end of the gap shown previously in the mouse inferior colliculus. These effects are specific to gaps: inhibition for fixed (70-dB SPL) or varied level pulses (30 to 60 dB) was unaffected by varying the ramped edges (experiments 3 and 4, n = 9). 相似文献
35.
Ison JR Virag TM Allen PD Hammond GR 《The Journal of the Acoustical Society of America》2002,112(1):238-246
Listeners asked to detect tones masked by noise hear frequent signals but miss infrequent probes, suggesting that they attend to spectral regions where they expect the signals to occur. The narrow detection pattern centered on the frequent target approximates that obtained in notched noise, indicating that attention is focused on the auditory filter. We measured attention bands in young and elderly listeners (n=5, 4; 20-25 and 62-82 years of age) for targets (800 or 1200 Hz) and infrequent probe signals (target +/-25-100 Hz) masked in wideband noise. We anticipated that their width would increase with age, as has been reported for auditory filters. A yes-no single-interval procedure provided detection probabilities and detection response speeds. Both measures showed near-linear declines with decreasing signal level, and graded decay functions as probe frequency deviated from the target frequency. Probes deviating from the target by 25 to 50 Hz were equivalent to a 2-dB reduction in signal level for both measures. The equivalent rectangular bandwidth (ERB) for detection approximated 11% of the signal frequency for each age group. Confidence intervals (95%) showed that the elderly ERB could be at most only about 20% larger than that of younger listeners. 相似文献
36.
Cameron S.M. Tracy M.D. Camacho J.F. 《IEEE transactions on plasma science. IEEE Nuclear and Plasma Sciences Society》1996,24(1):45-46
Temporally integrated ultraviolet collective Thomson scattering measurements were performed with frequency-quadrupled Nd:YAG laser radiation on an underdense long-scalelength aluminum plasma (nc ~1021 cm-3, Z≈7, Te≈Ti ⩾50 eV, L⩾100 μm). The plasma was preformed by an Nd:YAG fundamental beam (1.06 μm) with focusable intensities of 10 11 W/cm2. Color images of two-dimensional (2-D) spatially resolved (30 μm) electron density and electron temperature were obtained. These are the shortest wavelength Thomson scattering measurements on a plasma to date 相似文献
37.
38.
Frederick?M.?KronzEmail author Tracy?A.?Lupher 《International Journal of Theoretical Physics》2005,44(8):1239-1258
It has been maintained that the physical content of a model of a system is completely contained in the C∗-algebra of quasi-local observables
that is associated with the system. The reason given for this is that the unitarily inequivalent representations of
are physically equivalent. But, this view is dubious for at least two reasons. First, it is not clear why the physical content
does not extend to the elements of the von Neumann algebras that are generated by representations of
. It is shown here that although the unitarily inequivalent representations of
are physically equivalent, the extended representations are not. Second, this view detracts from special global features
of physical systems such as temperature and chemical potential by effectively relegating them to the status of fixed parameters.
It is desirable to characterize such observables theoretically as elements of the algebra that is associated with a system
rather than as parameters, and thereby give a uniform treatment to all observables. This can be accomplished by going to larger
algebras. One such algebra is the universal enveloping von Neumann algebra, which is generated by the universal representation
of
; another is the direct integral of factor representations that are associated with the set of values of the global features.
Placing interpretive significance on the von Neumann algebras mentioned earlier sheds light on the significance of unitarily
inequivalent representations of
, and it serves to show the limitations of the notion of physical equivalence. 相似文献
39.
We call a Dyson process any process on ensembles of matrices in which the entries undergo diffusion. We are interested in the distribution of the eigenvalues (or singular values) of such matrices. In the original Dyson process it was the ensemble of n×n Hermitian matrices, and the eigenvalues describe n curves. Given sets X1,...,Xm the probability that for each k no curve passes through Xk at time k is given by the Fredholm determinant of a certain matrix kernel, the extended Hermite kernel. For this reason we call this Dyson process the Hermite process. Similarly, when the entries of a complex matrix undergo diffusion we call the evolution of its singular values the Laguerre process, for which there is a corresponding extended Laguerre kernel. Scaling the Hermite process at the edge leads to the Airy process (which was introduced by Prähofer and Spohn as the limiting stationary process for a polynuclear growth model) and in the bulk to the sine process; scaling the Laguerre process at the edge leads to the Bessel process.In earlier work the authors found a system of ordinary differential equations with independent variable whose solution determined the probabilitieswhere A() denotes the top curve of the Airy process. Our first result is a generalization and strengthening of this. We assume that each Xk is a finite union of intervals and find a system of partial differential equations, with the end-points of the intervals of the Xk as independent variables, whose solution determines the probability that for each k no curve passes through Xk at time k. Then we find the analogous systems for the Hermite process (which is more complicated) and also for the sine process. Finally we find an analogous system of PDEs for the Bessel process, which is the most difficult.Dedicated to Freeman Dyson on the occasion of his eightieth birthdayAcknowledgement We thank Kurt Johansson for sending us his unpublished notes on the extended Hermite kernel. This work was supported by National Science Foundation under grants DMS-0304414 (first author) and DMS-0243982 (second author). 相似文献
40.
Hanna TA Ghosh AK Ibarra C Zakharov LN Rheingold AL Watson WH 《Inorganic chemistry》2004,43(24):7567-7569
Molybdenum monooxo compoundsMoO(OAr)4-nCln (n=0-2, Ar=2,6-Me2C6H3 or 2,6-i-Pr2C6H3) have been synthesized starting from the dioxo precursor MoO2Cl2. The complexes are characterized spectroscopically and by X-ray diffraction. The formation mechanism likely involves phenol precoordination followed by addition across the Mo=O bond. 相似文献