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151.
Influence of the Type of a Ligand on the Intensity of Luminescence of Ln3+ Ions in Aqueous Solutions
I. V. Barsukov E. N. Kabaeva V. V. Syt'ko S. D. Umreiko 《Journal of Applied Spectroscopy》2003,70(3):470-473
The luminescence characteristics of hydrated Ln3+ ions and their complexes with some acidic ligands have been investigated. The possibility of determining the stability of the complexes of lanthanides in solutions from the intensity of luminescence bands is shown. The influence of the characteristic features of the f-electron shell of Ln3+ on the formation of the spectrochemical series is discussed. 相似文献
152.
The mechanism of transition of a Bose gas to the superfluid state via thermal fluctuations under the condition of external cooling at a temperature above the transition point is considered. The probability of formation of such critical fluctuations (instantons) is calculated; it is found that this probability increases as the system approaches the transition temperature. It is shown that the evolution of an individual instanton is impossible without the formation of vortices in its superfluid part. 相似文献
153.
The aim of this work is to study the dynamic formation and dissociation of trions and excitons in double barrier resonant tunneling diodes. We propose a system of rate equations that takes into account the formation, dissociation and annihilation of these complexes inside the quantum well. From the solutions of the coupled equations, we are able to study the modulation of excitons and trions formation in the device as a function of the applied bias. The results of our model agree qualitatively with the experiments showing the viability of these rate equations system to study the dynamics of complex systems. 相似文献
154.
W M Niessen M A de Kraa E R Verheij P J Bergers G F La Vos U R Tjaden J van der Greef 《Rapid communications in mass spectrometry : RCM》1989,3(1):1-4
On-line sample pretreatment by means of the phase-system switching approach is an interesting technique for the analysis of aqueous samples, e.g., plasma, by means of supercritical-fluid chromatography. In order to analyse plasma samples the following analytical procedure is used. The plasma sample is injected on to a short precolumn, which is washed with water and subsequently dried with nitrogen. Next, the solutes are desorbed with the supercritical mobile phase, analysed with packed-column supercritical-fluid chromatography and detected with either a UV detector or a mass spectrometer, equipped with a moving-belt interface. The herbicide diuron is selected as a test compound to study the feasibility of this approach. Using a selective detector the procedure is sufficiently sensitive to detect diuron in plasma, but not appropriate to detect the diuron metabolites in a post-mortem plasma sample. These have been identified with liquid chromatography/mass spectrometry. The detection limit of diuron in plasma using the procedure described is about 30 ng/mL. 相似文献
155.
Martin E. Schimpf J. Calvin Giddings 《Journal of Polymer Science.Polymer Physics》1989,27(6):1317-1332
The thermal diffusion coefficient DT has been obtained for 17 polymer-solvent combinations, each of them spanning a range of polymer molecular weights, using thermal field-flow fractionation. The polymers examined include polystyrene, poly(alpha-methyl)styrene, polymethylmethacrylate, and polysioprene. The solvents include benzene, toluene, ethylbenzene, tetrahydrofuran, methylethylketone, ethylacetate, and cyclohexane. Although DT was confirmed as essentially independent of polymer molecular weight, it was found to vary substantially with the chemical composition of polymer and solvent. The results were used to evaluate several thermal diffusion theories; the agreement with theory was generally found to be unsatisfactory. Attempts were then made to correlate the measured thermal diffusion coefficients with various physicochemical parameters of the polymers and solvent. A good correlation was found in which DT increases with the thermal conductivity difference of the polymer and solvent and varies inversely with the activation energy of viscous flow of the solvent. 相似文献
156.
In recent years there has been tremendous progress in lithium niobate-based photonic switches. The various switch configurations proposed and implemented, and their characteristics, are reviewed. A summary of the device technology is given. Performance analysis based on different architecture and the size of arrays that can be relalized are discussed.Indian Institute of Science, Bangalore, India 相似文献
157.
M. P. Nosov V. A. Smirnova Yu. F. Zabashta A. Ya. Fridman M. P. Mokhnach 《Mechanics of Composite Materials》1989,25(1):8-12
Conclusion A method was proposed which makes it possible to study the low-frequency internal friction of complex fibers. This method was used to study the internal friction of complex composite fibers based on PCA and PE. We observed a relaxation process which is typical of the composite and is absent in the pure materials.Translated from Mekhanika Kompozitnykh Materialov, No. 1, pp. 11–15, January–February, 1989. 相似文献
158.
P. P. Kirpichok N. B. Voronina A. F. Sitnikov V. Ya. Garmash 《Russian Physics Journal》1989,32(1):26-30
The effect of rare-earth oxides on the properties of anisotropic barium ferrites has been studied by x-ray structural and Mössbauer methods. Additions of SrCO3, as well as SrCO3 and La2O3, SrCO3 and Pr6O11, SrCO3 and Nd2O3, SrCO3 and Sm2O3 in amounts of 7.5 mole % Sr and 10 mole % rare-earth element to grade-A barium powder results in the substitution of barium ions by Sr and rare-earth ions; consequently, the energy of magnetic anisotropy changes and the technically important parameters Br and (BH)max increase.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 1, pp. 34–39, January, 1989. 相似文献
159.
Quasi-wavelets (QWs) are a representation of turbulence consisting of self-similar, eddy-like structures with random orientations and positions in space. They are used in this paper to calculate the scattering, due to turbulent velocity fluctuations, of sound behind noise barriers as a function of the size and spatial location of the eddies. The sound scattering cross-section for QWs of an individual size class (eddy size) is derived and shown to reproduce results for the von Kármán spectrum when the scattered energies from a continuous distribution of QW sizes are combined. A Bragg resonance condition is derived for the eddy size that scatters most strongly for a given acoustic wavenumber and scattering angle. Results for scattering over barriers show that, for typical barrier conditions, most of the scattered energy originates from eddies in the size range of approximately one-half to twice the size of the eddies responsible for maximum scattering. The results also suggest that scattering over the barrier due to eddies with a line of sight to both the source and receiver is generally significant only for frequencies above several kilohertz, for sources and receivers no more than a few meters below the top of the barrier, and for very turbulent atmospheric conditions. 相似文献
160.
C Guéret N Jussien O Lhomme C Pavageau C Prins 《The Journal of the Operational Research Society》2003,54(5):458-465
In this paper, we describe an aircraft loading problem submitted by the French military agency (DGA) as part of a more general military airlift planning problem. It can be viewed as a kind of bi-dimensional bin-packing problem, with heterogeneous bins and several additional constraints. We introduce two-phase methods for solving this NP-hard problem. The first phase consists in building good initial solutions, thanks to two fast algorithms: a list-based heuristic and a loading pattern generation method. Both algorithms call a constraint-based subroutine, able to determine quickly if the items already loaded can be reshuffled to accommodate a new object. The second phase improves these preliminary solutions using local search techniques. Results obtained on real data sets are presented. 相似文献