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951.
Liang Liao Yi Pang Liming Ding Frank E. Karasz 《Journal of polymer science. Part A, Polymer chemistry》2003,41(20):3149-3158
A soluble cyano‐substituted poly[(1,3‐phenylene vinylene)‐alt‐(1,4‐phenylene vinylene)] derivative ( 9 ) was synthesized and characterized. Comparison between 9 and its model compound ( 10 ) showed that the chromophore in 9 remained to be well defined as a result of a π‐conjugation interruption at adjacent m‐phenylene units. The attachment of a cyano substituent only at the β position of the vinylene allowed the maximum electronic impact of the cyano group on the optical properties of the poly(p‐phenylene vinylene) material. At a low temperature (?108 or ?198 °C), the vibronic structures of 9 and 10 were partially resolved. The absorption and emission spectra of a film of 9 were less temperature‐dependent than those of a film of 10 , indicating that the former had a lower tendency to aggregate. A light‐emitting diode (LED) based on 9 emitted yellow light (λmax ≈ 578 nm) with an external quantum efficiency of 0.03%. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 3149–3158, 2003 相似文献
952.
V. Ballarini G. Barucca E. Bennici C. F. Pirri C. Ricciardi E. Tresso F. Giorgis 《Physica E: Low-dimensional Systems and Nanostructures》2003,16(3-4):591
All amorphous silicon-nitride planar optical microcavities operating in the visible range have been grown by plasma enhanced chemical vapor deposition. The luminescence intensity of the N-rich silicon-nitride layer from a microcavity with 6 period distributed Bragg reflectors (DBRs) is two order of magnitude higher than that of the luminescent layer without the cavity. Moreover, a strong directionality of the microcavities emission can be observed. Such results can be ascribed to the anisotropic optical density of states induced in the Fabry–Perot structure. The quality factors of the resonators are strictly correlated to the number of periods of the DBRs. 相似文献
953.
G. Lujanienë 《Czechoslovak Journal of Physics》2003,53(1):A57-A65
In order to understand better the way in which radioactive contamination may be transferred from the atmosphere to other ecological compartments it is necessary to obtain information of the deposition mechanisms of radionuclides. Concentration and speciation of 137Cs and 7Be in the atmospheric aerosol and deposition were studied. The mixed deposition velocities of water-soluble and insoluble 137Cs and 7Be were determined. The relation between activity concentrations of insoluble 7Be in the atmosphere and its amount in deposition was observed. It is supposed that in the deposition process of radiocesium the precipitation plays an important role in scavenging of water-soluble radiocesium by falling raindrops, in contrast to insoluble 137Cs where the dry deposition becomes predominant. 相似文献
954.
F. Grunewald B. Kunyavskii D. Nikolova E. Plotkin 《Journal of Mathematical Sciences》2003,116(1):2972-2981
We study two-variable Engel-like relations and identities characterizing finite-dimensional solvable Lie algebras and, conjecturally, finite solvable groups and introduce some invariants of finite groups associated with such relations. Bibliography: 29 titles. 相似文献
955.
The method of nonlinear moments, when used to solve the Boltzmann equation, necessitates the calculation of collision integral
matrix elements. The matrix elements are hard to calculate numerically, especially at large indices. The asymptotics of the
matrix elements are constructed. In terms of the model of pseudopower particle interaction, a formula free of summation is
derived. This makes it possible to find the asymptotic behavior of linear and nonlinear elements when two indices are large.
For an arbitrary interaction cross section, asymptotic expansions of linear and nonlinear matrix elements in one index are
obtained. For Maxwellian molecules, asymptotic formulas are derived for three large indices. 相似文献
956.
O. V. Sizova E. P. Sokolova V. I. Baranovskii D. A. Rozmanov O. A. Tomashenko 《Journal of Structural Chemistry》2004,45(5):762-770
Ab initio MP2 calculations with several basis sets proved the existence of a stable benzonitrile dimer with a planar structure and a short contact between the H atom of one molecule and the N atom of another. The structure is greatly stabilized by attraction between the neighboring oppositely directed dipoles and donor-acceptor interaction between the orbital of the lone electron pair of the N′ atom and the vacant antibonding orbital localized on the C-H bond.Original Russian Text Copyright © 2004 by O. V. Sizova, E. P. Sokolova, V. I. Baranovskii, D. A. Rozmanov, and O. A. Tomashenko__________Translated from Zhurnal Strukturnoi Khimii, Vol. 45, No. 5, pp. 807–815, September–October, 2004. 相似文献
957.
S. Koh K. Konishi Y. Shiraki 《Physica E: Low-dimensional Systems and Nanostructures》2004,21(2-4):440
Self-assembled GeSiC dots stacked on a Ge hut-cluster layer buried in Si have been investigated. The critical thickness for formation of GeSiC dots is reduced owing to the strain fields from the buried hut-clusters. By utilizing the stacked structure, the dot size is decreased and the uniformity is improved. The highest density of the GeSiC dots with stacked structures is 7.4×1010 cm−2, which is six times larger than that of single GeSiC dots. The formation of the self-assembled GeSiC dots is strongly influenced by being stacked with buried Ge dots as well as C incorporation. 相似文献
958.
A previously developed laser spallation technique has been modified to measure the tensile strength of thin film interfaces in-situ at temperatures up to 1100°C. Tensile strengths of Nb/A-plane sapphire, FeCrAl/A-plane sapphire and FeCrAlY/A-plane sapphire were measured up to 950°C. The measured strengths at high temperatures were substantially lower compared with their corresponding strengths at ambient temperature. For example, at 850°C, the interface tensile strength for the Nb/sapphire (151 ± 17 MPa), FeCrAl/sapphire (62 ± 8 MPa) and FeCrAlY/sapphire (82 ± 11 MPa) interface systems were lower by factors of approximately, 3, 5, and 8, respectively, over their corresponding ambient values. These results underscore the importance of using such in-situ measured values under operating conditions as the failure criterion in any life prediction or reliability models of such coated systems where local interface temperature excursions are expected. The results on alloy film interfaces also demonstrate that the presence of Y increases the strength of FeCrAl/Al2O3 interfaces. 相似文献
959.
The fine-structure parameters of a series of configurations of the first ion of indium and the gyromagnetic ratios in intermediate coupling are calculated by a semiempirical method in the single-configuration approximation. 相似文献
960.
The OPAL Collaboration G. Abbiendi et al. 《The European Physical Journal C - Particles and Fields》2003,27(3):311-329
This paper describes topological searches for neutral scalar bosons S0 produced in association with a Z0 boson via the Bjorken process at centre-of-mass energies of 91 GeV and 183-209 GeV. These searches are based on studies of the recoil mass spectrum of
and events and on a search for with and S or photons. They cover the decays of the S0 into an arbitrary combination of hadrons, leptons, photons and invisible particles as well as the possibility that it might
be stable.
No indication for a signal is found in the data and upper limits on the cross section of the Bjorken process are calculated.
Cross-section limits are given in terms of a scale factor k with respect to the Standart Model cross section for the Higgs-strahlung process .
These results can be interpreted in general scenarios independently of the decay modes of the S0. The examples considered here are the production of a single new scalar particle with a decay width smaller than the detector
mass resolution, and for the first time, two scenarios with continuous mass distributions, due to a single very broad state
or several states close in mass.
Received: 13 March 2002 / Published online: 19 February 2003 相似文献