Regio- and Stereoselective Addition of Selenium Dichloride to Alkyl Propiolates

Russian Journal of Organic Chemistry - The reaction of selenium dichloride with methyl and ethyl propiolates leads to formation of anti-Markovnikov adducts. The regio- and stereoselective synthesis...     

Experimental investigation on the thermophysical properties of beryllium oxide-based nanofluid and nano-enhanced phase change material

Journal of Thermal Analysis and Calorimetry - Low thermal conductivity is a primary issue in the development of efficient heat transfer fluids and materials required for the thermal management of...     

Synthesis of Substituted Aminopyrimidines as Novel Promising Tyrosine Kinase Inhibitors

Russian Journal of Organic Chemistry - A procedure has been proposed for the synthesis of a series of substituted N-(1,3-thiazol-2-yl)-pyrimidin-2-amines and N-(pyrimidin-2-yl)thioureas by...     

On Neyman–Pearson minimax detection of Poisson process intensity

The problem of the minimax testing of the Poisson process intensity \({\mathbf{s}}\) is considered. For a given intensity \({\mathbf{p}}\) and a set \(\mathcal{Q}\), the minimax testing of the simple hypothesis \(H_{0}: {\mathbf{s}} = {\mathbf{p}}\) against the composite alternative \(H_{1}: {\mathbf{s}} = {\mathbf{q}},\,{\mathbf{q}} \in \mathcal{Q}\) is investigated. The case, when the 1-st kind error probability \(\alpha \) is fixed and we are interested in the minimal possible 2-nd kind error probability \(\beta ({\mathbf{p}},\mathcal{Q})\), is considered. What is the maximal set \(\mathcal{Q}\), which can be replaced by an intensity \({\mathbf{q}} \in \mathcal{Q}\) without any loss of testing performance? In the asymptotic case (\(T\rightarrow \infty \)) that maximal set \(\mathcal{Q}\) is described.

     

A simple,rapid and sensitive method based on modified multiwalled carbon nanotube for preconcentration and determination of lead ions in aqueous media in natural pHs

In this study, multiwalled carbon nanotube (MWCNT) was modified by the pyridine group using a silane agent and characterized by infrared spectroscopy (IR), thermal analysis (TG/DTA), and elemental analysis (CHN) and scanning electron microscopy (SEM). The application of this sorbent was investigated in determination of lead ions in aqueous samples, using flame atomic absorption spectrometry (FAAS). Through this study, different parameters such as pH and sample flow rate on adsorption process and eluent concentration, volume and flow rate were optimized. The limit of detection (LOD), the relative standard deviation and the recovery of the method were 2 ng mL^?1, 1.3% and 99.7%, respectively. Two standard reference materials (NIST 1571 and NIST 1572) were used to verify accuracy of this method. Finally, the sorbent was successfully applied for extraction and determination of low levels of Pb(II) ions in aqueous samples.     

Synthesis and Anticancer Activity of Certain Selenophene Derivatives

Russian Journal of Organic Chemistry - Selenopheno[2,3-d]pyrimidine- and selenopheno[2,3-d][1,2,3]triazine-containing compounds were synthesized starting from...     

A novel synthesis route for brookite rich titanium dioxide photocatalyst involving organic intermediate

Journal of Sol-Gel Science and Technology - High temperature stable brookite rich titanium dioxide of average crystallite size 20&;nbsp;nm has been prepared by a novel aqueous sol–gel...     

Optimized spacer layer thickness for plasmonic-induced enhancement of photocurrent in a-Si:H

Journal of Nanoparticle Research - Plasmonic interfaces consisting of silver nanoparticles of different sizes (50–100&;nbsp;nm) have been processed by the self-assembled dewetting...     

Formation and pharmacological activity of silicon—chitosan-containing glycerohydrogels obtained by biomimetic mineralization

The biomimetic sol—gel synthesis of silicon—chitosan-containing glycerohydrogels was carried out using silicon tetraglycerolate as a precursor. It was found that chitosan accelerates gel formation in weakly acidic media. In more acidic media, the kinetics of the process changes according to the curve with a maximum, which can be attributed to different mechanisms of silanol condensation before and after the isoelectric point. The investigated silicon—chitosan-containing glycerohydrogels exhibit antibacterial, anti-inflammatory, and wound healing activity. The synthesized hybrid glycerohydrogels are promising materials for biomedical applications.