On Jordan Biderivations of Triangular Matrix Rings

Let $R$ and $S$ be rings with identity, $M$ be a unitary $(R,S)$-bimodule and $T=\left(\begin{array}{cc}R & M \\ 0 & S\end{array}\right) $ be the upper triangular matrix ring determined by $R$, $S$ and $M$. In this paper we prove that under certain conditions a Jordan biderivation of an upper triangular matrix ring $T$ is a biderivation of $T$.     

Role of hypaphorine in the toxicity of Astragalus lusitanicus

Hypaphorine, an alpha-N,N,N-trimethyltryptophan betaine, was isolated, for the first time, from Astragalus lusitanicus Lam. (Fabaceae), a plant highly toxic for lambs and goats. This alkaloid was characterized by NMR and MS analysis. Hypaphorine was previously reported to be a convulsive poison. To confirm the toxicity, it was synthesized and tested in goats. Hypaphorine was shown to be non-toxic for goats even at a high dose of 2 g kg(-1) by oral administration.     

Synthesis and structure determination of a 2D open-framework zincophosphate templated by cyclohexylamine molecules

The synthesis and crystal structure of a new bidimensional zincophosphate (ZnPO) are reported. Zn₂(HPO₄)₂Cl₂·2NC₆H₁₄ crystallizes in the monoclinic space group P2₁/a (n°14) with a = 8.830(3) Å, b = 9.278(3) Å, c = 26.950(9) Å, = 90.74(3)°, V = 2207.7(1) ų and Z = 4. This new material consists of a 2D open-framework of corner sharing ZnO₃Cl and PO₃OH tetrahedra alternating with planes of protonated cyclohexylamine molecules (NC₆H₁₄)⁺. The organic molecules are interconnected to the framework through hydrogen bonds.     

A New Thiophen Acetylene from Artemisia Absinthium

The investigation of the dried roots of A. absinthium afforded two known lignans of tetrahydrofuran skeleton, sesamin and yangambin, one known coumarin, 6‐methoxy‐7,8‐methylenedioxy coumarin and a new thiophen acetylene. The structures were elucidated by spectroscopic methods.     

Quantifying of Quantum Correlations in an Optomechanical System with Cross-Kerr Interaction

Journal of Russian Laser Research - Under the cross-Kerr effect, we investigate two different forms of quantum correlations in an optomechanical system consisting of a mechanical mode coupled with...     

One Pot Synthesis of Bisphosphonate Esters: A Way to Synthesize Tetraphosphonate Esters

Abstract

Several methods for the preparation of symmetrical bisphosphonates of general type (RO)₂P(O)(R′OH)P(O)(OR)₂, have been developed, and investigated for their pharmacological. Pharmacological screening of these bisphosphonates have shown that these compounds have potent cardiovascular activity and are. potentialy useful in the treatment of hypertension. In this work we described of new method “one pot” for the synthesis of hydroxy bis and tetra phosphonates (I, II, III and IV).     

Application Des Réseaux de Neurones Avec la Régularisation Bayésienne pour la Modélisation de la Synthèse de l’hydroxyapatite Élaborée à Partir du Carbonate de Calcium et de L’acide Phosphorique

We have used a new, robust model mapping technique—a Bayesian-regularized neural network—to develop a quantitative relationships model for the synthesis of the phosphocalcic hydroxyapatite by precipitation from a calcium carbonate solution and a phosphoric acid solution. This model was preformed by using a set of factors consisting on the pH of reactional medium, the Ca/P molar ratio of the reagents, reaction time, and the initial concentration of calcium. The results show that the method is robust and gives satisfied results. The Levenberg–Marquardt's algorithm implemented in the neural network Matlab's toolbox allowed a drastic improvement of the performance of the model. Very satisfactory results are then obtained by testing the validity by cross-validation technique.

We have also turned our interests to the explanatory capacities of our methodology to explore the relative contribution and/or the contribution profile of the input factors by using Garson weight portioning method.