Effect of precipitate and complex formation on the determination of silver by atomic-absorption spectroscopy

In the determination of silver, by atomic-absorption spectroscopy, the presence of small amounts of precipitating agents in the solution to be analysed can result in significant changes in the absorbance at 328.1 nm. The controlling factor is the physical form of the precipitated material. The presence of some complexing agents also causes variable absorption readings, and with ligands such as thiosulphate and cyanide ions the interference can be attributed to secondary reactions associated with the sparingly soluble compounds formed under specific conditions.     

Equilibrium effects in the determination of tantalum by atomic-absorption spectroscopy

The effect of solution variables on the efficiency of tantalum atom formation in hot flames is considered in terms of competing equilibria.     

Determination of mixed-mode stress intensity factors, fracture toughness, and crack turning angle for anisotropic foam material

A numerical and experimental investigation for determining mixed-mode stress intensity factors, fracture toughness, and crack turning angle for BX-265 foam insulation material, used by NASA to insulate the external tank (ET) for the space shuttle, is presented. BX-265 foam is a type of spray-on foam insulation (SOFI), similar to the material used to insulate attics in residential construction. This cellular material is a good insulator and is very lightweight. Breakup of segments of this foam insulation on the shuttle ET impacting the shuttle thermal protection tiles during liftoff is believed to have caused the space shuttle Columbia failure during re-entry. NASA engineers are interested in understanding the processes that govern the breakup/fracture of this material from the shuttle ET. The foam is anisotropic in nature and the required stress and fracture mechanics analysis must include the effects of the direction dependence on material properties. Material testing at NASA Marshall Space Flight Center (MSFC) has indicated that the foam can be modeled as a transversely isotropic material. As a first step toward understanding the fracture mechanics of this material, we present a general theoretical and numerical framework for computing stress intensity factors (SIFs), under mixed-mode loading conditions, taking into account the material anisotropy. We present SIFs for middle tension – M(T) – test specimens, using 3D finite element stress analysis (ANSYS) and FRANC3D fracture analysis software. SIF values are presented for a range of foam material orientations. Mode I fracture toughness of the material is determined based on the SIF value at failure load. We also present crack turning angles for anisotropic foam material under mixed-mode loading. The results represent a quantitative basis for evaluating the strength and fracture properties of anisotropic foam insulation material.     

Three loop gauge β-function for the most general single gauge-coupling theory

We calculate the three loop contribution to the β-function of the gauge coupling constant in a general, anomaly-free, renormalisable gauge field theory involving a single gauge coupling using the background field method in the scheme.     

Integrability test of a higher-order (2+1)-dimensional KdV-type equation

The so-called KdV6 equation has recently generated much interest. Here we show that a recently considered (2+1)-dimensional extension of this equation is in fact nonintegrable.     

Size and sequence and the volume change of protein folding

The application of hydrostatic pressure generally leads to protein unfolding, implying, in accordance with Le Chatelier's principle, that the unfolded state has a smaller molar volume than the folded state. However, the origin of the volume change upon unfolding, ΔV(u), has yet to be determined. We have examined systematically the effects of protein size and sequence on the value of ΔV(u) using as a model system a series of deletion variants of the ankyrin repeat domain of the Notch receptor. The results provide strong evidence in support of the notion that the major contributing factor to pressure effects on proteins is their imperfect internal packing in the folded state. These packing defects appear to be specifically localized in the 3D structure, in contrast to the uniformly distributed effects of temperature and denaturants that depend upon hydration of exposed surface area upon unfolding. Given its local nature, the extent to which pressure globally affects protein structure can inform on the degree of cooperativity and long-range coupling intrinsic to the folded state. We also show that the energetics of the protein's conformations can significantly modulate their volumetric properties, providing further insight into protein stability.