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21.
Francesco Napoli Dr. Mario Chiesa Dr. Elio Giamello Prof. Gloria Preda Dr. Cristiana Di Valentin Dr. Gianfranco Pacchioni Prof. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(23):6776-6785
The formation of O2? radical anions by contact of O2 molecules with a Na pre‐covered MgO surface is studied by a combined EPR and quantum chemical approach. Na atoms deposited on polycrystalline MgO samples are brought into contact with O2. The typical EPR signal of isolated Na atoms disappears when the reaction with O2 takes place and new paramagnetic species are observed, which are attributed to different surface‐stabilised O2? radicals. Hyperfine sublevel correlation (HYSCORE) spectroscopy allows the superhyperfine interaction tensor of O2?Na+ species to be determined, demonstrating the direct coordination of the O2? adsorbate to surface Na+ cations. DFT calculations enable the structural details of the formed species to be determined. Matrix‐isolated alkali superoxides are used as a standard to enable comparison of the formed species, revealing important and unexpected contributions of the MgO matrix in determining the electronic structure of the surface‐stabilised Na+? O2? complexes. 相似文献
22.
23.
Dr. Wei Liu Dr. Paramaconi Rodriguez Dr. Lars Borchardt Dr. Annette Foelske Dr. Jipei Yuan Anne‐Kristin Herrmann Dr. Dorin Geiger Dr. Zhikun Zheng Prof. Stefan Kaskel Dr. Nikolai Gaponik Dr. Rüdiger Kötz Prof. Thomas J. Schmidt Prof. Alexander Eychmüller 《Angewandte Chemie (International ed. in English)》2013,52(37):9849-9852
24.
Ciprian Preda 《Journal of Mathematical Analysis and Applications》2007,332(1):727-734
Following the Perron-Ta Li line of results, we give a characterization of the uniform exponential dichotomy property for the abstract continuous-time evolution families using a discrete-time approach. 相似文献
25.
We introduce pretty clean modules, extending the notion of clean modules by Dress, and show that pretty clean modules are sequentially Cohen–Macaulay. We also extend a theorem of Dress on shellable simplicial complexes to multicomplexes. 相似文献
26.
Jorgensen and Pedersen have proven that a certain fractal measure ν has no infinite set of complex exponentials which form an orthonormal set in L2(ν). We prove that any fractal measure μ obtained from an affine iterated function system possesses a sequence of complex exponentials which forms a Riesz basic sequence, or more generally a Bessel sequence, in L2(μ) such that the frequencies have positive Beurling dimension. 相似文献
27.
Iulian Preda Leonardo Soriano Daniel Díaz‐Fernández Guillermo Domínguez‐Cañizares Alejandro Gutiérrez Germán R. Castro Jesús Chaboy 《Journal of synchrotron radiation》2013,20(4):635-640
This work reports an X‐ray absorption near‐edge structure (XANES) spectroscopy study at the Ni K‐edge in the early stages of growth of NiO on non‐ordered SiO2, Al2O3 and MgO thin films substrates. Two different coverages of NiO on the substrates have been studied. The analysis of the XANES region shows that for high coverages (80 Eq‐ML) the spectra are similar to that of bulk NiO, being identical for all substrates. In contrast, for low coverages (1 Eq‐ML) the spectra differ from that of large coverages indicating that the local order around Ni is limited to the first two coordination shells. In addition, the results also suggest the formation of cross‐linking bonds Ni—O—M (M = Si, Al, Mg) at the interface. 相似文献
28.
The exponential stability property of an evolutionary process is characterized in terms of the existence of some functionals
on certain function spaces. Thus are generalized some well-known results obtained by Datko, Rolewicz, Littman and Van Neerven. 相似文献
29.
Vasile Preda 《Journal of Mathematical Analysis and Applications》2003,288(2):365-382
Necessary and sufficient optimality conditions are obtained for a nonlinear fractional multiple objective programming problem involving η-semidifferentiable functions. Also, a general dual is formulated and duality results are proved using concepts of generalized semilocally preinvex functions. 相似文献
30.
Integrating logical constraints into optimal control problems is not an easy task. In fact, optimal control problems are usually continuous while logical constraints are naturally expressed by integer (binary) variables. In this article we are interested is a particular form of an LQR optimal control problem: the energy (control L2 norm) is to be minimized, system dynamic is linear and logical constraints on the control use are to be fulfilled. Even if the starting continuous problem is not a complicated one, difficulties arise when integrating the additional logical constraints. First, we will present two different ways of modeling the problem, both of them leading us to Mixed Integer Problems. Furthermore, algorithms (Generalized Outer Approximation, Benders Decomposition and Branch and Cut) are applied on each model and results analyzed. We also present a Benders Decomposition algorithm variant that is adapted to our problem (taking into account its particular form) and we will conclude by looking at the optimal solutions obtained in an interesting physical example: the harmonic spring. 相似文献