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121.
Irina Popescu Marcel Ionel Popa Gabrielle Charlotte Chitanu 《Macromolecular Symposia》2008,272(1):125-131
Summary: The formation of polyelectrolyte complexes by interaction between chitosan and maleic acid copolymers as strong/weak dibasic polyanions was investigated. The interaction between the sodium salt of maleic acid copolymers with styrene or vinyl acetate and the chitosan hydrochloride in aqueous solution was followed by potentiometric, conductometric and turbidimetric titration. The effect of the added low molecular salt on the complex formation was also investigated. The precipitated complexes were analyzed by FTIR spectroscopy and TG analysis. Preliminary layer-by-layer deposition experiments were performed to obtain thin films. 相似文献
122.
Gheorghe Ilia Smaranda Iliescu Adriana Popa Aurelia Visa Bianca Maranescu Vasile Simulescu 《高分子科学杂志,A辑:纯化学与应用化学》2016,53(1):49-54
This paper presents for the first time the synthesis of poly(alkylene-H-phosphonate)s by one-pot tandem reaction of hypophosphorous acid and ethylene glycol. Zirconium oxychloride was used as esterification catalyst, Nickel vinylphosphonate, Nickel sulfate, Nickel chloride hexahydrate were used as transfer hydrogenation catalyst. Nickel vinylphosphonate was synthesized in our laboratory and used for the first time as catalyst in this process. The compounds were characterized by 1H-NMR, 13C-NMR and 31P-NMR spectroscopy. Molar masses were determined by SEC-MALLS technique and depend on the catalyst used. The obtained poly(alkylene-H-phosphonate)s have molar masses between 1.50 and 11.85 kDa, higher than those obtained by other methods mentioned in the literature. 相似文献
123.
Vera Balan Ivona Andreea Petrache Marcel Ionel Popa Maria Butnaru Eugen Barbu John Tsibouklis Liliana Verestiuc 《Journal of nanoparticle research》2012,14(2):730
Haemocompatible biotinylated superparamagnetic nanoparticles (size range 300–700 nm) have been obtained by coating magnetite
through ionic gelation with a mixture of chitosan and sodium tripolyphosphate, followed by subsequent functionalisation with
biotin. The evaluations of their magnetic properties together with haemocompatibility tests have shown that these nanoparticles
exhibit the prerequisite behaviour for use in magnetic field–assisted separations within biological systems. 相似文献
124.
Dumitru Popa 《Rendiconti del Circolo Matematico di Palermo》2012,61(3):307-319
We introduce the notion of multilinear nuclear operator with respect to a partition and extend Grothendieck??s characterizations of nuclear linear operators into $l_{1},$ resp. $L_{1}( \mu ),$ in this new setting. We give the necessary and sufficient conditions for a natural operator to be nuclear with respect to a partition. 相似文献
125.
Acrylate functionalized ionic liquids based on tetraalkylammonium salts with terminal acrylates- and methylacrylates were synthesized. Melting points and ionic conductivity of twenty compounds in six groups were determined. Within one group the effect of three different counterions was investigated and discussed. The groups differ in cationic structure elements because of their functional groups such as acrylate and methacrylate, alkyl residues at the nitrogen and number of quaternary ammonium atoms within the organic cation. The effect of these cationic structure elements has been examined concerning the compiled parameters with a view to qualifying them as components for solid state electrolytes. The newly synthesized ionic liquids were characterized by NMR and FTIR analysis. The exchange of halide ions like bromide as counter ions to weakly coordinating [PF?]?, [OTf]? or [TFSI]? reduces the melting points significantly and leads to an ion conductivity of about 10?? S/cm at room temperature. In the case of the dicationic ionic liquid, an ion conductivity of about 10?3 S/cm was observed. 相似文献
126.
Razvan Stefan Petru Pascuta Adriana Popa Oana Raita Emil Indrea Eugen Culea 《Journal of Physics and Chemistry of Solids》2012,73(2):221-226
Glasses in the system xFe2O3·(100?x) [45ZnO·55B2O3] (0≤x≤10 mol%) have been prepared by melting at 1200 °C and rapidly cooling at room temperature. The obtained samples were submitted to an additional thermal treatment at 570 °C for 12 h in order to relax the glass structure as well as to improve the local order. The as cast and heat treated samples were investigated using X-ray diffraction (XRD) and electron paramagnetic resonance (EPR) measurements. The XRD patterns of all the studied samples show their vitreous nature. Structural modifications occurring in the heat treated samples compared to the untreated ones have been pointed out. EPR spectra of untreated and heat treated samples revealed resonance absorptions centered at g≈2.0, g≈4.3 and g≈6.4. The compositional variation of the line intensity and linewidth of the absorptions from g≈4.3 and g≈2.0 have been interpreted in terms of the variation in the concentration of the Fe3+ ions and the interaction between the iron ions. The EPR spectra of the untreated samples containing 5 mol% Fe2O3 have been studied at different temperatures (110–290 K). The line intensity of the resonance signals decreases with increase in temperature whereas the linewidth is found to be independent of temperature. It was also found that the temperature variation of reciprocal line intensity obeys the Boltzmann law. 相似文献
127.
Daniel Crespy Kathrin Friedemann Ana‐Maria Popa 《Macromolecular rapid communications》2012,33(23):1978-1995
Solution‐, melt‐, and co‐axial electrospinning are well‐known methods for producing nano‐ and microfibers. The electrospinning of colloids (or colloid‐electrospinning) is a new field that offers the possibility to elaborate multicompartment nanomaterials. However, the presence of colloids in the electrospinning feed further complicates theoretical predictions in a system that is dependent on chemical, physical, and process parameters. Herein, we give a summary of recent important results and discuss the perspectives of electrospinning of colloids for the synthesis and characterization of multicompartment fibers. 相似文献
128.
Yu. M. Chumakov Yu. A. Simonov M. D. Mazus D. P. Popa P. F. Vlad 《Crystallography Reports》2000,45(2):244-247
The crystal structure of 11-hydroxy-7-oxodrim-8(9)-ene is determined. The crystals are monoclinic. The unit cell parameters
are a = 16.716(4) Å, b = 11.052(3) Å, c = 7.542(3) Å, γ = 76.11°, Z = 4, μ = 1.476 cm−1, ρcalcd = 1.147 g/cm3, and space group P21. The structure is solved by the direct method and refined by the least-squares procedure to R = 0.045. There are two molecules of 11-hydroxy-7-oxodrim-8(9)-ene in the asymmetric unit. Both molecules have the same conformation
of the skeleton and can be described as rotomers differing in orientation of the OH groups with respect to the skeleton. In
both molecules, the cyclohexane rings have a usual chair conformation. In the crystal, two independent molecules are linked
by a hydrogen bond. The molecular pairs related by the twofold screw axes are linked by hydrogen bonds into helices running
along the z-axis of the crystal. The helices are bound through van der Waals interactions.
__________
Translated from Kristallografiya, Vol. 45, No. 2, 2000, pp. 275–278.
Original Russian Text Copyright ? 2000 by Chumakov, Simonov, Mazus, Popa, Vlad.
Deceased. 相似文献
129.
Since the late seventies, the search for new molecular receptors has been constant in perfecting the affinity and selectivity of recognition in different media. At present, a renewed interest in (host:guest) chemistry focuses on the molecular detection of specific targets such as biological, pollutant, toxic or explosive species. This review of triphenylene-based receptors outlines their recent contribution to molecular recognition. Two main structural approaches were investigated to transform a simple triphenylene moiety into a host for neutral aromatic compounds or cations, by tailoring multivalent molecules provided with or without a flatten cavity. The properties of different receptors are presented along with the latest synthetic methods to prepare high-value triphenylenes and the perspectives in the field of sensing. In addition, the role of functionalized triphenylenes in extended (host:guest) systems is illustrated by the main examples of discotic liquid crystals and porous coordination polymers involving this polyaromatic compound. 相似文献
130.
Daniel D. Stöbener Dorian Donath Marie Weinhart 《Journal of polymer science. Part A, Polymer chemistry》2018,56(21):2496-2504
Low-molecular weight linear poly(glycidyl ether)s are typically synthesized via the “classical,” oxy-anionic ring-opening polymerization (ROP) of glycidyl ether monomers at elevated temperatures. To reduce reaction times, a fast process was developed to synthesize oligo(glycidyl ether)s (OGEs) in bulk at a gram-scale utilizing microwave heating. Well-defined thermoresponsive copolymers comprising glycidyl methyl ether and ethyl glycidyl ether with molecular weights of up to 3 kDa were synthesized via microwave-assisted ROP with reaction times of approximately 10 min. The fast reaction kinetics were attributed to the rapid and uniform heating and high temperatures reached during the reaction. Consequently, no significant microwave-specific acceleration of the oxy-anionic ROP was observed. The temperature-triggered phase transition of the OGEs in aqueous solution revealed cloud point temperatures that are highly dependent on the OGE molecular weight, concentration, and comonomer composition, which extends previously reported data. Furthermore, oligo(glycidyl ether) acrylates (OGEAs) with reactive, functional end groups were directly accessible via in situ quenching of the anionic, microwave-assisted ROP with acrylic acid chloride. The obtained thermoresponsive OGEA macromonomers represent a promising material for the functionalization of surfaces via radical grafting methods to obtain functional, thermoresponsive coatings with potential application in cell culture. © 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2018 , 56, 2496–2504 相似文献