Line shapes in intramolecular penning ionization

Discrepancies in the observed lineshapes and shifts of the resonance lines from Intramolecular Penning Ionization in aromates seeded into argon measured by two different groups are attributed to the different operating conditions in the molecular beam expansions used. Results are reported that clarify the influence of the premixing and expansion parameters on the observed structures.     

Electron energy loss spectra of dye vapors

Electron energy loss studies of POPOP andp-terphenyl in the vapor phase at an incident electron energy of 25 eV have been performed. The spectra covering an energy loss between 0 and 9 eV revealed a considerable initial triplet population under electron impact excitation. The implications for electron-beam pumped vapor phase dye lasers are discussed.     

Hydrogen atom transfer in indole clusters: formation dynamics of , n = 1-6, fragments

The H atom transfer reaction in electronically excited indole(NH ₃ ) _n clusters is studied in pump-probe experiments with femtosecond laser pulses. By applying different probe photon energies we are able to detect the dissociation products (NH ₃ ) _{n - 1} NH ₄ for n = 1-6. Furthermore we show that the analysis of the corresponding ion signals is not distorted by contributions from larger cluster ions due to evaporation of NH ₃ molecules. The formation times of the products are ca. 140ps for n = 2-4 and about 80ps for n = 5, 6. Received 30 April 2002 / Received in final form 29 May 2002 Published online 13 September 2002     

A heuristic solution framework for the resource constrained (multi-)project scheduling problem with sequence-dependent transfer times

We consider the problem of scheduling multiple projects subject to joint resource constraints. Most approaches proposed in the literature so far are based on the unrealistic assumption that resources can be transferred from one project to the other without any expense in time or cost. In order to contribute to closing this gap to reality, we generalise the multi-project scheduling problem by additionally including sequence- and resource-dependent transfer times, which represent setup activities necessary when a resource is removed from one project and reassigned to another (or from one job to another within the same project). In this paper, we define the modified resource constrained multi-project scheduling problem with transfer times (called RCMPSPTT), which aims at minimising the multi-project duration for the single-project approach or the mean project duration for the multi-project approach. We formulate both perspectives as an integer linear program, propose priority rule based solution procedures and present results of comprehensive computational experiments. Provided that the combination of scheduling scheme and priority rules is chosen appropriately, the procedures obtain good results. In particular, resource oriented priority rules are identified to be successful.     

Disentangling the physical contributions to the electrical resistance in magnetic domain walls: a multiscale study

We analyze the origin of the electrical resistance arising in domain walls of perpendicularly magnetized materials by considering a superposition of anisotropic magnetoresistance and the resistance implied by the magnetization chirality. The domain wall profiles of L1(0)-FePd and L1(0)-FePt are determined by micromagnetic simulations based on which we perform first-principles calculations to quantify electron transport through the core and closure region of the walls. The wall resistance, being twice as high in L1(0)-FePd than in L1(0)-FePt, is found to be clearly dominated in both cases by a high gradient of magnetization rotation, which agrees well with experimental observations.     

Exciton dissociation in conjugated polymers

In conjugated polymers, a majority of photogenerated charges form metastable geminate pairs (GPs), of which only some fraction can dissociate completely. Both the yield of GP photogeneration and the probability of further dissociation of GPs into free charges depend upon an external electric field. In the present article we discuss several experimental methods to detect the existence of geminate pairs such as delayed field collection of charges, field quenching of fluorescence, and field-assisted photoinduced optical absorption. It is shown that the field dependences of the exciton dissociation into GPs and of the free carrier photogeneration yield are rather similar. This is in contrast with the traditional Onsager theory, which assumes field-independent yield of primary photoionization and disregards the field dependence of the initial separations between carriers in GPs.