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121.
Fengbo Liu Hai Yang Dongdong Sun Fang Gao Xiongzhi Zhang Zhiyong Zhao Xie Han Simin Liu 《Chemical science》2022,13(24):7247
Aqueous room temperature phosphorescence (aRTP) from purely organic materials has been intriguing but challenging. In this article, we demonstrated that the red aRTP emission of 2Br–NDI, a water-soluble 4,9-dibromonaphthalene diimide derivative as a chloride salt, could be modulated by anion–π and intermolecular electronic coupling interactions in water. Specifically, the rarely reported stabilization of anion–π interactions in water between Cl− and the 2Br–NDI core was experimentally evidenced by an anion–π induced long-lived emission (λAnion–π) of 2Br–NDI, acting as a competitive decay pathway against the intrinsic red aRTP emission (λPhos) of 2Br–NDI. In the initial expectation of enhancing the aRTP of 2Br–NDI by inclusion complexation with macrocyclic cucurbit[n]urils (CB[n]s, n = 7, 8, 10), we surprisingly found that the exclusion complexation between CB[8] and 2Br–NDI unconventionally endowed the complex with the strongest and longest-lived aRTP due to the strong intermolecular electronic coupling between the nπ* orbit on the carbonyl rims of CB[8] and the ππ* orbit on 2Br–NDI in water. It is anticipated that these intriguing findings may inspire and expand the exploration of aqueous anion–π recognition and CB[n]-based aRTP materials.The aqueous room temperature phosphorescence of 2Br–NDI is modulated by long-lived-emitting anion–π interactions and tremendously enhanced by intermolecular electronic coupling interactions with the ISC-boosting carbonyl rims of CB[8] host. 相似文献
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在无网格法中,离散节点之间的相互联系由节点形函数影响域的大小确定,因此形函数影响域的大小对无网格法的计算精度有着直接和重要的影响.但由于无网格形函数的形式较为复杂,目前形函数影响域大小的选择仍然缺乏系统的理论依据,通常在实际计算中仍凭借经验进行选取,难以保证计算精度.卷积神经网络是一类机器学习方法,其感受野与无网格形函数的影响域具有内在相似性,因此在形函数影响域选择方面有很好的适用性.基于该特性,论文通过引入卷积神经网络对无网格形函数的影响域进行了优化选择.首先,针对感受野和影响域的匹配关系,分析了卷积神经网络的结构设计和超参数选择,提出了一种无网格法内禀卷积神经网络结构的设计方法;然后依托该网络结构设计方法,建立了对无网格形函数影响域和数值解分别优化或同时优化的卷积神经网络.文中通过算例系统验证了所提无网格法内禀卷积神经网络对形函数影响域选择和计算结果的优化效应. 相似文献
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Seven thousand five hundred holograms are stored in 15 locations within a bar of Zn:Mn:Fe:LiNbO3, using a signal beam that propagates along the long axis of the bar. At each location, angular multiplexing is performed with the reference light changing its orientation in two-dimensional space. The same angular multiplexing is repeated at different locations along the long axis of the Zn:Mn:Fe:LiNbO3 bar. When operating as a holographic correlator, an input image is compared simultaneously with the records stored in all locations within the bar and is recalled accurately. 相似文献
126.
Rhodium‐Catalyzed Synthesis of 4‐Bromo‐1,2‐dihydroisoquinolines: Access to Bromonium Ylides by the Intramolecular Reaction of a Benzyl Bromide and an α‐Imino Carbene
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Jun He Yinping Shi Wanli Cheng Zengming Man Dongdong Yang Prof. Dr. Chuan‐Ying Li 《Angewandte Chemie (International ed. in English)》2016,55(14):4557-4561
Highly functionalized 4‐bromo‐1,2‐dihydroisoquinolines were synthesized from readily available 4‐(2‐(bromomethyl)phenyl)‐1‐sulfonyl‐1,2,3‐triazoles. A bromonium ylide is proposed as the key intermediate, which can be formed by the intramolecular nucleophilic attack of the benzyl bromide on the α‐imino rhodium carbene formed in the presence of the rhodium catalyst. 相似文献
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Niu HT Su D Jiang X Yang W Yin Z He J Cheng JP 《Organic & biomolecular chemistry》2008,6(17):3038-3040
The nucleophilic nature of cyanide is used to create a simple, sensitive, and highly effective sensor, 2-(trifluoroacetylamino)anthraquinone (2-TFAQ), for the easy "naked-eye" detection of very low concentrations of cyanide in an aqueous environment. 相似文献
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将磁性粒子与形状记忆聚合物复合,通过设计渐变式构型构筑了梯度形状磁性材料,并与润滑涂层相结合,制备了一种磁性润滑表面.在磁性梯度的作用下,超顺磁液滴在表面上能够自发定向运动.借助于材料形状记忆效应对表面区域形态进行可逆调控,进一步展示了超顺磁液滴自发定向运动过程中的启停开关式控制,实现了将液滴定向自发运输与启停控制相结合.考察了磁性粒子含量对材料形状记忆性能的影响,以及区域形态调控尺寸与液滴滑动性能间的相互关系.机理分析进一步阐明磁场梯度提供的定向驱动力促使液滴定向自发输运,表面区域形态控制的可逆调控则可以在液滴运动过程中增加/消除黏滞阻力,基于两种因素的协同作用,可以实现对超顺磁液滴运动的智能操控. 相似文献