The nature of phase separation in binary oxide melts and glasses. III. Borate and germanate systems

A review of immiscibility data in binary borate and germanate systems was performed in order to compare miscibility gap consolute temperatures with ionic potentials and radii of their associated cations. The trends obtained demonstrate that a selective solution mechanism similar to the one identified for the binary silicate systems is present in the borate and germanate binaries. More importantly, the borate and germanate immiscibility data permitted the identification of a new group of cations depicting an immiscibility behaviour different from the ones identified in binary silicate systems. The new group involves highly polarizable cations possessing a lone pair of electrons. This lone pair of electrons together with oxygen bonded by strong covalent bonds to modifier cations provides efficient shielding to the cations' nuclei which considerably reduces the coulombic repulsions and produces miscibility gaps with very low consolute temperatures. A new group of cations having an homogenizing effect on melts (i.e. a capacity to make immiscible melts single phase) is thus reported. Experimental and spectroscopic data suggest that miscibility gaps associated with cations having a lone pair of electrons exist in binary silicate systems such as TlO_1/2-SiO₂, PbO-SiO₂, SnO-SiO₂ and Bi₂O₃-SiO₂. The consolute temperature of their miscibility gaps is expected to be relatively low and metastable.     

Assessing and predicting changes in vegetation cover associated with military land use activities using field monitoring data at Fort Hood, Texas

We assessed short-term impacts of changes in military training load on vegetative cover at Fort Hood, TX. From 1989 to 1995, permanent field transects were monitored for vegetative cover and land use disturbance using standard army monitoring methods [Land Condition Trend Analysis (LCTA)]. Land use intensity (training load) was quantified and used to develop a model to predict future vegetation cover values. We found that standard Army monitoring methods detected changes in installation resources associated with changes in training load. Increased training loads were associated with increased measures of disturbance, decreased ground cover, and decreased aerial vegetative cover. We found that the spatial pattern of disturbance and vegetation cover remained relatively constant over the study period despite large variations in overall training load. Our model used the consistency in spatial cover patterns over time and the strong relationship between training load and vegetation cover to predict the impact of future training loads on vegetation.     

Enhanced multi‐objective optimization of a dimpled channel through evolutionary algorithms and multiple surrogate methods

Using a multi‐objective evolutionary algorithm (MOEA) and enhanced surrogate approximations, the present study demonstrates the numerical analysis and optimization of staggered‐dimple channels. Two surrogates, the response surface approximation (RSA) model and the Kriging (KRG) model, are applied in light of the surrogate fidelity of the approximate analysis. An enhanced Pareto‐optimal front is obtained by performing local resampling of the Pareto‐optimal front, which provides relatively more accurate Pareto‐optimal solutions in the design space for each surrogate model. Three dimensionless design variables are selected, which are related to geometric parameters, namely, the channel height, dimple print diameter, dimple spacing, and dimple depth. Two objective functions are selected that are related to the heat transfer and pressure loss, respectively. The objective‐function values are numerically evaluated through Reynolds‐averaged Navier–Stokes analysis at the design points that are selected through the Latin hypercube sampling method. Using these numerical simulations two surrogates, viz, the RSA and Kriging models, are constructed for each objective function and a hybrid MOEA is applied to obtain the Pareto‐optimal front. For the particular implementation of surrogate models, it is observed that Pareto‐optimal predictions of the RSA model are better than those of the KRG model, whereas the KRG model predicts equally well at the off‐Pareto‐region (region away from the Pareto‐optimal solutions), which is not the case with the RSA model. The local resampling of the Pareto‐optimal front increases the fidelity of the approximate solutions near the Pareto‐optimal region. The ratios of the channel height to the dimple print diameter and of the dimple print diameter to the dimple pitch are found to be more sensitive along the Pareto‐optimal front than the ratio of the dimple depth to the print diameter. The decrease of the ratio of the channel height to the dimple diameter and the increase of the ratio of the dimple print diameter to the pitch lead to greater heat transfer at the expense of the pressure loss, whereas the ratio of the dimple depth to the print diameter is rather insensitive to Pareto‐optimal solutions. Pareto‐optimal solutions at higher values of the Nusselt number are associated with higher values of the pressure loss due to the increased recirculation, mixing of fluid and vorticity generation. Copyright © 2010 John Wiley & Sons, Ltd.     

Mathematical Analysis of Geophysical Balance Models

An analysis of an approximation to the rotating shallow-water equations is presented. The approximation removes the fast waves without introducing secular terms and is valid for physical boundaries and prepared initial data. In particular, the shallow-water equations are decomposed into two equations describing the slow and fast dynamics. The basic idea is one of enslaving in which the fast part of the solution is expressed as a function of the slow part yielding an approximation to the slow dynamics. Existence and convergence theorems are given.     

Macroscopic wall number analysis of single-walled, double-walled, and few-walled carbon nanotubes by X-ray diffraction

The layer number is of great importance for nanocarbon materials, such as carbon nanotubes (CNTs) and graphene. While simple optical methods exist to evaluate few-layer graphene, equivalent analysis for CNTs is limited to transmission electron microscopy. We present a simple macroscopic method based on the (002) X-ray diffraction peak to evaluate the average wall number of CNTs in the range from single- to few-walled. The key was the finding that the (002) peak could be decomposed into two basic components: the intertube structure (outer-wall contacts) and the intratube structure (concentric shells). Decomposition of the peaks revealed a linear relationship between the average wall number and the ratio of the intertube and intratube contributions to the (002) peak. Good agreement with CNTs having average wall numbers ranging from 1 to ～5 demonstrated this as a macroscopic method for average wall number analysis.     

Photoelectron imaging spectroscopy and theoretical investigation of ZrSi

The photoelectron spectrum of ZrSi(-) has been measured at two different photon energies: 2.33 eV and 3.49 eV, providing electron binding energy and photoelectron angular distribution information. The obtained vertical detachment energy of ZrSi(-) is 1.584(14) eV. The neutral ground and excited state terms are assigned based on experimental and theoretical results. The ground state of ZrSi is tentatively assigned as a (3)Σ(+) state with a configuration of 1σ(2) 1π(4) 1δ(0) 2σ(1) 3σ(1). A low lying (3)Π(i) neutral excited state is identified to be 0.238 eV (1919 cm(-1)) above the ground state. The anion ground state is designated as a (2)Σ(+) state with a 1σ(2) 1π(4) 1δ(0) 2σ(2) 3σ(1) valence electron configuration. A Franck-Condon (FC) simulation of the photoelectron spectrum has been carried out. For the (3)Σ(+) ← (2)Σ(+) band, theoretically calculated bond lengths and frequencies are used in the FC calculation which give good agreement with experiment, while for the (3)Π(i) ← (2)Σ(+) band, the ZrSi bond length is estimated from the FC spectrum. Comparisons are made with previously published theoretical studies and inconsistencies are pointed out. To the best of our knowledge, this study provides the first spectroscopic information on the transition metal-silicon diatomic, ZrSi.     

Über die gegenseitige Einwirkung von flüssigen Filmen

Zusammenfassung Es wird gezeigt, da? ?ls?ure auf anges?uerter Permanganatl?sung einen Film ergibt, der au?erordentlich empfindlich gegenüber Einwirkungen anderer Flüssigkeiten ist. Die charakteristischen sternf?rmigen Teilchen dieses Filmes werden durch viele organische Flüssigkeiten und auch durch menschliche Blutseren ver?ndert. Besonders ausgepr?gt ist dies der Fall, wenn die Seren Wassermannreaktion zeigen, denn dann ist die Ver?nderung der Teilchen sehr einfacher Natur. Diese Reaktion kann aber nicht als wirklich spezifisch für syphilitische Seren betrachtet werden, da die Seren gewisser Patienten, die jedoch nicht syphilitisch sind, ganz ?hnliche Reaktionen ergeben. übersetzt von Rud. Walter (Leipzig). Die Verfasser danken den Herren Dr. Robb M. D. und Dr. Ross M. B. C. M. für ihre wertvolle Unterstützung bei diesen Untersuchungen.