Electron Spin Resonance Study on the Photoinduced Electron Transfer in Chlorophyll a in Reconstituted Lipid Bilayer Vesicles

Abstract  

The photoinduced electron transfer from chlorophyll a through the interface of positively charged dioctadecyltrimethylammonium chloride (DODAC), neutral dipalmitoylphosphatidylcholine (DPPC) and negatively charged dihexadecylphosphate (DHP) headgroup of the lipid bilayers was studied. The photoinduced radicals were identified by electron spin resonance (ESR) and radical yields of chlorophyll a were determined by double integration of the ESR spectra. The formation of vesicles was identified indirectly by measuring change of the λ _max value of optical absorption spectrophotometer from diethyl ether solution to vesicle solutions, and observed directly with scanning and transmission electron microscopic images. The interaction distance between chlorophyll a and interface water (D₂O) determined by deuterium modulation depth with electron spin echo modulation (ESEM) showed a decreasing order DODAC > DPPC > DHP. The interface charge of each vesicle was determined with zeta potential measurement. The interface charge of the lipid bilayers affected the radical yields of chlorophyll a more critically than the interaction distance between chlorophyll a and interface water.     

General reflexivity and pattern subspaces

This paper extends the theory of reflexivity triples by extending notions and results in the theory of dual operator algebras to this more general setting. In addition, a complete and simple characterization is given for the reflexivity of two-dimensional pattern spaces of finite matrices.     

Ion Behavior in an Electrically Compensated Ion Cyclotron Resonance Trap

We recently described a new electrically compensated trap in FT ion cyclotron resonance mass spectrometry and developed a means of tuning traps of this general design. Here, we describe a continuation of that research by comparing the ion transient lifetimes and the resulting mass resolving powers and signal-to-noise (S/N) ratios that are achievable in the compensated vs. uncompensated modes of this trap. Transient lifetimes are ten times longer under the same conditions of pressure, providing improved mass resolving power and S/N ratios. The mass resolving power as a function of m/z is linear (log-log plot) and nearly equal to the theoretical maximum. Importantly, the ion cyclotron frequency as a function of ion number decreases linearly in accord with theory, unlike its behavior in the uncompensated mode. This linearity should lead to better control in mass calibration and increased mass accuracy than achievable in the uncompensated mode.     

On optimal polling policies

In a single-server polling system, the server visits the queues according to a routing policy and while at a queue, serves some or all of the customers there according to a service policy. A polling (or scheduling) policy is a sequence of decisions on whether to serve a customer, idle the server, or switch the server to another queue. The goal of this paper is to find polling policies that stochastically minimize the unfinished work and the number of customers in the system at all times. This optimization problem is decomposed into three subproblems: determine the optimal action (i.e., serve, switch, idle) when the server is at a nonempty queue; determine the optimal action (i.e., switch, idle) when the server empties a queue; determine the optimal routing (i.e., choice of the queue) when the server decides to switch. Under fairly general assumptions, we show for the first subproblem that optimal policies are greedy and exhaustive, i.e., the server should neither idle nor switch when it is at a nonempty queue. For the second subproblem, we prove that in symmetric polling systems patient policies are optimal, i.e., the server should stay idling at the last visited queue whenever the system is empty. When the system is slotted, we further prove that non-idling and impatient policies are optimal. For the third subproblem, we establish that in symmetric polling systems optimal policies belong to the class of Stochastically Largest Queue (SLQ) policies. An SLQ policy is one that never routes the server to a queue known to have a queue length that is stochastically smaller than that of another queue. This result implies, in particular, that the policy that routes the server to the queue with the largest queue length is optimal when all queue lengths are known and that the cyclic routing policy is optimal in the case that the only information available is the previous decisions.This work was supported in part by NSF under Contract ASC-8802764.     

Mathematical Analysis of Geophysical Balance Models

An analysis of an approximation to the rotating shallow-water equations is presented. The approximation removes the fast waves without introducing secular terms and is valid for physical boundaries and prepared initial data. In particular, the shallow-water equations are decomposed into two equations describing the slow and fast dynamics. The basic idea is one of enslaving in which the fast part of the solution is expressed as a function of the slow part yielding an approximation to the slow dynamics. Existence and convergence theorems are given.     

Implantation of the 111In/Cd Probe as InO− Ion for Radioisotope Tracer Studies

A radioisotope ion implanter has been developed using a cesium-sputtering, negative ion source, which offers versatility and sustained operation. Employing the molecular ¹¹¹In¹⁶O⁻ ion, μCi activities of the radioisotope probe ¹¹¹In/Cd have been implanted into different material hosts. The implanted tracer activity has been shown to be sufficient for LTNO, NMRON and PAC. A new NMRON resonance for ¹¹¹InAg was observed at 75.08 MHz. In₂O₃ powder performed well as the radioisotope carrier in the ion source, with the ratio of radioisotope and parasitic ion current being typically 4 × 10⁻⁴.