全文获取类型
收费全文 | 1615篇 |
免费 | 48篇 |
国内免费 | 3篇 |
专业分类
化学 | 1123篇 |
晶体学 | 9篇 |
力学 | 54篇 |
数学 | 283篇 |
物理学 | 197篇 |
出版年
2023年 | 8篇 |
2022年 | 13篇 |
2021年 | 20篇 |
2020年 | 21篇 |
2019年 | 15篇 |
2018年 | 17篇 |
2017年 | 15篇 |
2016年 | 34篇 |
2015年 | 37篇 |
2014年 | 42篇 |
2013年 | 82篇 |
2012年 | 127篇 |
2011年 | 113篇 |
2010年 | 89篇 |
2009年 | 84篇 |
2008年 | 106篇 |
2007年 | 113篇 |
2006年 | 96篇 |
2005年 | 90篇 |
2004年 | 81篇 |
2003年 | 59篇 |
2002年 | 65篇 |
2001年 | 22篇 |
2000年 | 22篇 |
1999年 | 19篇 |
1998年 | 17篇 |
1997年 | 17篇 |
1996年 | 10篇 |
1995年 | 7篇 |
1994年 | 27篇 |
1993年 | 15篇 |
1992年 | 7篇 |
1991年 | 11篇 |
1990年 | 10篇 |
1989年 | 11篇 |
1987年 | 6篇 |
1986年 | 12篇 |
1985年 | 12篇 |
1984年 | 14篇 |
1983年 | 5篇 |
1982年 | 12篇 |
1981年 | 9篇 |
1980年 | 9篇 |
1979年 | 9篇 |
1978年 | 11篇 |
1977年 | 6篇 |
1976年 | 6篇 |
1975年 | 7篇 |
1974年 | 7篇 |
1972年 | 6篇 |
排序方式: 共有1666条查询结果,搜索用时 187 毫秒
141.
Baril-Robert F Petit S Pilet G Chastanet G Reber C Luneau D 《Inorganic chemistry》2010,49(23):10970-10976
A series of lanthanide-doped nonanuclear yttrium(III) clusters with general formulas (Y(9-x)Ln(x))(acac)(16)(μ(3)-OH)(8)(μ(4)-O)(μ(4)-OH) (Ln = Pr, Eu, Tb, Dy, and Yb) were synthesized. Characterization by single-crystal X-ray diffraction allowed for analysis of relative populations of yttrium (Z = 39) and dopant trivalent lanthanide (Z = 59-70) at every crystallographic metal position. Nonuniform distribution of ions along the three different sites seems to be correlated to the site volume and the ratio of ionic radii. In support, luminescence spectra of europium(III)-doped nonanuclear clusters were measured over a wide range of dopant concentrations. Emission intensities of peaks characteristic of specific sites correlate well with the site population determined through X-ray diffraction. 相似文献
142.
143.
Francesca Tessore Dr. Elena Cariati Prof. Franco Cariati Prof. Dominique Roberto Prof. Renato Ugo Prof. Patrizia Mussini Prof. Cristiano Zuccaccia Dr. Alceo Macchioni Prof. 《Chemphyschem》2010,11(2):495-507
A series of 4‐X‐1‐methylpyridinium cationic nonlinear optical (NLO) chromophores (X=(E)‐CH?CHC6H5; (E)‐CH?CHC6H4‐4′‐C(CH3)3; (E)‐CH?CHC6H4‐4′‐N(CH3)2; (E)‐CH?CHC6H4‐4′‐N(C4H9)2; (E,E)‐(CH?CH)2C6H4‐4′‐N(CH3)2) with various organic (CF3SO3?, p‐CH3C6H4SO3?), inorganic (I?, ClO4?, SCN?, [Hg2I6]2?) and organometallic (cis‐[Ir(CO)2I2]?) counter anions are studied with the aim of investigating the role of ion pairing and of ionic dissociation or aggregation of ion pairs in controlling their second‐order NLO response in anhydrous chloroform solution. The combined use of electronic absorption spectra, conductimetric measurements and pulsed field gradient spin echo (PGSE) NMR experiments show that the second‐order NLO response, investigated by the electric‐field‐induced second harmonic generation (EFISH) technique, of the salts of the cationic NLO chromophores strongly depends upon the nature of the counter anion and concentration. The ion pairs are the major species at concentration around 10?3 M , and their dipole moments were determined. Generally, below 5×10?4 M , ion pairs start to dissociate into ions with parallel increase of the second‐order NLO response, due to the increased concentration of purely cationic NLO chromophores with improved NLO response. At concentration higher than 10?3 M , some multipolar aggregates, probably of H type, are formed, with parallel slight decrease of the second‐order NLO response. Ion pairing is dependent upon the nature of the counter anion and on the electronic structure of the cationic NLO chromophore. It is very strong for the thiocyanate anion in particular and, albeit to a lesser extent, for the sulfonated anions. The latter show increased tendency to self‐aggregate. 相似文献
144.
Chati F Léon F Décultot D Maze G 《The Journal of the Acoustical Society of America》2011,129(4):1899-1904
This paper revisits the vanishing of the transverse component of the particle displacement vector in free surfaces of an isotropic homogeneous plate, for both symmetric and antisymmetric Lamb waves. Drawing on well-known analytical expressions from Viktorov's book [(1967) Rayleigh and Lamb Waves: Physical Theory Applications, Chap. II, pp. 67-121], two distinct frequency-thickness product expressions, in cases where this vanishing occurs, are derived: one for the symmetric modes and another for the antisymmetric modes. At these frequency-thickness products, phase and group velocities have appreciable values which are discussed herein. It appears that these velocities depend on the transverse bulk wave velocity only. This is the specific condition of the Lame? modes. Moreover, theoretical and experimental investigations of displacements in the surface of a plate in air have been carried out. The theoretical part shows that the normal and transverse displacements have, respectively, a local maximum and a local minimum in the vicinity of these frequency-thickness products. The experimental part corroborates the presence of the local maximum of the S(0) Lamb mode for various materials. 相似文献
145.
We consider the counterpropagating interaction of a signal and a pump beam in a spun fiber and in a randomly birefringent fiber, the latter being relevant to optical telecommunication systems. On the basis of a geometrical analysis of the Hamiltonian singularities of the system, we provide a complete understanding of the phenomenon of polarization attraction in these two systems, which allows to achieve a control of the polarization state of the signal beam by adjusting the polarization of the pump. In spun fibers, all polarization states of the signal beam are attracted toward a specific line of polarization states on the Poincaré sphere, whose characteristics are determined by the polarization state of the injected backward pump. In randomly birefringent telecommunication fibers, we show that an unpolarized signal beam can be repolarized into any particular polarization state, without loss of energy. 相似文献
146.
147.
We establish a dichotomy theorem characterizing the circumstances under which a treeable Borel equivalence relation E is essentially countable. Under additional topological assumptions on the treeing, we in fact show that E is essentially countable if and only if there is no continuous embedding of E1 into E. Our techniques also yield the first classical proof of the analogous result for hypersmooth equivalence relations, and allow us to show that up to continuous Kakutani embeddability, there is a minimum Borel function which is not essentially countable-to-one. 相似文献
148.
Dominique Bourn 《Applied Categorical Structures》2014,22(5-6):833-856
We investigate what is the common part of the action accessible and the fibrewise algebraically cartesian closed (facc) categories dealing with the existence of centralizers of equivalence relations. Doing this, we shall introduce some new aspects of the Beck-Chevalley commutation with respect to the fibration of points \(\P _{\mathbb C}\) and shall characterize the existence of those centralizers by a specific property of this same fibration. 相似文献
149.
150.
Saleha Bakhta Michel Guerro Frédéric Barrière Dominique Lorcy 《Tetrahedron letters》2010,51(34):4497-3433
The synthesis and the ability of TTF-hydrazone to act as a versatile precursor for the design of electroactive ligands are reported together with the chelating ability of these ligands through their M(CO)4 complexes, (M = Mo, W). 相似文献