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51.
We examine the following version of a classic combinatorial search problem introduced by Rényi: Given a finite set X of n elements we want to identify an unknown subset Y of X, which is known to have exactly d elements, by means of testing, for as few as possible subsets A of X, whether A intersects Y or not. We are primarily concerned with the non-adaptive model, where the family of test sets is specified in advance, in the case where each test set is of size at most some given natural number k. Our main results are nearly tight bounds on the minimum number of tests necessary when d and k are fixed and n is large enough.  相似文献   
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Fuel-rich combustion of methane in a homogeneous-charge compression-ignition (HCCI) engine can be used as a polygeneration process producing work, heat, and useful chemicals like syngas. Due to the inertness of methane, additives such as dimethyl ether (DME) are needed to achieve ignition at moderate inlet temperatures and to control combustion phasing. Because significant concentrations of DME are then needed, a considerable part of the fuel energy comes from DME. An alternative ignition promotor known from fuel-lean HCCI is ozone (O3). Here, a combined experimental and modelling study on the ignition of fuel-rich partial oxidation of methane/air mixtures at Φ = 1.9 with ozone and DME as additives in an HCCI engine is conducted. Experimental results show that ozone is a suitable additive for fuel-rich HCCI, with only 75 ppm ozone reducing the fuel-fraction of DME needed from 11.0% to 5.3%. Since ozone does not survive until the end of the compression stroke, the reaction paths are analyzed in a single-zone model. The simulation shows that different ignition precursors or buffer molecules are formed, depending on the additives. If only DME is added, hydrogen peroxide (H2O2) and formaldehyde (CH2O) are the most important intermediates, leading to OH formation and ignition around top dead center (TDC). With ozone addition, methyl hydroperoxide (CH3OOH) becomes very important earlier in the compression stroke under these fuel-rich conditions. It is then later converted to CH2O and H2O2. Thus, ozone is a very effective additive not only for fuel-lean, but also for fuel-rich combustion. However, the mechanism differs between both regimes. Because less of the expensive additives are needed, ozone could help improving the economics of a polygeneration process with fuel-rich operated HCCI engines.  相似文献   
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Dominik Smith   《Nuclear Physics A》2009,820(1-4):227c
We perform simulations of an effective theory of SU(2) Wilson lines in three dimensions. Our action includes a kinetic term, the one-loop perturbative potential for the Wilson line, a non-perturbative “fuzzy-bag” contribution and spatial gauge fields. We determine the phase diagram of the theory and confirm that, at moderately weak coupling, the non-perturbative term leads to eigenvalue repulsion in a finite region above the deconfining phase transition.  相似文献   
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The activity of Mo/V/W mixed oxide catalyst in the gas phase oxidation of acrolein to acrylic acid is tremendously influenced by addition of fed water. This effect of water is investigated and connected to the catalytic mechanism by several stationary kinetic measurements and transient response methods, such as temperature-programmed reduction, oxidation and desorption experiments, special concentration-programmed methods as well as H218O-SSITKA and D2O-SSITKA experiments. Furthermore, kinetic modeling, based on results of H218O-SSITKA experiments in a wide temperature and feed water content range gives access to kinetic parameters of single reaction steps in the catalytic mechanism. The developed mechanism is not only able to describe conversion and selectivities, inclusively the effect of water, but also describes the 18O-degree of labeling of all reaction components quantitatively.  相似文献   
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Hydrogen-bonded organic semiconductors are extraordinarily stable organic solids forming stable, large crystallites with the ability to preserve favorable electrical properties upon bioconjugation. Lately, tremendous efforts have been made to use these bioconjugated semiconductors as platforms for stable multifunctional bioelectronics devices, yet the detailed characterization of bio-active binding sites (orientation, density, etc.) at the nanoscale has not been achieved yet. The presented work investigates the bioconjugation of epindolidione and quinacridone, two representative semiconductors, with respect to their exposed amine-functionalities. Relying on the biotin-avidin lock-and-key system and applying the atomic force microscopy (AFM) derivative topography and recognition (TREC) imaging, we used activated biotin to flag crystal-faces with exposed amine functional groups. Contrary to previous studies, biotin bonds were found to be stable towards removal by autolysis. The resolution strength and clear recognition capability makes TREC-AFM a valuable tool in the investigation of bio-conjugated, hydrogen-bonded semiconductors.  相似文献   
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The consideration of residual stresses in forming processes is a promising opportunity to influence the final component's properties in a positive manner. Instead of their minimization, a targeted application of residual stresses can extend life time or durability and enhance manufacturability of metallic components. For this reason, detailed experimental and numerical analyses are an object of current research. Here, the cooling process is simulated in order to analyze the influence of the microscopic phase evolution on the macroscopic stress distribution in a cylinder with eccentric hole made of steel 100Cr6.  相似文献   
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For modeling the solid‐solid transformation using the phase‐field method, we need to describe the phase‐fields strain and stress fields in the interfacial regions which are necessary to define the mechanical driving force density of the phase‐fields motion. Seeking quantitative modeling, we introduce briefly a multi‐phase‐field elasticity model based on the rank‐one convexification of the pairwise energies which satisfies the pairwise interfacial static equilibrium and kinematic compatibility conditions. As an application, we simulate the martensitic transformation in a two‐dimensional polycrystalline SMAs at small strains. The finial evaluated microstructure consists of stress‐free laminates meeting the theoretical expectations.  相似文献   
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