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121.
Gutiérrez-Tauste D Domènech X Domingo C Ayllón JA 《Chemical communications (Cambridge, England)》2007,(44):4659-4661
The straightforward modification of commercial hexafluorotitanic acid with organic derivatives containing a tetraalkylammonium cation produced stable precursor solutions with only a small fraction of water, which were then used as a reaction medium for the synthesis of nanocrystalline TiO(2). 相似文献
122.
Pentacyclic pyrrolo- and pyrido[1,2-a]xanthene[1,9-de]azepines were synthesized in various oxidation states by assembling the azepine ring following two strategies: 7-endo-trig cyclization of the aryl radical derived from a gamma-methylene lactam and cyclodehydration of aldehydes. Other strategies examined (Heck reaction and intramolecular acylation) did not afford azepines, but six-membered nitrogenated rings. 相似文献
123.
Garcia G Doménech-Ferrer R Pi F Santiso J Rodríguez-Viejo J 《Journal of combinatorial chemistry》2007,9(2):230-236
We have grown thin film libraries of the Mg-Al system using a high-throughput synthesis methodology that combines the sequential deposition of pure elements (Mg and Al) by an electron-beam (e-beam) evaporation technique and the use of a special set of moving shadow masks. This novel mask has been designed to simultaneously prepare four identical arrays of different compositions that will permit the characterization of the same library after several treatments. Wavelength dispersive spectroscopy (WDS) and micro-X-ray diffraction have been used as high-throughput screening techniques for the determination of the composition and structure of every member of the library in the as-deposited state and after hydrogenation at 1 atm of H2 during 24 h at three different temperatures: 60, 80, and 110 degrees C. We have analyzed the influence of the Mg-Al ratio on the hydrogenation of magnesium, as well as on the appearance of complex hydride phases. We have also found that aluminum can act as a catalyzer for the hydrogenation reaction of magnesium. 相似文献
124.
Domínguez H 《The journal of physical chemistry. B》2007,111(16):4054-4059
Molecular dynamics simulations of sodium dodecyl sulfate (SDS) molecules on a graphite surface are presented. The simulations were conducted at low and high surface coverage to study aggregation at the water/graphite interface. Results showed that at low surface coverage, the SDS molecules form hemicylindrical aggregates, in agreement with AFM experiments, whereas at high surface coverage, the surfactants form full cylinders. The latter aggregates have not been reported in systems of SDS on hydrophobic substrates, such as graphite. The unexpected results are explained in terms of a water layer adsorbed at the solid surface which was the responsible for the formation of these aggregates. Moreover, the SDS tails in the full cylindrical configuration became straighter than those of the hemicylindrical aggregate. Hydrogen bond formation between water and surfactant head groups was also studied, and it was found that they did not depend on the surfactant concentration. 相似文献
125.
Oettel M Domínguez A Tasinkevych M Dietrich S 《The European physical journal. E, Soft matter》2009,28(2):99-111
The elastic and capillary interactions between a pair of colloidal particles trapped on top of a nematic film are studied
theoretically for large separations d. The elastic interaction is repulsive and of quadrupolar type, varying as d-5. For macroscopically thick films, the capillary interaction is likewise repulsive and proportional to d-5 as a consequence of mechanical isolation of the system comprised of the colloids and the interface. A finite film thickness
introduces a nonvanishing force on the system (exerted by the substrate supporting the film) leading to logarithmically varying
capillary attractions. However, their strength turns out to be too small to be of importance for the recently observed pattern
formation of colloidal droplets on nematic films. 相似文献
126.
Noelia Calvar Elena Gómez Begoña González Ángeles Domínguez 《The Journal of chemical thermodynamics》2009,41(8):939-944
Densities, speeds of sound, and refractive indices of 12 binary systems of alkanes (hexane, heptane, octane, and nonane) with aromatics (benzene, or toluene, or ethylbenzene) at T = 313.15 K and at atmospheric pressure were determined over the whole composition range, and are presented in this paper. From the experimental results, the derived and excess properties (isentropic compressibility, excess molar volumes, and excess molar isentropic compressibility) at T = 313.15 K were calculated and satisfactorily fitted to the Redlich–Kister equation. 相似文献
127.
O. Domínguez-Renedo M.A. Alonso-Lomillo L. Ferreira-Gonçalves M.J. Arcos-Martínez 《Talanta》2009,79(5):1306-1310
Enzymatic amperometric procedures for measurement of Hg (II), based on the inhibitive action of this metal on urease enzyme activity, were developed. Screen-printed carbon electrodes (SPCEs) and gold nanoparticles modified screen-printed carbon electrodes (AuNPs/SPCEs) were used as supports for the cross-linking inmobilization of the enzyme urease. The amperometric response of urea was affected by the presence of Hg (II) ions which caused a decreasing in the current intensity. The optimum working conditions were found using experimental design methodology. Under these conditions, repeatability and reproducibility for both types of biosensors were determined, reaching values below 6% in terms of residual standard deviation. The detection limit obtained for Hg (II) was 4.2 × 10?6 M for urease/SPCE biosensor and 5.6 × 10?8 M for urease/AuNPs/SPCE biosensor. Analysis of the possible effect of the presence of foreign ions in the solution was performed. The method was applied to determine levels of Hg (II) in spiked human plasma samples. 相似文献
128.
Doménech-Carbó MT Kuckova S de la Cruz-Cañizares J Osete-Cortina L 《Journal of chromatography. A》2006,1121(2):248-258
Terpenoid resins have been mainly used as components of pictorial varnishes and binding media from ancient times. In such latest instances, the resin is mixed with pigments affecting its physical and chemical properties. A new procedure based on gas chromatography-mass spectrometry (GC/MS) has been applied, in this work, in combination with Fourier transform infrared spectroscopy (FTIR), with the aim of determining the changes undergone by di- and triterpenoid resins employed as components of binding media. The GC/MS method is based on the derivatisation of these resins using trimethylsilylimidazol. Characterization of the main components of the di- and triterpenoid fractions and their oxidised products, occurring in the diterpenoid resin colophony and a triterpenoid Mexical copal (Bursera cuneata (Schl) Engl.), has been achieved. Artificially photoaged specimens of pure resin and binary systems pigment+resin prepared as thin films using lead white, ochre yellow, umber raw and verdigris have also been analysed to study the changes undergone by the di- and triterpenoid components of the resins. Oxidation processes taking place on di- and triterpenoids during photoageing are described. Moreover, the results obtained indicate that pigments have a different effect on the two studied resins. Thus, the presence of pigments induces, in general, a catalysing effect on the oxidative polymerisation reactions in the earliest stages of the natural curing of the paint films whereas a loss of the catalysing effectiveness, in particular, for verdigris containing specimens, is observed during photoageing. Complexation of diterpenoid molecules with copper(II) ions in the earliest stages of the curing has also been evidenced by FTIR analysis. 相似文献
129.
130.
The sequential Stille cross-coupling reactions of the dihalogenated gamma-alkylidenebutenolide 7 with stannanes 9 and 6 afforded the carbon skeleton of pyrrhoxanthin, a highly functionalized C7'-C8' acetylenic C37-norcarotenoid butenolide. Although the first halogen-selective Stille coupling takes place in 90% yield at ambient temperature, double isomerization of the Z,E- to the E,Z-C7'-C10' enyne, likely induced by the catalyst, accompanyied the bond formation, leading to 9'Z-20 and, ultimately, to 9'Z-pyrrhoxanthin 9'Z-1. 相似文献