全文获取类型
收费全文 | 117篇 |
免费 | 0篇 |
专业分类
化学 | 76篇 |
晶体学 | 1篇 |
力学 | 2篇 |
数学 | 11篇 |
物理学 | 27篇 |
出版年
2022年 | 2篇 |
2021年 | 3篇 |
2020年 | 1篇 |
2019年 | 2篇 |
2017年 | 2篇 |
2016年 | 1篇 |
2015年 | 2篇 |
2014年 | 2篇 |
2013年 | 8篇 |
2012年 | 4篇 |
2011年 | 9篇 |
2010年 | 3篇 |
2009年 | 5篇 |
2008年 | 8篇 |
2007年 | 7篇 |
2006年 | 7篇 |
2005年 | 5篇 |
2004年 | 2篇 |
2003年 | 8篇 |
2002年 | 6篇 |
2001年 | 2篇 |
2000年 | 2篇 |
1999年 | 8篇 |
1997年 | 1篇 |
1996年 | 3篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1987年 | 1篇 |
1985年 | 1篇 |
1984年 | 2篇 |
1981年 | 1篇 |
1980年 | 3篇 |
1979年 | 1篇 |
1976年 | 1篇 |
1974年 | 1篇 |
1973年 | 1篇 |
排序方式: 共有117条查询结果,搜索用时 15 毫秒
91.
Results are presented on the thermal behaviour of [Fe(III)2Cu(C2C4)2(OH)4(H2O)2] precursor of copper ferrite. An investigation of the decomposition steps and intermediates was followed by a non-isothermal kinetic analysis of the processable steps. 相似文献
92.
L. Patron P. Budrugeac A. Balu Oana Carp L. Diamandescu M. Feder 《Journal of Thermal Analysis and Calorimetry》2007,88(1):273-277
The thermal
behaviour of five polynuclear coordination compounds containing tartaric anion
as ligand, namely (NH4)3[LnFe(C4O6H4)3(OH)3] (Ln=La
and Eu), (NH4)2[PrFe(C4O6H4)3(OH)2] and (NH4)[LnFe(C4O6H4)3(OH)]·3H2O (Ln=Nd and Gd) was investigated. The reaction progress
was studied by TG/DTA and FTIR measurements. Oxalates and oxocarbonates were
identified as intermediates. In the case of Ln=La,
Nd, Pr, Eu and Gd, pure LnFeO3 was obtained as final
decomposition product. The thermal decomposition of Eu-Fe compound, leads
to a mixture of mixed (ortho-ferrite (EuFeO3) and garnet
(Eu3Fe5O12))
and simple oxides (Eu2O3 and
α-Fe2O3). 相似文献
93.
Luminita Patron Oana Carp I. Mindru G. Marinescu J. Hanss A. Reller 《Journal of Thermal Analysis and Calorimetry》2008,92(1):307-312
The thermal behaviour of four coordination compounds (NH4)6[Y3Fe5(C4O5H4)6(C4O5H3)6]·12H2O, (NH4)6[Y3Fe5(C6O7H10)6(C6O7H9)6]·8H2O, (NH4)6[Er3Fe5(C4O5H4)6(C4O5H3)6]·10H2O and (NH4)6[Er3Fe5(C4O6H4)6(C4O6H3)6]·22H2O has been studied to evaluate their suitability for garnet synthesis. The thermal decomposition and the phase composition
of the resulted decomposition compounds are influenced by the nature of metallic cations (yttrium-iron or erbium-iron) and
ligand anions (malate or gluconate). 相似文献
94.
Rodica Olar Mihaela Badea Oana Carp Dana Marinescu Veronica Lazar Carmen Balotescu Anca Dumbrava 《Journal of Thermal Analysis and Calorimetry》2008,92(1):245-251
The investigation concerning the synthesis, spectrochemical and biological properties as well as thermal stability of some tiosulfato-and sulfato copper(II) complexes of type [Cuphen(S2O3)(H2O)n]·mH2O (phen: 1,10-phenanthroline; (1): n=2, m=0; (2): n=2, m=0.5) and respectively [Cuphen(OSO3)(H2O)n] ((3): n=0; (4): n=2) are presented in this paper. The bonding and stereochemistry of the complexes have been characterised by IR and electronic studies. The in vitro qualitative and quantitative assays of the antimicrobial activity of the tested compounds vs. planktonic and adherent Gram negative bacterial strains isolated from different surfaces in the hospital environment demonstrated that all compounds exhibited very good antimicrobial activity vs. Escherichia coli, Klebsiella sp. and Enterobacter sp. with very low M.I.C. values. The thermal analysis has evidenced the thermal intervals of stability and also the thermodynamics effects that accompany them both in synthetic air and argon. The thermal behaviour is complex according to DTG and DSC curves including dehydration as well as thiosulfate and phenanthroline decomposition. 相似文献
95.
Carmen Paraschiv B. Jurca Adelina Ianculescu Oana Carp 《Journal of Thermal Analysis and Calorimetry》2008,94(2):411-416
Two bismuth ferrite potential precursors systems, namely Fe(NO3)3·9H2O-Bi(NO3)3·9H2O-glycine/urea with different metal nitrate/organic compound molar ratios have been investigated in order to evaluate their
suitability as BiFeO3 precursors. The presence into the precursor of both reducing (glycine and urea) and oxidizing (NO3−) components, modifies dramatically their thermal behaviour comparative with the raw materials, both from the decomposition
stoichiometries and temperature occurrence intervals points of view. Also, the thermal behaviour is dependent on the fuel
nature but practically independent with the fuel content. The fuel nature influences also some characteristics of the resulted
oxides (phase composition, morphologies). In the case of the oxides prepared using urea as fuel, a faster evolution toward
a single phase composition with the temperature rise is evidenced, the formation of the BiFeO3 perovskite phase being completed in the temperature range of 500–550°C. 相似文献
96.
A cheap and efficient fibrous hydrolyzed polyacrylonitrile (HPAN) sorbent was obtained by alkaline hydrolysis of Romanian
polyacrylonitrile fibres. Scanning electronic microscopy and infrared spectroscopy were used to characterize the hydrolyzed
product and to confirm its functionalization. The adsorptive potential of the proposed sorbent for reactive dye Brilliant
Red HE-3B removal from aqueous solutions of pH=2 was examined by the batch technique as a function of dye concentration, temperature
solution and contact time. The Freundlich, Langmuir and Dubinin-Radushkevich adsorption models were applied to describe equilibrium
sorption data and to determine the corresponding isotherm constants. The thermodynamic parameters ΔG, ΔH and ΔS were also
determined; the values obtained show that sorption of reactive dye on HPAN fibres is a spontaneous, endothermic and entropy-driven
process. The kinetics of sorption of the reactive dye were analyzed using pseudo-first order and pseudo-second order kinetic
models. The kinetic data fitted well to pseudo-second order kinetics, indicating the chemisorption of reactive dye onto the
fibrous sorbent. The sorption mechanism of the dye onto hydrolyzed fibres was confirmed by FTIR spectroscopy. The dye-loaded
HPAN sorbent can be regenerated by treatment with 0.1M NaOH and the regenerated sorbent may be reused in several adsorption-desorption
cycles. The results of this study provided evidence that the HPAN fibres are effective for removing reactive dye Brilliant
Red HE-3B from aqueous effluents.
相似文献
97.
Doina Cioranescu Patrizia Donato Horia I. Ene 《Mathematical Methods in the Applied Sciences》1996,19(11):857-881
We study the Stokes system with non-homogeneous Fourier boundary conditions depending on a parameter, in a domain with periodic inclusions of the size of the period. Following the values of this parameter, we obtain at the limit a Darcy's law, a Brinkmann type equation or a Stokes type equation. We also present a physical model to which the results apply. This model describes the flow of an incompressible viscous fluid through a porous medium under the action of an exterior electric field. 相似文献
98.
99.
Doina Bejan Ecaterina Cornelia Niculescu 《The European Physical Journal B - Condensed Matter and Complex Systems》2016,89(6):138
We investigated the combined effects of a non-resonant intense laser field and a static electric field on the electronic structure and the nonlinear optical properties (absorption, optical rectification) of a GaAs asymmetric double quantum dot under a strong probe field excitation. The calculations were performed within the compact density-matrix formalism under steady state conditions using the effective mass approximation. Our results show that: (i) the electronic structure and optical properties are sensitive to the dressed potential; (ii) under applied electric fields, an increase of the laser intensity induces a redshift of the optical absorption and rectification spectra; (iii) the augment of the electric field strength leads to a blueshift of the spectra; (iv) for high electric fields the optical spectra show a shoulder-like feature, related with the occurrence of an anti-crossing between the two first excited levels. 相似文献
100.
Magnetic nanoparticles and concentrated magnetic nanofluids: Synthesis, properties and some applications 总被引:2,自引:0,他引:2
Ladislau Vékás 《中国颗粒学报》2007,5(1):43-49
This paper reviews some recent results concerning chemical synthesis of magnetic nanoparticles and preparation of various types of magnetic nanofluids. Structural properties and behaviour in external magnetic field of magnetic nanofluids will be emphasized with relation to their use in leakage-free rotating seals and in biomedical applications. 相似文献