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Alexander Horn Dirk Wortmann Andreas Brand Ilya Mingareev 《Applied Physics A: Materials Science & Processing》2010,101(2):231-235
A modified Mach–Zehnder interferometer set-up combined with microscope objectives has been developed for the measurement of
phase changes in the processed material sample, like modification and melting of glass. The white light is generated by focusing
ultrafast laser radiation (t
p=80 fs) in a sapphire crystal using a micro-lens array to minimize temporal and spatial fluctuations in the white-light continuum.
Lateral and coaxial pump-probe measurements of the phase changes during material processing are performed using two coupled
ultrafast laser sources at different repetition rates (f
rep=1 Hz–1 MHz). The optical phase shift and therefore the refractive index of the material are calculated from the interference
images using two approaches. The knowledge of the refractive index during the laser processing with a temporal resolution
in the ps-range and a spatial resolution of several microns leads to a better understanding of the initial processes for the
permanent material modifications. 相似文献
184.
Minimalistic Ditopic Ligands: An α‐S,N‐Donor‐Substituted Alkyne as Effective Intermetallic Conjugation Linker
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Julia Rüger Christopher Timmermann Dr. Alexander Villinger Alexander Hinz Dr. Dirk Hollmann Prof. Dr. Wolfram W. Seidel 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(32):11191-11195
The capability of donor‐substituted alkynes to link different metal ions in a side‐on carbon donor‐chelate coordination mode is extended from the donor centers S and P to the second period element N. The complex [Tp′W(CO)2{η2‐C2(S)(NHBn)}] (Tp′=hydrido‐tris(3,5‐dimethylpyrazolyl)borate, Bn=benzyl) bearing a terminal sulfur atom and a secondary amine substituent is accessible by a metal‐template synthesis. Subsequent deprotonation allowed the formation of remarkably stable heterobimetallic complexes with the [(η5‐C5H5)Ru(PPh3)] and the [Ir(ppy)2] moiety. Electrochemical and spectroscopic investigations (cyclic voltammetry, IR, UV/Vis, luminescence, EPR), as well as DFT calculations, and X‐ray structure determinations of the W–Ru complex in two oxidation states reveal a strong metal–metal coupling but also a limited delocalization of excited states. 相似文献
185.
Let ξA,B be the Krein spectral shift function for a pair of operatorsA, B, with C =A-B trace class. We establish the bound
whereF is any non-negative convex function on [0, ∞) with F(0) = 0 and Ώj (C) are the singular values ofC. The choice F(t) =t
p
,p ≥ 1, improves a recent bound of Combes, Hislop and Nakamura.
Supported in part by NSF grant DMS-9707661. 相似文献
186.
Reaction of N-benzoyl-1,2,3,4-tetrahydroquinoline-2-carboxylic acid with acetic anhydride resulted in 1H,3H,5H-oxazolo[3,4-a]quinolin-3-one derivative 13. Different cyclopropanation processes were applied to 13, but only diazomethane in the presence of water furnished the hitherto unknown methyl 1,2,7,7a-tetrahydro-1aH-cyclopropa[b]quinoline-1a-carboxylate 14, which can be considered as a doubly constrained 1-aminocyclopropane-1-carboxylic acid system. The mechanism of the cyclopropanation was studied in detail. The new ACC ester 14 was transformed into fused tetracyclic hydantoin derivatives, which comprised a new type of heterocyclic system. 相似文献
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