Synthesis of graft copolymers with “V‐shaped” and “Y‐shaped” side chains via controlled radical and anionic polymerizations

A combination of nitroxide‐mediated radical polymerization and living anionic polymerization was used to synthesize a series of well‐defined graft (co)polymers with “V‐shaped” and “Y‐shaped” branches. The polymer main chain is a copolymer of styrene and p‐chloromethylstyrene (PS‐co‐PCMS) prepared via nitroxide‐mediated radical polymerization. The V‐shaped branches were prepared through coupling reaction of polystyrene macromonomer, carrying 1,1‐diphenylethylene terminus, with polystyryllithium or polyisoprenyllithium. The Y‐shaped branches were prepared throughfurther polymerization initiated by the V‐shaped anions. The obtained branches, carrying a living anion at the middle (V‐shaped) or at the end of the third segment (Y‐shaped), were coupled in situ with pendent benzyl chloride of PS‐co‐PCMS to form the target graft (co)polymers. The purified graft (co)polymers were analyzed by size exclusion chromatography equipped with a multiangle light scattering detector and a viscometer. The result shows that the viscosities and radii of gyration of the branched polymers are remarkably smaller than those of linear polystyrene. In addition, V‐shaped product adopts a more compact conformation in dilute solution than the Y‐shaped analogy. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4013–4025, 2007     

Partially Strictly Monotone and Nonlinear Penalty Functions for Constrained Mathematical Programs

We introduce the concept of partially strictly monotone functions and apply it to construct a class of nonlinear penalty functions for a constrained optimization problem. This class of nonlinear penalty functions includes some (nonlinear) penalty functions currently used in the literature as special cases. Assuming that the perturbation function is lower semi-continuous, we prove that the sequence of optimal values of nonlinear penalty problems converges to that of the original constrained optimization problem. First-order and second-order necessary optimality conditions of nonlinear penalty problems are derived by converting the optimality of penalty problems into that of a smooth constrained vector optimization problem. This approach allows for a concise derivation of optimality conditions of nonlinear penalty problems. Finally, we prove that each limit point of the second-order stationary points of the nonlinear penalty problems is a second-order stationary point of the original constrained optimization problem.     

Investigation on chaotic motion in hysteretic non-linear suspension system with multi-frequency excitations

This paper presents the investigation on possible chaotic motion in a vehicle suspension system with hysteretic non-linearity, which is subjected to the multi-frequency excitation from road surface. The Melnikov’s function is used to derive the critical condition for the chaotic motion, and then it is investigated that the effects of parameters in non-linear damping on the chaotic field. The path from quasi-periodic to chaotic motion is found via Poincaré map and Lyapunov exponents.     

Low-threshold interband cascade lasers operating above room temperature

Mid-IR type-II interband cascade lasers were demonstrated in pulsed mode at temperatures up to 325 K and in continuous mode up to 200 K. At 80 K, the threshold current density was 8.9 A/cm² and a continuous wave output power of 140 mW/facet was obtained.     

非相干辐照对LiNbO3:Fe晶体光折变非线性的影响与控制作用

研究了非相干辐照对LiNbO3:Fe晶体中从自散焦到自聚焦的动态转换过程的影响和控制作用.无论是从前向还是从背向加入非相干辐照，都能加快自散焦、自聚焦过程以及从自散焦到自聚焦的转换过程，增大折射率的变化值.当非相干辐照以一定的时间间隔重复辐照在晶体上时，透射功率能迅速地上升和下降，具有明显的开关效应.这种在非相干辐照控制下折射率的迅速改变有望应用于全光学开关器件. 关键词： 非相干辐照 光伏效应 自散焦 自聚焦     

<Emphasis FontCategory="NonProportional">L</Emphasis>-Matrices and solvability of linear complementarity problems by a linear program-Matrices and solvability of linear complementarity problems by a linear program

The classes ofL ₁-matrices,L ₂-matrices,L ₃-matrices andW-matrices are introduced to study solvability of a linear complementarity problem via solving a linear program. Three sufficient conditions are presented to guarantee that a linear complementarity problem is solvable via a linear program. The new sufficient conditions are weaker than the ones introduced by Mangasarian. This fact is also illustrated by an example. Partially supported by NSFC. This author is also with College of Business Administration of Human University as a Lotus chair professor.     

Value of Optical Bypass in Packet Ring Networks

This paper firstly examines the value of optical bypass scheme in packet ring networks. An Integer Linear Program (ILP) formulation is presented and analytical results under different traffic patterns are given.     

Investigation on ultrafast thrid—order optical nonlinearity of metal（dmit）2／mnt）2 Charge transfer complexes

We have investigated the transient third-order optical nonlinearity of the solutions of Metal(dmit)2/(mnt)2 salts in acetone by employing femtosecond optical Kerr gate measurement at 830nm wavelength.An order of enhancement on the second-order hyperppolarizability is found for the above salts with central atoms of Cu and Ni.We have suggested an explanation for the enhancement based on the extension of electronic conjugation by the entring Cu or Ni atom.     

Software Cold Test Simulation of Coupled Cavity Slow-Wave Structure in Millimeter Wave TWT

In this paper, the software cold-test simulation method to obtain RF dispersion, interaction impedance by MAFIA software is discussed considering effect of the conducting barrel in the millimeter-wave TWT. The dispersion simulation result is obtained more consistent with experiment data than the method that ignoring effect of the conducting barrel. By changing the structure parameter, high frequency characteristic will be affected. The change relationship of high frequency characteristic with structure parameter is obtained. The different calculation methods of the interaction impedance are discussed. These results are received and are consistent with experiment data.     

Electrical properties of high Curie temperature (1−x)Pb(In1/2Nb1/2)O3-xPbTiO3 single crystals grown by the solution Bridgman technique

0.65Pb(In_1/2Nb_1/2)O₃-0.35PbTiO₃ (PINT65/35) (starting composition) single crystals were grown successfully through the solution Bridgman technique using PbO flux and PMNT67/33 seed crystals. Because of the composition variation, the final composition of achievable crystals is in a range of 0.32-0.34 with the corresponding T_c range of 265-269 °C. The (001) plates of as-grown PINT66/34 single crystals show high Curie temperature (T_c=269 °C) and rhombohedral-tetragonal phase transition temperature (T_rt=134 °C). Besides, good electrical properties with high dielectric constant (ε>3000), low dielectric loss (tan δ∼1.2%), high piezoelectric constant (d₃₃∼2000 pC/N) and large electromechanical coupling factor (k_t≈59%) at room temperature have been obtained on the (001) plates. The sound velocity, acoustic impedance and other piezoelectric parameters were also measured on the (001) plates in this study, which provide us more detailed information about PINT66/34 single crystals.