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481.
It is known that the T-dual of a circle bundle with H-flux (given by a Neveu-Schwarz 3-form) is the T-dual circle bundle with dual H-flux. However, it is also known that torus bundles with H-flux do not necessarily have a T-dual which is a torus bundle. A big puzzle has been to explain these mysterious missing T-duals. Here we show that this problem is resolved using noncommutative topology. It turns out that every principal T2-bundle with H-flux does indeed have a T-dual, but in the missing cases (which we characterize), the T-dual is non-classical and is a bundle of noncommutative tori. The duality comes with an isomorphism of twisted K-theories, just as in the classical case. The isomorphism of twisted cohomology which one gets in the classical case is replaced by an isomorphism of twisted cyclic homology.VM was supported by the Australian Research Council.JR was partially supported by NSF Grant DMS-0103647, and thanks the Department of Pure Mathematics of the University of Adelaide for its hospitality in January 2004, which made this collaboration possible.  相似文献   
482.
X-ray photoemission spectroscopy and X-ray magnetic circular dichroism have been used to study the growth process, chemical composition and magnetic character of iron deposited on ordered and disordered GaN(0 0 0 1) surfaces. On the (1 × 1) ordered surface the Fe grows uniformly but with disruption to the substrate surface, subsequently nitrogen desorbs from the surface, some of which diffuses into the Fe overlayer. The film is magnetically fractured, with high magnetic coercivity and broad switching fields. Conversely, the gallium rich disordered surface protects the underlying substrate from any disruption and initially induces non-uniform growth, the Fe clusters coalesce at ∼12 Å, to produce a uniform film with desirable magnetic characteristics. Films beyond this point (>12 Å) indicate sharp hysteresis loops with low coercivities. For the resultant film (36 Å) we measure a magnetic moment of 2.02 μB, in agreement with bulk bcc iron (2.068 μB.)  相似文献   
483.
We present a simulation study of the charging of a dust grain immersed in a plasma, considering the effect of thermionic electron emission from the grain. It is shown that the orbit motion limited theory is no longer reliable when electron emission becomes large: screening can no longer be treated within the Debye-Huckel approach and an attractive potential well can form, leading to the possibility of attractive forces on other grains with the same polarity. We suggest to perform laboratory experiments where emitting dust grains could be used to create nonconventional dust crystals or macromolecules.  相似文献   
484.
  总被引:2,自引:0,他引:2  
This work describes the development of a fast method for speciation analysis of triethyl-lead and tributyl-tin species in urine samples after in situ derivatization by tetraethyl- or tetrapropyl-borate reagents. The alkylation reaction is done in the aqueous and urine medium and the less-polar derivatives are extracted in hexane by liquid-liquid extraction. The species were extracted and the extract was efficiently collected from the aqueous phase after centrifugation. Finally, the organometallic species are separated by gas chromatography and determined from the emission signals of elemental lead and tin. Atomic lead and tin are formed from the organolead and organotin compounds during atomization of the column eluate in a microwave-induced helium plasma source. The simultaneous measurement of lead (Pb) at 405.780 nm and tin (Sn) at 303.419 nm was achieved by an atomic emission detector. Finally, the analytes were determined with satisfactory precision (<5%) and detection limits of 0.05 μg Pb/L and 0.48 μg Sn/L, respectively, when 10 mL of urine is extracted with 1 mL of hexane and 1 μL of extract is injected.  相似文献   
485.
486.
    
Orthogonally protected bis(aminomethyl)malonic acid ( 1 ) was synthesized and used as a key building block for the construction of cyclic peptide conjugates on a solid support. The applicability of the building block was demonstrated by preparation of 19 backbone cyclized/branched peptide conjugates of N-2-alkyl-5-(3-aminopropoxy)-1,2,3,4-tetrahydroisoquinoline as stereoisomeric pairs.  相似文献   
487.
    
The reactions of two mononuclear zinc complexes, [Zn(HL1)(H2O)2], 1 , and [ZnL4(H2O)], 7 , (H3L1 = Schiff base derived from 3-formylsalicylic acid and glycine, H2L4 = Schiff base derived from 2,6-diformyl-4-methylphenol and 1,2-diaminoethane), with Mg2+ has been studied. These complexes contain binucleating Schiff base ligands and have vacant coordination sites. For both compounds, substitution of zinc by magnesium has been observed in DMSO. Likewise, the Zn complex of H2L2 (Schiff base derived from salicylaldehyde and glycine) can be converted into the corresponding Mg compound. The following complexes were characterized by single-crystal X-ray analysis: [MgL3(H2O)3], 4 , [MgL2(H2O)2]n, 5 , [Mg(sal)2(H2O)2], 6 , and [MgL4(H2O)(CH3OH)], 8 (H2L3 = Schiff base derived from 5-bromosalicylaldehyde and glycine, Hsal = salicylaldehyde). The tri- and tetradentate N,O ligands H2L3 and H2L4 form discrete complex molecules in the solid state, while a carboxylate-bridged polymeric structure is formed by H2L2. In 4 and 8 the aqua ligands hydrogen bond with the deprotonated phenolate and carboxylate oxygen atoms, resulting in the formation of dimers. In 6 two aqua ligands, two phenolate oxygens and two aldehyde oxygens give rise to an O6 coordination sphere.  相似文献   
488.
  总被引:4,自引:0,他引:4       下载免费PDF全文
In this work we consider connected, complete and orientable hypersurfaces of the sphere with constant nonnegative -mean curvature. We prove that under subsidiary conditions, if the Gauss image of is contained in a closed hemisphere, then is totally umbilic.

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489.
    
Chemical modification of penicillin β-lactam ring was made.Six thiazolidine amides were produced through N4-C7 β-lactam ring opening of penicillin V methyl ester with various aliphatic,aromatic,and heterocyclic primary amines.Five 8-hydroxypenillic acid derivatives with side chains of methyl,propyl,benzyl,and diethylaminoethyl groups were yielded via β-lactam ring rearrangement from6-aminopenicillanic acid(6-APA).Parallel synthetic methods were used for the alkylation of8-hydroxypenillic acid and β-lactam ring opening of penicillin V methyl ester.The biological activities of the compounds were evaluated.  相似文献   
490.
    
We study weak analogues of the Paley-Wiener Theorem for both the scalar-valued and the operator-valued Fourier transforms on a nilpotent Lie group . Such theorems should assert that the appropriate Fourier transform of a function or distribution of compact support on extends to be ``holomorphic' on an appropriate complexification of (a part of) . We prove the weak scalar-valued Paley-Wiener Theorem for some nilpotent Lie groups but show that it is false in general. We also prove a weak operator-valued Paley-Wiener Theorem for arbitrary nilpotent Lie groups, which in turn establishes the truth of a conjecture of Moss. Finally, we prove a conjecture about Dixmier-Douady invariants of continuous-trace subquotients of when is two-step nilpotent.

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