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31.
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Daniel S. Covita Dimitrios F. Anagnostopoulos Hermann Fuhrmann Hubert Gorke Detlev Gotta Alexander Gruber Albert Hirtl Tomoichi Ishiwatari Paul Indelicato Thomas S. Jensen Eric-Olivier Le Bigot Valeri E. Markushin Michael Nekipelov Vladimir N. Pomerantsev Vladimir P. Popov Joaquim M. F. dos Santos Philipp Schmid Leopold M. Simons Marian Theisen Martino Trassinelli Joao F. C. A. Veloso Johann Zmeskal 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2018,72(4):72
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Rebeca G. Castillo Justin T. Henthorn Jeremy McGale Dimitrios Maganas Serena DeBeer 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(31):13065-13075
In recent years, X-ray emission spectroscopy (XES) in the Kβ (3p-1s) and valence-to-core (valence-1s) regions has been increasingly used to study metal active sites in (bio)inorganic chemistry and catalysis, providing information about the metal spin state, oxidation state and the identity of coordinated ligands. However, to date this technique has been limited almost exclusively to first-row transition metals. In this work, we present an extension of Kβ XES (in both the 4p-1s and valence-to-1s [or VtC] regions) to the second transition row by performing a detailed experimental and theoretical analysis of the molybdenum emission lines. It is demonstrated in this work that Kβ2 lines are dominated by spin state effects, while VtC XES of a 4d transition metal provides access to metal oxidation state and ligand identity. An extension of Mo Kβ XES to nitrogenase-relevant model complexes shows that the method is sufficiently sensitive to act as a spectator probe for redox events that are localized at the Fe atoms. Mo VtC XES thus has promise for future applications to nitrogenase, as well as a range of other Mo-containing biological cofactors. Further, the clear assignment of the origins of Mo VtC XES features opens up the possibility of applying this method to a wide range of second-row transition metals, thus providing chemists with a site-specific tool for the elucidation of 4d transition metal electronic structure. 相似文献
36.
Katarzyna Skrzypek Milou Groot Nibbelink Jolanda Liefers‐Visser Alexandra M. Smink Eleftheria Stoimenou Marten A. Engelse Eelco J. P. de Koning Marcel Karperien Paul de Vos Aart van Apeldoorn Dimitrios Stamatialis 《Macromolecular bioscience》2020,20(8)
Macroencapsulation of islets of Langerhans is a promising strategy for transplantation of insulin‐producing cells in the absence of immunosuppression to treat type 1 diabetes. Hollow fiber membranes are of interest there because they offer a large surface‐to‐volume ratio and can potentially be retrieved or refilled. However, current available fibers have limitations in exchange of nutrients, oxygen, and delivery of insulin potentially impacting graft survival. Here, multibore hollow fibers for islets encapsulation are designed and tested. They consist of seven bores and are prepared using nondegradable polymers with high mechanical stability and low cell adhesion properties. Human islets encapsulated there have a glucose induced insulin response (GIIS) similar to nonencapsulated islets. During 7 d of cell culture in vitro, the GIIS increases with graded doses of islets demonstrating the suitability of the microenvironment for islet survival. Moreover, first implantation studies in mice demonstrate device material biocompatibility with minimal tissue responses. Besides, formation of new blood vessels close to the implanted device is observed, an important requirement for maintaining islet viability and fast exchange of glucose and insulin. The results indicate that the developed fibers have high islet bearing capacity and can potentially be applied for a clinically applicable bioartificial pancreas. 相似文献
37.
Bornheim A Lipeles E Pappas SP Shapiro A Sun WM Weinstein AJ Masek G Paar HP Mahapatra R Morrison RJ Briere RA Chen GP Ferguson T Tatishvili G Vogel H Adam NE Alexander JP Bebek C Berkelman K Blanc F Boisvert V Cassel DG Drell PS Duboscq JE Ecklund KM Ehrlich R Gibbons L Gittelman B Gray SW Hartill DL Heltsley BK Hsu L Jones CD Kandaswamy J Kreinick DL Magerkurth A Mahlke-Krüger H Meyer TO Mistry NB Nordberg E Palmer M Patterson JR Peterson D Pivarski J Riley D Sadoff AJ Schwarthoff H 《Physical review letters》2002,88(23):231803
We report a new measurement of the Cabibbo-Kobayashi-Maskawa parameter Vub made with a sample of 9.7 x 10(6) BB- events collected with the CLEO II detector. Using heavy quark theory, we combine the observed yield of leptons from semileptonic B decay in the end-point momentum interval 2.2-2.6 GeV/c with recent CLEO II data on B-->X(s)gamma to find Vub = (4.08+/-0.34+/-0.44+/-0.16+/-0.24)x10(-3), where the first two uncertainties are experimental and the last two are from theory. 相似文献
38.
Dimitrios Bagkavos 《Annals of the Institute of Statistical Mathematics》2011,63(5):1019-1046
A new kernel based local linear estimate of the hazard rate, under the random right censorship model is proposed in this article.
We study its finite sample and asymptotic properties and prove its asymptotic normality. Then we bring in three popular methods
for bandwidth selection to the hazard setting as potential bandwidth choice rules for the estimate. We discuss their practical
implementation and through Monte Carlo simulations we use four distributions with different hazard rate shapes to compare
their performance over various sample sizes and levels of censoring. 相似文献
39.
Hans L. Bodlaender Dimitrios M. Thilikos 《Journal of Algorithms in Cognition, Informatics and Logic》1999,32(2):167
In this paper we investigate both the structure of graphs with branchwidth at most three, as well as algorithms to recognise such graphs. We show that a graph has branchwidth at most three if and only if it has treewidth at most three and does not contain the three-dimensional binary cube graph as a minor. A set of four graphs is shown to be the obstruction set for the class of graphs with branchwidth at most three. Moreover, we give a safe and complete set of reduction rules for the graphs with branchwidth at most three. Using this set, a linear time algorithm is given that verifies if a given graph has branchwidth at most three, and, if so, outputs a minimum width branch decomposition. 相似文献
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