Synthesis and X-ray analysis of 1-((1S)-phenylethyl)-azetidine-(2R)-piperidinamide

The crystal and molecular structure of a new azetidine-2-carboxylic amide derivative is described. The structure was solved by direct methods and refined by least squares methods toR1=0.0393 for 4264 reflections (withI>2(I)) The structure consists of two independent molecules which are chemically the same with slight differences in geometry. Crystal data: C₁₇H₂₄N₂O, monoclinic, space groupP2₁,a=8.3782(4),b=20.0342(13),c=9.7769(8) Å, =109.687(6)°,V=1545.1(2)ų,Z=4.     

On the spectrum of the sum of generators for a finitely generated group

Let Γ be a finitely generated group. In the group algebra ℂ[Γ], form the averageh of a finite setS of generators of Γ. Given a unitary representation π of Γ, we relate spectral properties of the operator π(h) to properties of Γ and π. For the universal representationπ _un of Γ, we prove in particular the following results. First, the spectrum Sp(π _un (h)) contains the complex numberz of modulus one iff Sp(π _un (h)) is invariant under multiplication byz, iff there exists a character such that η(S)={z}. Second, forS ⁻¹=S, the group Γ has Kazhdan’s property (T) if and only if 1 is isolated in Sp(π _un (h)); in this case, the distance between 1 and other points of the spectrum gives a lower bound on the Kazhdan constants. Numerous examples illustrate the results.     

An in vitro investigation of human enamel wear by restorative dental materials

A radiometric method was applied to assess enamel wear by another enameland by restorative materials. The radioactive enamel was submitted to wearin a machine which allows sliding motion of an antagonistic surface in contactwith the radioactive enamel. The enamel wear was evaluated by measuring thebeta-activity of ³²P transferred to water from this irradiatedtooth. Results obtained indicated that dental porcelains cause pronouncedenamel wear when compared with that provoked by another natural enamel orby resin materials. Resin materials caused less enamel wear than another naturalenamel. Vickers microhardness data obtained for antagonistic materials showeda correlation with the wear caused to the enamel.     

Two-photon spectroscopy of the low-lying singlet states of naphthalene and acenaphthene

Two-photon excitation spectra of naphthalene and acenaphthene have been measured up to 50000 cm^?1. In naphthalene. three two-photon allowed states are observed for which the symmetry assignment is confirmed by polarization. The corre- sponding transitions are also seen in acenaphthene. The experimental data are in excellent agreement with theoretical predictions.     

Construction of functional porphyrin polystyrene nano-architectures by ATRP

A series of mono-functionalized metallo-porphyrin polystyrenes have been synthesized using atom transfer radical polymerization and their self-assembling behavior was studied by electron microscopy showing that the polystyrene tail-length influences the aggregate architecture.