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51.
Dan Xie Yuan Sang Dan-Hong Wang Wan-Yue Diao Fang-Yu Tao Chang Liu Prof. Jia-Wei Wang Prof. Hai-Zhu Sun Prof. Jing-Ping Zhang Prof. Xing-Long Wu 《Angewandte Chemie (International ed. in English)》2023,62(7):e202216934
Uncontrolled dendrites growth and serious parasitic reactions in aqueous electrolytes, greatly hinder the practical application of aqueous zinc-ion battery. On the basis of in situ-chemical construction and performance-improving mechanism, multifunctional fluoroethylene carbonate (FEC) is introduced into aqueous electrolyte to construct a high-quality and ZnF2-riched inorganic/organic hybrid SEI (ZHS) layer on Zn metal anode (ZMA) surface. Notably, FEC additive can regulate the solvated structure of Zn2+ to reduce H2O molecules reactivity. Additionally, the ZHS layer with strong Zn2+ affinity can avoid dendrites formation and hinder the direct contact between the electrolyte and anode. Therefore, the dendrites growth, Zn corrosion, and H2 evolution reaction on ZMA in FEC-included ZnSO4 electrolyte are highly suppressed. Thus, ZMA in such electrolyte realize a long cycle life over 1000 h and deliver a stable coulombic efficiency of 99.1 % after 500 cycles. 相似文献
52.
Kou-Lin Zhang Yan Chang Li-Min Yuan Guo-Wang Diao 《Journal of solid state chemistry》2011,184(5):1263-1272
One homochiral 1D coordination polymer [Cu(ATIBDC)(2,2′-bipy)]·3H2O·CH3OH (1) and three achiral 1D coordination polymers: [Cd(ATIBDC)(2,2′-bipy)(H2O)]·3H2O (2), [Cd(ATIBDC)(phen)(H2O)]·4H2O (3), and [Mn(ATIBDC)(phen)2]·5H2O (4) have been synthesized and characterized (H2ATIBDC=5-amino-2,4,6-triiodoisophthalic acid, 2,2′-bipy=2,2′-bipyridine, and phen=1,10-phenanthroline). Extended high dimensional network architectures are further constructed with the help of weak secondary interactions, such as hydrogen bonding, aromatic stacking, and halogen bonding (C-I…π and C-I…N/O). Complex 1 crystallizes in the monoclinic system with chiral space group P2(1) and exhibits a right-handed 21 helical chain structure. The homochirality of 1 was confirmed by CD spectrum. Interestingly, two new configurations of decameric water cluster are found in 3 and 4. The acyclic tetrameric cluster (H2O)3(CH3OH) in 1 and (H2O)4 in 2 array into highly ordered helical infinite chains. Thermal stabilities of all the complexes have been studied. Solid state fluorescent properties of the Cd(II) complexes have been explored. 相似文献
53.
A rapid, sensitive and environmentally friendly method for the analysis of 14 anilines in water samples by dispersive liquid–liquid
microextraction based on solidification of floating organic drop (DLLME-SFO) prior to gas chromatography–mass spectrometry
(GC-MS) was developed and optimized. In the proposed method, cyclohexane was used as the extraction solvent as its toxicity
was much lower than that of the solvent usually used in dispersive liquid–liquid microextraction (DLLME). In the optimized
conditions, the method exhibited good analytical performance. Based on a signal-to-noise ratio of 3, limits of detection for
anilines were in the range of 0.07 to 0.29 μg L−1, and the linear range was 0.5–200 μg L−1 with regression coefficients (r
2) higher than 0.9977. It was efficient for qualitative and quantitative analysis of anilines in water samples. The relative
standard deviations varied from 2.9 to 8.6 % depending on different compounds indicating good precision. Tap water and river
water were selected for evaluating the application to real water samples. The relative recoveries of anilines for the two
real samples spiked with 10 μg L−1 anilines were in the scope of 78.2–114.6 % and 77.3–115.6 %, respectively. 相似文献
54.
A 1 064-nm pulsed coherent Doppler lidar (CDL) prototype is developed to measure short range wind speed in the lower altitude troposphere layer. The CDL system adopts an injection-seeded Nd:YAG laser with the pulse duration of 80 ns, single pulse energy of 0.5 mJ, and pulse repetition rate of 200 Hz. Speed calibration experiments are implemented to obtain a speed accuracy of 0.3 m/s using a hard target. Data analysis results show that the CDL system can obtain a line-of-sight wind velocity at a range of 30 to 500 m with the range resolution of 40 m and 38 pulses accumulation. 相似文献
55.
沉积物中石英ESR测年功率饱和效应的初步研究 总被引:2,自引:0,他引:2
介绍了几组沉积物中石英ESR功率饱和效应的基础实验情况,认为在用石英进行ESR测年时,微波功率的选择是一个重要参数,它直接影响累积剂量(AD)的求取,从而严重影响测年结果。在某些特定的地质环境下(如黄土,海洋沉积物),采用比较高的微波功率,可从沉积物石英的E'心得到较老沉积物(大于50万年)可信的ESR年代。 相似文献
56.
Partitionally assembled organosulfur monolayers were prepared by using an electrochemically assisted assembly method on gold films that were preseparated into two regions insulated from each other. Cyclic voltammetry (CV) and X-ray photoelectron spectroscopy (XPS) were employed to characterize the n-dodecanethiol (DDT) and the 11-mercaptoundecanoic acid (MUA) monolayers, which were separately assembled on different substrate regions. CV results indicated that both the DDT- and MUA-coated gold electrodes showed a blocking property toward the negatively charged redox probe Fe(CN)6(3-). However, when positively charged Ru(NH3)6(3+) was used as the redox probe, the MUA- and DDT-modified electrodes showed quasireversible and blocking CV features, respectively. These phenomena were attributed to different interactions between the negatively charged MUA surface and the negatively or positively charged redox probes. XPS spectra obtained on the MUA modified region exhibited an O(1s) peak and a small discrete C(1s) peak, which arose from the oxygen and the carbon atoms in the carboxylic acid groups, respectively. For the DDT-modified region, these two peaks were absent. CV and XPS experimental results provided strong evidence that different SAMs were selectively deposited onto different regions of the preexisting patterns of the substrate by electrochemically partitioned assembly. The partitionally assembled sulfur-based monolayers with different terminal groups were used to form location-selective nanoparticle assemblies. This electrochemically partitioned assembly technique has great potential in controllable constructions of molecular layers and nanostructures on different surface microarchitectures that are closely integrated on one substrate but insulated from each other. 相似文献
57.
混合超图是含有两类超边的超图,一类称为C-超边,一类称为D-超边,它们的区别主要体现在染色要求上.混合超图的染色,要求每一C-超边至少有两个点染相同的颜色,而每一D-超边至少有两个点染不同的颜色.所用的最大颜色数称为对应混合超图的上色数,所用的最小颜色数称为对应混合超图的下色数.上、下色数与边数有密切关系.作者在文献[2]中证明了具有最小上色数的3一致C-超图边数的一个下界为‘n(n-2)/3’,其中n为对应混合超图的顶点数.该文证明当n=2k 1时,该下界是可以达到的. 相似文献
58.
This study aims to reveal the laws of the relationship between fractional-order system and integer-order system. Meanwhile, delayed feedback control is introduced to control the fractional-order PMSG (permanent magnet synchronous generator) model of a wind turbine. First, the fractional-order mathematical model of PMSG is established. Next, numerical simulations under different system orders are given and the system dynamic behaviors are analyzed in detail. Then, the delayed feedback control method is introduced to control the fractional-order PMSG and the control results when different parameters vary are analyzed. Complex dynamics are presented and some interesting phenomena are discovered. It is found that the system order influences the dynamics of the system in many aspects such as chaos pattern, bifurcation behavior, period window, shape and size of strange attractor. The delayed time, feedback gain, feedback limitation, system order can obviously influence the control result except the initial state of the system. Moreover, the feedback limitation has a minimum to successfully control the system to stable states and the system order also has a maximum to do so. 相似文献
59.
The inclusion complexation behavior of the dye guest molecule neutral red with three kinds of water-soluble p-sulfonated calix[n]arene sodium (n=4,6,8) was investigated. p-Sulfonated calix[4,6,8]arene sodium (pSC4, pSC6, pSC8) can react with neutral red to form inclusion
complexes, which were confirmed by UV-vis absorption and fluorescence spectroscopy. Fluorescence spectroscopy experiments
were performed in pH=4.6 acetic buffer solutions at 25 °C to calculate the stability constants (K
S) for the stoichiometric 1:1 inclusion complexes of pSC4, pSC6 and pSC8 with neutral red. The thermodynamic parameters for
the inclusion complexes were determined through a van’t Hoff analysis. Formation of the inclusion complexes of pSC4, pSC6
and pSC8 with neutral red was driven by favorable enthalpic changes with their accompanying negative entropy changes. The
complex stability constants monotonically increased with the number of phenolic units in the calixarene ring, which was attributed
mainly to electrostatic interactions and hydrogen bonding, rather than to the cavity size. 相似文献
60.