全文获取类型
收费全文 | 6523篇 |
免费 | 503篇 |
国内免费 | 359篇 |
专业分类
化学 | 4022篇 |
晶体学 | 58篇 |
力学 | 310篇 |
综合类 | 40篇 |
数学 | 827篇 |
物理学 | 2128篇 |
出版年
2024年 | 17篇 |
2023年 | 77篇 |
2022年 | 240篇 |
2021年 | 214篇 |
2020年 | 258篇 |
2019年 | 207篇 |
2018年 | 175篇 |
2017年 | 167篇 |
2016年 | 261篇 |
2015年 | 274篇 |
2014年 | 257篇 |
2013年 | 437篇 |
2012年 | 434篇 |
2011年 | 511篇 |
2010年 | 326篇 |
2009年 | 320篇 |
2008年 | 378篇 |
2007年 | 364篇 |
2006年 | 328篇 |
2005年 | 281篇 |
2004年 | 228篇 |
2003年 | 195篇 |
2002年 | 165篇 |
2001年 | 141篇 |
2000年 | 86篇 |
1999年 | 99篇 |
1998年 | 59篇 |
1997年 | 53篇 |
1996年 | 69篇 |
1995年 | 57篇 |
1994年 | 71篇 |
1993年 | 56篇 |
1992年 | 49篇 |
1991年 | 39篇 |
1990年 | 41篇 |
1989年 | 30篇 |
1988年 | 22篇 |
1987年 | 23篇 |
1986年 | 18篇 |
1985年 | 30篇 |
1984年 | 40篇 |
1983年 | 16篇 |
1982年 | 35篇 |
1981年 | 19篇 |
1980年 | 22篇 |
1979年 | 37篇 |
1978年 | 26篇 |
1976年 | 23篇 |
1975年 | 15篇 |
1974年 | 20篇 |
排序方式: 共有7385条查询结果,搜索用时 15 毫秒
991.
Cristina Maria Di Bari 《Rendiconti del Circolo Matematico di Palermo》1915,39(1):65-78
We introduce several types of countable separation and we give necessary and sufficient conditions, in terms of measurability of some sets constructed by means of multifunctions, in order that a topological space satisfies such a property. We give a characterization of measurability of multifunctions in terms of their graphs. 相似文献
992.
993.
Nikhil M. Kriplani David P. Nackashi Christian J. Amsinck Neil H. Di Spigna Michael B. Steer Paul D. Franzon Ramon L. Rick Gemma C. Solomon Jeffrey R. Reimers 《Chemical physics》2006
Two efficient, physically based models for the real-time simulation of molecular device characteristics of single molecules are developed. These models assume that through-molecule tunnelling creates a steady-state Lorentzian distribution of excess electron density on the molecule and provides for smooth transitions for the electronic degrees of freedom between the tunnelling, molecular-excitation, and charge-hopping transport regimes. They are implemented in the fREEDA™ transient circuit simulator to allow for the full integration of nanoscopic molecular devices in standard packages that simulate entire devices including CMOS circuitry. Methods are presented to estimate the parameters used in the models via either direct experimental measurement or density-functional calculations. The models require 6–8 orders of magnitude less computer time than do full a priori simulations of the properties of molecular components. Consequently, molecular components can be efficiently implemented in circuit simulators. The molecular-component models are tested by comparison with experimental results reported for 1,4-benzenedithiol. 相似文献
994.
Nonisothermal kinetics of the solid‐solid phase transition in (n‐C10H21NH3)2ZnCl4(C10Zn), (n‐C16H33NH3)2ZnCl4(C16Zn) and their binary system were determined by Kissinger and Ozawa methods from DSC measurements. The activation energy Ea of the binary system shows a waving dependence on WC10Zn%, which is caused by not only an intermediate (C10H21NH3)(n‐C16H33NH3)ZnCl4 but also three solid solution ranges (α, β, γ) in the phase diagram of C10Zn‐C16Zn. The variations of the layer d‐spacing are also convenient for the above result. 相似文献
995.
Funk T Kennepohl P Di Bilio AJ Wehbi WA Young AT Friedrich S Arenholz E Gray HB Cramer SP 《Journal of the American Chemical Society》2004,126(18):5859-5866
We show that X-ray magnetic circular dichroism (XMCD) can be employed to probe the oxidation states and other electronic structural features of nickel active sites in proteins. As a calibration standard, we have measured XMCD and X-ray absorption (XAS) spectra for the nickel(II) derivative of Pseudomonas aeruginosa azurin (NiAz). Our analysis of these spectra confirms that the electronic ground state of NiAz is high-spin (S = 1); we also find that the L(3)-centroid energy is 853.1(1) eV, the branching ratio is 0.722(4), and the magnetic moment is 1.9(4) mu(B). Density functional theory (DFT) calculations on model NiAz structures establish that orbitals 3d(x2-y2) and 3d(z2) are the two valence holes in the high-spin Ni(II) ground state, and in accord with the experimentally determined orbital magnetic moment, the DFT results also demonstrate that both holes are highly delocalized, with 3d(x2-y2) having much greater ligand character. 相似文献
996.
997.
Recently several theoretical studies have examined oxygen adsorption on the clean, reduced TiO2(110) surface. However the photocatalytic behavior of TiO2 and the scavenging ability of oxygen are known to be influenced by the presence of surface hydroxyls. In this paper the chemistry of O2 on the hydroxylated TiO2 surface is investigated by means of first-principles total energy calculations and molecular dynamics (MD) simulations. The MD trajectories show a direct, spontaneous reaction between O2 and the surface hydroxyls, thus supporting the experimental hypothesis that the reaction does not necessarily pass through a chemisorbed O2 state. Following this reaction, the most stable chemisorbed intermediates are found to be peroxide species HO2 and H2O2. Although these intermediates are very stable on the short time scale of MD simulations, the energetics suggests that their further transformation is connected to a new 300 K feature observed in the experimental water temperature programmed desorption (TPD) spectrum. The participation of two less stable intermediate states, involving terminal hydroxyls and/or chemisorbed water plus oxygen adatoms, to the desorption process, is not supported by the total energy calculations. Analysis of the projected density of states, however, suggests the possibility that these intermediates have a role in completing the surface oxidation immediately before desorption. 相似文献
998.
Metal–organic frameworks (MOFs) are promising alternative precursors for the fabrication of heteroatom‐doped carbon materials for energy storage and conversion. However, the direct pyrolysis of bulk MOFs usually gives microporous carbonaceous materials, which significantly hinder the mass transportation and the accessibility of active sites. Herein, N‐doped carbon aerogels with hierarchical micro‐, meso‐, and macropores were fabricated through one‐step pyrolysis of zeolitic imidazolate framework‐8/carboxymethylcellulose composite gel. Owing to the hierarchical porosity, high specific surface area, favorable conductivity, excellent thermal and chemical stability, the as‐prepared N‐doped carbon aerogel exhibits excellent oxygen reduction reaction (ORR) activity, long‐term durability, and good methanol tolerance in alkaline medium. This work thus provides a new way to fabricate new types of MOF‐derived carbon aerogels for various applications. 相似文献
999.
利用电导法研究了烷基三甲基溴化铵表面活性剂(CnTAB,n=12,14,16),即十二烷基三甲基溴化铵(DTAB),十四烷基三甲基溴化铵(TTAB)和十六烷基三甲基溴化铵(CTAB),在混合极性溶剂乙二醇/水(体积分数0~40%)中的胶团化行为。考察了温度对胶团形成的影响,应用相分离模型估算了三个表面活性剂的胶团热力学参数。结果表明临界胶团浓度(cmc)和反离子解离度(α)都随乙二醇组分的增加而增大。在乙二醇/水混合溶剂中胶团形成的标准吉布斯自由能相差很小,混合焓都是负值,而混合熵都为正值,说明焓-熵补偿效应在胶团形成中起主导作用。 相似文献
1000.
Cordaro M Di Donna L Grassi G Maiuolo L Mazzotti F Perri E Sindona G Tagarelli A 《European journal of mass spectrometry (Chichester, England)》2004,10(5):691-697
An evaluation of the gas-phase ion chemistry of rotenone (1) by electrospray ionisation (ESI) mass spectrometry (MS) and tandem mass spectrometry (MS2) is presented, aiming at providing tools for its determination in natural and biological matrices. The behaviour of its cycloadducts with benzonitrile-N-oxide (2) and 2,4,6-trimethylbenzonitrile-N-oxide (3) was also evaluated and the MS data thus obtained have provided evidence into the mechanism of formation of the key product ion at m/z 192 which can be considered a marker in the MS and MS2 spectra of rotenone and its derivatives. 相似文献