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131.
132.
A traceless synthesis of 3,5-disubstituted 1,2,4-triazoles has been developed on polymeric supports. The synthetic process utilizes immobilized mesoionic 1,3-oxazolium-5-olates (munchnones) as key intermediates in the 1,3-dipolar cycloaddition reaction. The initial step in the synthesis involves reductive alkylation of phenylglycine methyl esters with Ameba resin. The resulting immobilized amino acid esters were subsequently acylated with a variety of carboxylic acid chlorides and subjected to hydrolysis with 15% KOH to yield the polymer-bound carboxylic acids. Finally, the cycloaddition between diethyl diazocarboxylate or 4-phenyl-4H-1,2,4-triazoline-3,5-dione and the polymer-bound munchnones generated from the corresponding carboxylic acids afforded the polymer-bound 3,5-disubstituted 1,2,4-triazoles. Cleavage from the polymeric support using trifluoroacetic acid gave the desired 3,5-disubstituted 1,2,4-triazoles with excellent yield and high purity. 相似文献
133.
Syntheses of alkali metal adducts [LVO(2)M(H(2)O)(n)] (1-7) (M = Na(+), K(+), Rb(+), and Cs(+); L = L(1)(-)L(3)) of anionic cis-dioxovanadium(V) species (LVO(2)(-)) of tridentate dithiocarbazate-based Schiff base ligands H(2)L (S-methyl-3-((5-(R-2-hydroxyphenyl))methyl)dithiocarbazate, R = H, L = L(1); R = NO(2), L = L(2); R = Br, L = L(3)) have been reported. The LVO(2)(-) moieties here behave like an analogue of carboxylate group and have displayed interesting variations in their binding pattern with the change in size of the alkali metal ions as revealed in the solid state from the X-ray crystallographic analysis of 1, 3, 6, and 7. The compounds have extended chain structures, forming ion channels, and are stabilized by strong Coulombic and hydrogen-bonded interactions. The number of coordinated water molecules in [LVO(2)M(H(2)O)(n)] decreases as the charge density on the alkali metal ion decreases (n = 3.5 for Na(+) and 1 for K(+) and Rb(+), while, for Cs(+), no coordinated water molecule is present). In solution, compounds 1-7 are stable in water and methanol, while in aprotic solvents of higher donor strengths, viz. CH(3)CN, DMF and DMSO, they undergo photoinduced reduction when exposed to visible light, yielding green solutions from their initial yellow color. The putative product is a mixed-oxidation (mu-oxo)divanadium(IV/V) species as revealed from EPR, electronic spectroscopy, dynamic (1)H NMR, and redox studies. 相似文献
134.
The necessity for more sustainable industrial chemical processes has internationally been agreed upon. During the last decade, the scientific community has responded to this urgent need by developing novel sustainable methodologies targeted at molecular transformations that not only produce reduced amounts of byproducts, but also by the use of cleaner and renewable energy sources. A prime example is the electrochemical functionalization of organic molecules, by which toxic and costly chemicals can be replaced by renewable electricity. Unrivalled levels of resource economy can thereby be achieved via the merger of metal-catalyzed C–H activation with electrosynthesis. This perspective aims at highlighting the most relevant advances in metallaelectro-catalysed C–H activations, with a particular focus on the use of green solvents and sustainable wind power and solar energy until June 2020.The merger of C–H activation with electrosynthesis, powered by renewable energies and resources, will guide towards a sustainable future. 相似文献
135.
Krishna C. Majumdar Swapan K. Samanta 《Monatshefte für Chemie / Chemical Monthly》2002,133(9):1187-1192
Summary. 5-(Cyclohex-2-enyl)-1,3-dimethyl-6-hydroxyuracil undergoes regioselective heterocyclization to afford fused tricyclic heterocycles
upon treatment with bromine and m-CPBA. However, the same substrate furnished bridged tricyclic heterocycles when treated with N-iodosuccinimide and conc. H2SO4 and a mixture of bridged tricyclic heterocycles and fused tricyclic heterocycles when treated with hexamine hydrotribromide
or pyridine hydrotribromide.
Corresponding author. E-mail: kcm@klyuniv.ernet.in
Received September 27, 2001. Accepted (revised) December 3, 2001 相似文献
136.
Krishna C. Majumdar Swapan K. Samanta 《Monatshefte für Chemie / Chemical Monthly》2002,36(6):1187-1192
5-(Cyclohex-2-enyl)-1,3-dimethyl-6-hydroxyuracil undergoes regioselective heterocyclization to afford fused tricyclic heterocycles upon treatment with bromine and m-CPBA. However, the same substrate furnished bridged tricyclic heterocycles when treated with N-iodosuccinimide and conc. H2SO4 and a mixture of bridged tricyclic heterocycles and fused tricyclic heterocycles when treated with hexamine hydrotribromide or pyridine hydrotribromide. 相似文献
137.
Swapan K. Ghosh Alok Samanta B. M. Deb 《International journal of quantum chemistry》1997,62(5):461-465
A new local density functional approach for the calculation of correlation energies of many-electron atomic systems is proposed by using the exact results for the correlation energy of a two-electron system bound by a harmonic oscillator external potential. This is motivated by the fact that the correlation energy is a universal functional of the electron density, and the form of this functional is independent of the external potential. The calculated numerical results for the correlation energies show very good agreement with the standard values reported in the literature. © 1997 John Wiley & Sons, Inc. Int J Quant Chem 62: 461–465, 1997 相似文献
138.
139.
140.
K. Schwarz C. Samanta M. Fujiwara H. Rebel R. De Leo N. Matsuoka H. Utsunomiya H. Akimune I. Daito H. Fujimura F. Ihara K. Ishibashi Y. Maeda T. Yamanaka H. Yoshida A. Okihana T. Yoshimura P.K.J. van Aarle W.A.T. Uijen M. Ito Y. Sakuragi 《The European Physical Journal A - Hadrons and Nuclei》2000,7(3):367-375
Elastic scattering and inclusive breakup of 6Li particles on 12C, 58Ni, 90Zr, and 208Pb targets are measured at 100A MeV. The elastic scattering data are compared with single channel and Coupled Discretized
Continuum Channels calculations. The coupling-effect between the elastic and the breakup channels is important even at an
incident energy of 100A MeV and cannot be neglected. The inclusive breakup data are investigated for orbital dispersion effects
which are found to be less significant at 100A MeV. The longitudinal momentum distributions are broader than predicted by
theoretical expectations.
Received: 17 December 1999 / Revised version: 9 February 2000 相似文献