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排序方式: 共有122条查询结果,搜索用时 31 毫秒
111.
Yongsheng Zhang Ke Yu Deyan Peng Hongmei Hu Wei Bai Ziqiang Zhu 《Applied Surface Science》2006,253(2):792-796
A simple and reliable method has been developed for synthesizing finely patterned tin dioxide (SnO2) nanostructure arrays on silicon substrates. A patterned Au catalyst film was prepared on the silicon wafer by radio frequency (RF) magnetron sputtering and photolithographic patterning processes. The patterned SnO2 nanostructures arrays, a unit area is of ∼500 μm × 200 μm, were synthesized via vapor phase transport method. The surface morphology and composition of the as-synthesized SnO2 nanostructures were characterized by means of scanning electron microscopy (SEM) and X-ray diffraction (XRD). The mechanism of formation of SnO2 nanostructures was also discussed. The measurement of field emission (FE) revealed that the as-synthesized SnO2 nanorods, nanowires and nanoparticles arrays have a lower turn-on field of 2.6, 3.2 and 3.9 V/μm, respectively, at the current density of 0.1 μA/cm2. This approach must have a wide variety of applications such as fabrications of micro-optical components and micropatterned oxide thin films used in FE-based flat panel displays, sensor arrays and so on. 相似文献
112.
Xianju Zhou Lihui Weng Jianming Zhang Deyan Shen Jian Xu 《Journal of Polymer Science.Polymer Physics》2003,41(19):2290-2295
A novel transmittance change of poly(acrylamide‐co‐acrylic acid) hydrogel in a DC electric field was observed. Transmittance of a specimen increased when the electric field was on and decreased by removing the electric force. In certain cases, the sample was able to switch from white opaque to colorless transparent. The rate and extent of the transition depended on the applied electric potential, ambient temperature, and composition of the specimen. These observations are closely related to the dissociation of hydrogen bonding in the network induced by an external electric field. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 2290–2295, 2003 相似文献
113.
尼龙1010的远红外光谱研究 总被引:1,自引:0,他引:1
本文研究了结晶程度不同的尼龙1010远红外光谱的差异,对其谱带进行了经验归属。用分峰方法详细地研究了尼龙1010结晶程度的变化对其远红外谱带的位置、宽度和强度的影响。并对由不同退火方式得到的结晶样品的远红外光谱作了比较,由此证明了两者的结晶结构有所差异。 相似文献
114.
在研究了激光光束质量因子M^2理论及测量技术基础上,作者提出了一种新的用干涉测量光束质量因子M^2的理论,技术与方法。文中概述了该技术的理论基础、实验结果及误差分析。结果表明,该方法具有精度高,适用性强,测量简便等优点,有可能进一步仪器化并推广应用。 相似文献
115.
Dr. Yongjin Fang Dr. Deyan Luan Dr. Ye Chen Prof. Shuyan Gao Prof. Xiong Wen Lou 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(7):2666-2670
The construction of hybrid architectures for electrode materials has been demonstrated as an efficient strategy to boost sodium-storage properties because of the synergetic effect of each component. However, the fabrication of hybrid nanostructures with a rational structure and desired composition for effective sodium storage is still challenging. In this study, an integrated nanostructure composed of copper-substituted CoS2@CuxS double-shelled nanoboxes (denoted as Cu-CoS2@CuxS DSNBs) was synthesized through a rational metal–organic framework (MOF)-based templating strategy. The unique shell configuration and complex composition endow the Cu-CoS2@CuxS DSNBs with enhanced electrochemical performance in terms of superior rate capability and stable cyclability. 相似文献
116.
Dr. Weiren Cheng Dr. Xue Feng Lu Dr. Deyan Luan Prof. Xiong Wen Lou 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(41):18391-18396
Developing noble-metal-free bifunctional oxygen electrocatalysts is of great significance for energy conversion and storage systems. Herein, we have developed a transformation method for growing NiMn-based bimetal–organic framework (NiMn-MOF) nanosheets on multi-channel carbon fibers (MCCF) as a bifunctional oxygen electrocatalyst. Owing to the desired components and architecture, the MCCF/NiMn-MOFs manifest comparable electrocatalytic performance towards oxygen reduction reaction (ORR) with the commercial Pt/C electrocatalyst and superior performance towards oxygen evolution reaction (OER) to the benchmark RuO2 electrocatalyst. X-ray absorption fine structure (XAFS) spectroscopy and density functional theory (DFT) calculations reveal that the strong synergetic effect of adjacent Ni and Mn nodes within MCCF/NiMn-MOFs effectively promotes the thermodynamic formation of key *O and *OOH intermediates over active NiO6 centers towards fast ORR and OER kinetics. 相似文献
117.
Monodisperse and core-shell-structured SiO2@YBO3:Eu3+ spherical particles: synthesis and characterization 总被引:1,自引:0,他引:1
Y0.9Eu0.1BO3 phosphor layers were deposited on monodisperse SiO2 particles of different sizes (300, 570, 900, and 1200 nm) via a sol-gel process, resulting in the formation of core-shell-structured SiO2@Y0.9Eu0.1BO3 particles. X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), photoluminescence (PL), and cathodoluminescence (CL) spectra as well as lifetimes were employed to characterize the resulting composite particles. The results of XRD, FE-SEM, and TEM indicate that the 800 degrees C annealed sample consists of crystalline YBO3 shells and amorphous SiO2 cores, in spherical shape with a narrow size distribution. Under UV (240 nm) and VUV (172 nm) light or electron beam (1-6 kV) excitation, these particles show the characteristic 5D0-7F1-4 orange-red emission lines of Eu3+ with a quantum yield ranging from 36% (one-layer Y0.9Eu0.1BO3 on SiO2) to 54% (four-layer Y0.9Eu0.1BO3 on SiO2). The luminescence properties (emission intensity and color coordinates) of Eu3+ ions in the core-shell particles can be tuned by the coating number of Y0.9Eu0.1BO3 layers and SiO2 core particle size to some extent, pointing out the great potential for these particles applied in displaying and lightening fields. 相似文献
118.
Deyan Lesigyarski Žiga Šmit Boika Zlateva-Rangelova Kristina Koseva Ivelin Kuleff 《Journal of Radioanalytical and Nuclear Chemistry》2013,295(3):1605-1619
Using PIXE (proton induced X-ray emission), PIGE (proton induced gamma emission) and ICP-AES (inductively coupled plasma-atomic emission spectroscopy) the concentrations of the 24 elements Al, As, Ba, Br, Ca, Cl, Co, Cr, Cu, Fe, K, Mg, Mn, Na, Pb, Rb, S, Sb, Si, Sn, Sr, Ti, Zn and Zr in 53 archaeological glass samples from South-Eastern Bulgaria, were determined. The glasses are dated from the 1st to 6th century AD. The analytical data showed the samples to be typical soda-lime-silica glass, with natron as flux. A rather broad range of aluminium, titanium and iron impurities was found, with a tendency for more impure glass in the later periods. The decolouring agents were antimony and manganese oxides, with Sb prevailing in earlier, and Mn in later glass. 相似文献
119.
We present ab initio calculation within the framework of the density‐functional theory (DFT) on band structure and vibrational properties of bulk V2O5. The structure of V2O5 comes from optimization of the experimental data with lattice parameters fixed. The band structure of the optimized structure has been calculated, and the result fits the experimental data very well and also gives similar results as those calculated by other methods. The phonon eigenwavenumbers of the Γ‐ point of V2O5 bulk have been calculated ab initio in density‐functional perturbation theory (DFPT). The calculated vibrational wavenumbers are in good agreement with observed infrared and Raman wavenumbers, and the predictive full phonon dispersion of bulk V2O5 has also been obtained. Further we calculated the Raman spectrum of vanadium pentoxide (V2O5) powder sample using the obtained Raman susceptibility. Calculated and measured intensities show overall good agreement. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
120.
Via a simple wet chemical etching followed by stearic acid modification, the presence of synergistic binary structures at micro- and nanometer scales and stearic acid bestows superhydrophobic property on steel and aluminum alloy surfaces. The as-prepared surfaces show superhydrophobic not only for pure water but also for corrosive liquids such as acid, basic and salt solutions. The stable superhydrophobicity of steel and aluminum alloy surfaces will extend their applications as engineering materials. 相似文献