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111.
Christos Christodouleas Demetrios Xenides Theodore E. Simos 《Journal of computational chemistry》2010,31(2):412-420
A test set of 10 molecules (open and ring forms of ozone and sulfur dioxide as well as water and hydrogen sulfide and their respective fluoro‐ and chloro‐substituted analogs) of specific atmospheric interest has been formed as to assess the performance of various density functional theory methods in (hyper)polarizability calculations against well‐established ab initio methods. The choice of these molecules was further based on (i) the profound change in the physics between isomeric systems, e.g., open (C2v) and ring (D3h) forms of ozone, (ii) the relation between isomeric forms, e.g., open and ring form of sulfur dioxide (both of C2v symmetry), and (iii) the effect of the substitution, e.g., in fluoro‐ and chloro‐substituted water analogs. The analysis is aided by arguments chosen from the information theory, graph theory, and pattern recognition fields of Mathematics: In brief, a multidimensional space is formed by the methods which are playing the role of vectors with the independent components of the electric properties to act as the coordinates of these vectors, hence the relation between different vectors (e.g., methods) can be quantified by a proximity measure. Results are in agreement with previous studies revealing the acceptable and consistent behavior of the mPW1PW91, B3P86, and PBE0 methods. It is worth noting the remarkable good performance of the double hybrid functionals (namely: B2PLYP and mPW2PLYP) which are for the first time used in calculations of electric response properties. © 2009 Wiley Periodicals, Inc. J Comput Chem 2010 相似文献
112.
Peleg O Bartal G Freedman B Manela O Segev M Christodoulides DN 《Physical review letters》2007,98(10):103901
We study wave dynamics in honeycomb photonic lattices, and demonstrate the unique phenomenon of conical diffraction around the singular diabolical (zero-effective-mass) points connecting the first and second bands. This constitutes the prediction and first experimental observation of conical diffraction arising solely from a periodic potential. It is also the first study on k space singularities in photonic lattices. In addition, we demonstrate "honeycomb gap solitons" residing in the gap between the second and the third bands, reflecting the special properties of these lattices. 相似文献
113.
Laser-induced breakdown spectroscopy (LIBS) has emerged in the past ten years as a promising technique for analysis and characterization
of the composition of a broad variety of objects of cultural heritage including painted artworks, icons, polychromes, pottery,
sculpture, and metal, glass, and stone artifacts. This article describes in brief the basic principles and technological aspects
of LIBS, and reviews several test cases that demonstrate the applicability and prospects of LIBS in the field of archaeological
science. 相似文献
114.
Zavatta et al. [A. Zavatta, S. Viciani, M. Bellini, Science 306 (2004) 660; A. Zavatta, S. Viciani, M. Bellini, Phys. Rev. A 72 (2006) 023820], using parametric down-conversion, have carried out experiments to conditionally generate a single-photon added coherent state. In this Letter, we propose an extension of their method in order to generate the two-photon added coherent state, and point the way toward generating m-photon added coherent states for m>2, all using only one down-conversion crystal. 相似文献
115.
Demetrios L. Antzoulakos 《Annals of the Institute of Statistical Mathematics》1999,51(2):323-330
A general technique is developed to study the waiting time distribution for the r-th occurrence of a success run of length k in a sequence of Markov dependent trials. Sooner and later waiting time problems are also discussed. 相似文献
116.
Markos V. Koutras Sotirios Bersimis Demetrios L. Antzoulakos 《Methodology and Computing in Applied Probability》2006,8(3):409-426
The most popular multivariate process monitoring and control procedure used in the industry is the chi-square control chart.
As with most Shewhart-type control charts, the major disadvantage of the chi-square control chart, is that it only uses the
information contained in the most recently inspected sample; as a consequence, it is not very efficient in detecting gradual
or small shifts in the process mean vector. During the last decades, the performance improvement of the chi-square control
chart has attracted continuous research interest. In this paper we introduce a simple modification of the chi-square control
chart which makes use of the notion of runs to improve the sensitivity of the chart in the case of small and moderate process
mean vector shifts.
相似文献
117.
Demetrios B. Papoulias 《The Journal of the Operational Research Society》1984,35(7):579-586
This paper discusses the relationship between the type of operational research current in economically developed countries and that applicable to countries in the developing world and concludes that the direct transfer of O.R. from the former to the latter is not as beneficial as is normally assumed. 相似文献
118.
Demetrios Voreades 《Surface science》1976,60(2):325-348
For the purpose of investigating how secondary electrons are produced in carbon, the correlation between energy-loss events and secondary electrons was studied experimentally by using the coincidence method. If a secondary electron is detected in coincidence with an electron transmitted through a thin film which has lost an amount of energy E, then the process causing this energy loss results in the production of secondary electrons. We established the existence of these coincidences and have taken inelastic and coincidence spectra for films of different thickness. We found that in carbon secondary electrons are predominantly produced as a result of energy losses of about 20 eV, with an efficiency of about 5%. The escape depth of secondary electrons was also estimated to be approximately 30 Å. 相似文献
119.
Cohen O Schwartz T Fleischer JW Segev M Christodoulides DN 《Physical review letters》2003,91(11):113901
We predict multiband vector solitons in nonlinear periodic systems, using photonic lattices as a prime example. The solitons consist of two optical fields arising from different bands of the transmission spectrum, which involve both bound state and radiation mode components. 相似文献
120.
Freedman B Carmon T Carvalho MI Segev M Christodoulides DN 《Physical review letters》2003,91(13):133902
We report the first experimental observation of optical spatial shock-wave pairs. The shock waves consist of two coupled kink and antikink beams that remain locked to each other throughout propagation in a nonlinear diffusion-driven photorefractive crystal. These coupled shock-wave pairs move undistorted at angles that fall outside their original angular sector of propagation. 相似文献