排序方式: 共有95条查询结果,搜索用时 15 毫秒
61.
A series of N‐(5‐chloro‐2‐hydroxyphenyl)‐(3/4/5‐substituted)‐salicylaldimines ( I – XI ) were synthesized using appropriate synthetic route. Their structures were characterized by FT‐IR, UV‐Visible, ESI‐MS, 1H and 13C NMR spectroscopic techniques and analytical methods. The crystal structure of N‐(5‐chloro‐2‐hydroxyphenyl)‐5‐bromosalicylaldimine ( V ) was determined by X‐ray diffraction at room temperature. Relationship between the melting points and the structures of the compounds was examined. Antimicrobial activity of the compounds was evaluated against Staphylococcus aureus, Staphylococcus epidermidis, Escherichia coli, Klebsiella pneumoniae, Pseudomonas aeruginosa, Proteus mirabilis. Antifungal activities were reported for Candida albicans. Schiff bases showed considerable antimicrobial activity against S. aureus, S. epidermidis and C. albicans. N‐(5‐Chloro‐2‐hydroxyphenyl)‐3‐hydroxy‐salicylaldimine ( II ) has the broadest and highest antimicrobial activity according to the others. 相似文献
62.
Four new y-shaped fluorophores of 4- {4,5-[2,2'-Bis(2,4,6-trimethoxyphenyl)vinyl]-1-H-imidazole-2-yl}benzonitrile 1a, 2-phenyl-{4,5-[2,2'-Bis(2,4,6-trimethoxyphenyl)vinyl]-1-H-imidazole} 1b, 2- (9-anthryl)-{4,5-[2,2'-Bis(2,4,6-trimethoxyphenyl)vinyl] }-1-H-imidazole 1c and 2- (4-nitrophenyl) - {4,5-[2,2'-Bis(2,4,6-trimethoxyphenyl)vinyl] -1-H-imidazole 1d which bear an imidazole core, were synthesized for the first time via intermediate 1,6-Bis(2,4,6-trimethoxyphenyl)hexa-1,5-diene-3,4-dion with different aldehydes. The structures of the new derivatives were confirmed by (1)H NMR, (13)C NMR and FT-IR. The optical properties such as absorption and emission maxima, Stokes' shift and quantum yield values were investigated in solvents of toluene, tetrahydrofuran and acetonitrile. The products show intense emission maxima in the range of 440-630?nm. The imidazole derivatives exhibited excellent photostabilities. 相似文献
63.
In this study,we aimed to determine the radiation parameters of some potential bioactive compounds.1-Aryl-3-dibenzylamino-propane-1-on hydrochloride type Mannich bases were synthesized via classical conventional heating method.Aryl part was changed as phenyl(C6H5),4-methylphenyl(4-CH3C6H4),4-fluorophenyl(4-FC6H4),4-nitrophenyl(4-NO2C6H4),4-chlorophenyl(4-ClC6H4),4-bromophenyl(4-BrC6H4),and 2-thienyl(C4H3S-2-yl).Mass attenuation coefficient(μm),effective atomic number(Zeff)and effective electron density(Nel)of compounds were determined experimentally and theoretically for at 8.040,8.910,13.40,14.96,17.48,19.61,22.16,24.94,32.19,36.38,44.48,50.38and 59.54keV photon energies by using an HPGe detector with a resolution of 182eV at 5.9keV.Radiation parameters of these compounds which can be anti-cancer drug candidate were given in the tables.The results show that phenyl ring behave like thiophene ring in terms of radiation absorption.It is thought that the results of study may drive allow the development of drug candidate new compounds in medical oncology. 相似文献
64.
Mesut Bilgi Demet Karaca Balta Binnur Aydogan Temel Gokhan Temel 《Journal of polymer science. Part A, Polymer chemistry》2018,56(24):2709-2714
This contribution describes a simple method for preparing polymeric nanoparticles using photodimerization of anthracene moieties on the side chain of terpolymers in dilute regime and transformation of obtained polymeric nanoparticles into pyrene functional nanoparticles via Menschutkin quaternization procedure. Subsequently, pyrene possessing polymeric nanoparticles are attached onto multiwalled carbon nanotube (MWCNT) surfaces by π–π stacking strategy. Gel permeation chromatography, thermal gravimetric analysis, ultraviolet–visible, and fluorescence spectroscopies are used to analyze modified nanoparticles and their precursors. Electron microscopy and dispersion studies show that pyrene-modified polymeric nanoparticles are able to interconnect various CNTs. © 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2018 , 56, 2709–2714 相似文献
65.
Demet ?zk?r Emel Bayol A. Ali G��rten Yavuz S��rme Fatma Kandemirli 《Chemical Papers》2013,67(2):202-212
The electrochemical behaviours of a brass alloy in 0.1 M nitric acid, including the hyamine inhibitor with concentrations between 2.5 × 10?4 M and 1.0 × 10?5 M, were studied. For this purpose, potentiodynamic polarisation, electrochemical impedance spectroscopy (EIS), linear polarisation resistance (LPR) techniques, and flame atomic absorption spectroscopy (FAAS) were utilised. The inhibitor molecules adsorbed on the brass surface were calculated to be in good agreement with the Langmuir adsorption isotherm and the standard free enthalpy of adsorption (??G ads ° ). Hyamine effectively improved the corrosion inhibition of brass and acted as a mixed-type inhibitor on alloy surfaces. The surface morphology of the alloy was also clarified by optical microscopic and SEM techniques. A theoretical study of the corrosion inhibition efficiency of hyamine molecule was carried out using density functional theory (DFT) at the B3LYP/6-311G(d,p) basis set level. 相似文献
66.
Synthesis and characterization of some novel chalcones by condensation of 2-acetylbenzofurane and various aromatic aldehydes is described. 相似文献
67.
Ay?eg��l A?k?n Salih Selman Et?z Demet Topalo?lu Yaz?c? Fatma T��msek 《Chromatographia》2011,73(1-2):109-115
The surface properties of polystyrene were investigated by inverse gas chromatography at infinite dilution region. The standard enthalpy (??H 0), entropy (??S 0) and free energy (??G 0) of adsorption were calculated for the adsorption of n-alkanes (n-hexane, n-heptane, n-octane, n-nonane, n-decane) and some polar probes (acetone, ethyl acetate, DCM, chloroform, THF) on polystyrene. Additionally, the dispersive (London) component of the surface free energy (?? S d ), surface Lewis acidity (K A ) and Lewis basicity (K D ) of polystyrene surface were determined. The values obtained for K A and K D by three different methods demonstrate that polystyrene surface has a basic nature. 相似文献
68.
Fatma T��msek Murat B?rek?i Demet Topalo?lu Yaz?c? Ay?eg��l A?k?n 《Chromatographia》2011,73(1-2):117-122
In this study, adsorption of some hydrocarbons on polystyrene was investigated with inverse gas chromatography. An experimental study was carried out above glass transition temperature. Thermodynamic parameters belonging to the polymer-solute system, weight fraction activity coefficients, Flory?CHuggins interaction parameter and solubility parameter for solute and polymer were calculated from the obtained data. The results were discussed with respect to the changes in hydrocarbon??s carbon number and temperature. 相似文献
69.
Compton scattering method has been used as a possible tool in the study of the properties of soil for agricultural purposes. In this study, the soil water is determined by using Compton scattering method. The soil sample was collected from Erzurum and a 2 × 2 in. NaI (Tl) scintillation detector measured Compton scattered radiation from the soil sample. The radioactive source used in the experiment was a 133Ba. The soil samples were irrigated by adding known quantities of water and a standard curve was constructed with the amount of water added versus Compton scattering intensity. It was observed that Compton scattering method in measurement of the soil water has advantages such as practical, inexpensive, non‐destructive and fast analysis. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
70.
Bromination of norbornene derivatives: synthesis of brominated norbornanes and norbornenes 总被引:1,自引:0,他引:1
The low and high temperature bromination of 7-bromobicyclo[2.2.1]hept-2-ene and 2,7-dibromobicyclo[2.2.1]hept-2-ene were studied and the possible role of a neighboring group participation in rearrangements was investigated. The formation mechanism of the isomers as well as the role of the substituent on the rearrangement were discussed. The structure elucidation of the formed compounds was achieved by NMR spectral data; particularly, the γ-gauche effect was discussed in connection with the configuration of the bromine atoms. 相似文献