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21.
V. G. Dedgaonkar S. Mitra Sunil Waghmare 《Journal of Radioanalytical and Nuclear Chemistry》1985,96(2):79-85
Halogen recoil following /n, / reaction has been studied in some heterocyclic systems. The organic yields are 60% for irradiation as solids: exceptions are dioxanide furoate /34%/ and 5-chloro isatoic anhydride /31%/. As solutions in 11 THF + benzene and 11 HTF+DMSO, these yields are lower by 10% and decrase further when only THF is the solvent. Mass-spectroscopy data revealed the possible fragmentation pattern. 相似文献
22.
Subhendu?Biswas Kamala?Mitra Bibhutosh?AdhikaryEmail author C.?Robert.?Lucas 《Transition Metal Chemistry》2005,30(5):586-592
Synthesis of six hydroxo-bridged binuclear manganese(III) complexes of formulae [MnL-X-MnL](ClO4) [X = OH (1–6)] along with a mononuclear manganese(III) complex (7) [Mn(L)(L′)(MeOH)2] [HL′ = 2-(2-hydroxy-phen-yl)benzimidazole] and two carboxylate-bridged binuclear manganese(III) complexes (8) and (9) are described. The complexes have been characterized by the combination of i.r., u.v.-vis spectroscopy, magnetic moments and by their redox properties. The electronic spectra of all the complexes exhibit almost identical features consisting of two d–d bands at ca. 550 and 600 nm, one MLCT band at ca.400 nm, together with two π–π* intra-ligand transitions at ca. 250 nm and ca.300 nm. Room temperature magnetic data range from μ = 2.7–3.0 BM indicates some super-exchange between the binuclear metal centers via bridging hydroxo/carboxylato groups. The X-ray crystal structure of the binuclear complex (5) revealed that it has a symmetric MnIIIN2O2 core bridged by a hydroxyl group. The X-ray analysis of the mononuclear complex (7) showed that the manganese-center possesses a distorted octahedral geometry. Electrochemical properties of hydroxo-bridged manganese(III) complexes (1–6) show identical features consisting of an irreversible and a quasi-reversible reduction corresponding to the Mn2III → MnIIMnIII → MnIIMnII couples in the voltammogram. It was found that electron withdrawing substituents on the ligand result in easier reduction. Complex (7) displays an irreversible reduction at 0.08 V and a reversible oxidation at 0.45V assignable to the MnIII → MnII reduction and MnIII → MnIV oxidation, respectively. The carboxylate-bridged compound (8) exhibits two irreversible oxidations at 0.4 and 0.6 V, probably due to Mn2III → MnIIIMnIV → MnIVMnIV oxidations and shows a quasi-reversible reductive wave at −0.85 V, tentatively assigned to Mn2III → MnIIMnIII reduction. 相似文献
23.
Aspects of hadronic dynamics which play a crucial role in proton decay (exclusive and inclusive) are examined in the context of a comprehensive Bethe-Salpeter (BS) formalism forq \(\bar q\) andqqq systems, under harmonic confinement. The BS model which is characterized by two basic parameters—the universal spring constant \(\tilde \omega \) GeV and the quark massm q =0.28 GeV, has already provided an impressive set of agreements in respect of a large number and variety of hadronic observables (mass spectra, and an extensive list of e.m. and pionic couplings of both mesons and baryons). TheSU(5) GUT parameters, on the other hand, are kept fixed at the ‘standard’ values, (see e.g. Langacker's review). The absolute normalization of the baryon, which is rather crucial in this case, is fixed with reference to the (topologically equivalent) process of its ‘dissociation’ into three quarks by a hard photon, which makes use of the structure function sum rule \(\int\limits_0^1 {dxF_2^p (x)/x = \sum {Q_i^2 } } \) , instead of the usual BS normalization (which amounts to the conservation of charge). Thee + inclusive rate, which is about three times that of thee +π0 mode, works out at0.54×10 ?33 yr ?1 which is smaller than most contemporary calculations by two orders of magnitude. Other exclusive modes are also consistent with the above estimate. The theoretical implications of these results vis a vis contemporary calculations as well as current experimental searches are discussed. 相似文献
24.
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26.
Brajagopal Samanta Joy Chakraborty C. R. Choudhury S. K. Dey D. K. Dey S. R. Batten P. Jensen Glenn P. A. Yap Samiran Mitra 《Structural chemistry》2007,18(1):33-41
We have reported herein the synthesis of three new Cu(II) complexes of tri- and tetradentate Schiff base ligands containing
N3 or N4 donor set along with terminal NNN− or SCN− ligands: [L1Cu(NCS)]ClO4 (1), [L2Cu(NCS)2] (2) and [L3Cu(NNN)]ClO4 (3) [L1 = NC5H4C(CH3)=N(CH2)3N=C(CH3)C5H4N, L2= Me2N–(CH2)3–N=C(CH3)C5H4N and L3 = NC5H4CH=N–(CH2)4–N=CHC5H4N]. The complexes have been systematically characterised by elemental, spectroscopic and electrochemical techniques. Antimicrobial
activities of the Schiff base ligands and their metal complexes have been studied using the disc diffusion method on the strains
of Candida tropicalis and Bacillus megaterium. Structures of all the complexes have been unequivocally established from single crystal X-ray diffraction analyses that
show the monomeric units containing a five-coordinated copper center in highly distorted square pyramidal geometry with thiocyanate
or azide anion coordinated as terminal ligand. The complexes 1 and 3 crystallise in monoclinic (P21/c) and 2 in triclinic (P-1) space group, respectively. 相似文献
27.
Treatment of the ligand 6‐aza‐2‐thiothymine (ATT, HL, 1 ) with palladium chloride in methanol forms the ionic complex [(HL)4Pd]Cl2·8MeOH ( 2 ), while its reaction with palladium iodide in same solvent produces the neutral complex trans‐[(HL)2PdI2]·2MeOH ( 3 ) in high yields. The reaction of 1 with Na2[PdCl4] in the presence of sodium acetate in a molar ratio of 2:1:2 and with platinum(II) chloride in presence of sodium acetate led to the dimer tetranuclear complexes [(L4Pd2)NaCl]2·8MeOH ( 4 ) and [L4Pt2Cl2]·6MeOH·H2O ( 5 ). The latter is the first PtIII complex of the ligand. All complexes were characterized by elemental analyses and IR spectroscopy and the crystal structures of 2 , 3 , 4 and 5 are determined by single‐crystal X‐ray diffraction. Crystal data for 2 at ?80 °C: triclinic space group , a = 1006.6(1), b = 1006.9(1), c = 1158.1(1) pm, α = 85.20(1)°, β = 83.84(1)°, γ = 88.91(1)°, Z = 1, R1 = 0.0278; for 3 at ?80 °C: triclinic space group , a = 490.5(1), b = 977.2(2), c = 1116.8(2) pm, α = 90.26(1)°, β = 102.33(1)°, γ = 96.08(1)°, Z = 1, R1 = 0.0394; for 4 at ?80 °C: orthorhombic space group Ccca, a = 1791.7(2), b = 1874.1(2), c = 2044.0(1) pm, Z = 4, R1 = 0.0341 and for 5 at ?80 °C: monoclinic space group P21/c, a = 1464.3(1), b = 2003.7(1), c = 1368.5(1) pm, β = 95.66(1)°, Z = 4, R1 = 0.0429. 相似文献
28.
Joy Chakraborty Brajagopal Samanta Andrei S. Batsanov Joan Ribas M. Salah El Fallah Samiran Mitra 《Structural chemistry》2006,17(4):401-407
A ligand–metal–ligand type co-ordination polymer [Ni (C6H12N4)(NCS)2(H2O)2]
n
has been synthesised under controlled hydrothermal conditions. Here 1,3,5,7-tetraazatricyclo[3.3.1]decane [or hexamethylenetetramine (hmt)] has been used as a μ-(N,N′) bidentate spacer molecule. The prepared polymeric complex has been characterised by elemental and spectral analyses. The structure has been confirmed by a single crystal X-ray diffraction study. Magneto-structural correlation has been drawn from cryomagnetic susceptibility measurements (2–300 K) which unequivocally reflects very weak magnetic spin interactions among the long distant octahedral Ni(II) metal centres mediated by hmt and weak hydrogen bonding interactions between the adjacent zigzag one-dimensional polymeric chains carrying into a two-dimensional infinite polymeric framework. 相似文献
29.
The feasibility of DNA microarray sensor technology as a routine technique of molecular pharmacology to perform high throughput drug screening and the advantages of directly labeled RNA for a high throughput experiment are presented in this paper. A novel, single-step direct chemical labeling method for DNA microarray target samples has been developed to reduce the sample amount, cost, time and error of the experiment by eliminating the need for enzyme mediated labeling. Reproducibility of the data for high throughput drug screening is demonstrated by monitoring differential gene expression of a set of 45 gene targets involved in the genotoxic stress response pathways. 相似文献
30.
The reaction of 3,6-diphenyl-1,2,4,5-tetrazine 1 with cis,cis-cycloocta-1,5-diene 7 has been studied with a view to preparing some interesting dihydropyridazine derivatives. Refluxing a mixture of 1 with excess of 7 in benzene solution for 8hr resulted in the formation of a mixture of products consisting of 1,4-diphenyl-10a-hydroperoxy-4a, 5,6,9,10,10a-hexahydrocycloocta[d]pyridazine (8, 27%) and 2,4a,5,6,8,10a,11,12-octahydro-1,4,7,10-tetraphenyldipyridazo[4,5-a:4',5'-e]cyclooctene ( However, when the reaction of 1 with 7 was carried out in refluxing benzene for nearly 40 hr, the products formed were a 14% yield of 8, a 17% yield of 9 and a 37% yield of 1,4-diphenyl-5,6,9,10-tetrahydrocycloocta[d]pyridazine (10). Neat heating of 1 with 7 around 150° for 10 hr, on the other hand, gave a 20% yield of 9, as the only isolable product. Thermolysis of 8 around 155° gave a mixture of products consisting of 2-oxocyclooct-5-enyl phenyl ketone N-benzoylhydrazone (15,30%) and 1H-3-phenyl-4,5,8,9-tetrahydrocycloocta[d]pyrazole (16, 22%). Nickel peroxide-oxidation of the adduct 9 gave a 67% yield of 1,4,7,10-tetraphenyldipyridazo[4,5-a:4',5'-e]cyclooctene (27). Acetylation of 9, on the other hand, gave a 70% yield of 2,3,8,9-tetraacetyl-2,3,5,6,8,9,11,12-octahydro-1,4,7,10-tetraphenyldipyridazo[4,5-a:4',5'-e]cyclooctene(28). 相似文献