Influence of Rhodamine (B) doping on vibrational,morphological and absorption properties of poly(vinyl) alcohol

Contribution of Rhodamine B doping on the structural and optical properties of PVA is investigated here. With increasing doping wt%, Raman spectra show the disappearance of main PVA peaks revealing a decrease in crystallinity and breaking of bonds, which also results in modified surface morphology as seen from corresponding SEM measurements. Optical absorption measurements show the possibility of both direct and indirect transitions, also indicating strong modifications in optical properties as a result of doping fluorescent dye in the polymer host.     

Discreteness of space from the generalized uncertainty principle

Various approaches to Quantum Gravity (such as String Theory and Doubly Special Relativity), as well as black hole physics predict a minimum measurable length, or a maximum observable momentum, and related modifications of the Heisenberg Uncertainty Principle to a so-called Generalized Uncertainty Principle (GUP). We propose a GUP consistent with String Theory, Doubly Special Relativity and black hole physics, and show that this modifies all quantum mechanical Hamiltonians. When applied to an elementary particle, it implies that the space which confines it must be quantized. This suggests that space itself is discrete, and that all measurable lengths are quantized in units of a fundamental length (which can be the Planck length). On the one hand, this signals the breakdown of the spacetime continuum picture near that scale, and on the other hand, it can predict an upper bound on the quantum gravity parameter in the GUP, from current observations. Furthermore, such fundamental discreteness of space may have observable consequences at length scales much larger than the Planck scale.     

A Logical Approach to Entanglement

In this paper we innovate a logical approach to develop an intuition regarding the phenomenon of quantum entanglement. In the vein of the logic introduced we substantiate that particles that were entangled in the past will be entangled in perpetuity and thereby abide a rule that restricts them to act otherwise. We also introduce a game and by virtue of the concept of Nash equilibrium we have been able to show that entangled particles will mutually correspond to an experiment that is performed on any one of the particle.     

Discreteness of space from GUP II: Relativistic wave equations

Various theories of Quantum Gravity predict modifications of the Heisenberg Uncertainty Principle near the Planck scale to a so-called Generalized Uncertainty Principle (GUP). In some recent papers, we showed that the GUP gives rise to corrections to the Schrödinger equation, which in turn affect all quantum mechanical Hamiltonians. In particular, by applying it to a particle in a one-dimensional box, we showed that the box length must be quantized in terms of a fundamental length (which could be the Planck length), which we interpreted as a signal of fundamental discreteness of space itself. In this Letter, we extend the above results to a relativistic particle in a rectangular as well as a spherical box, by solving the GUP-corrected Klein–Gordon and Dirac equations, and for the latter, to two and three dimensions. We again arrive at quantization of box length, area and volume and an indication of the fundamentally grainy nature of space. We discuss possible implications.     

Completely random nanoporous Cu4O3–CuO–C composite thin films for potential application as multiple channel photonic band gap based filter in the telecommunication wavelengths

In 2003, Babin et al. theoretically predicted (J. Appl. Phys. 94:4244, 2003) that fabrication of organic–inorganic hybrid materials would probably be required to implement structures with multiple photonic band gaps. In tune with their prediction, we report synthesis of such an inorganic–organic nanocomposite, comprising Cu₄O₃–CuO–C thin films that experimentally exhibit the highest (of any known material) number (as many as eleven) of photonic band gaps in the near infrared. On contrary to the report by Wang et al. (Appl. Phys. Lett. 84:1629, 2004) that photonic crystals with multiple stop gaps require highly correlated structural arrangement such as multilayers of variable thicknesses, we demonstrate experimental realization of multiple stop gaps in completely randomized structures comprising inorganic oxide nanocrystals (Cu₄O₃ and CuO) randomly embedded in a randomly porous carbonaceous matrix. We report one step synthesis of such nanostructured films through the metalorganic chemical vapor deposition technique using a single source metalorganic precursor, Cu₄(deaH)(dea)(oAc)₅???(CH₃)₂CO. The films displaying multiple (4/9/11) photonic band gaps with equal transmission losses in the infrared are promising materials to find applications as multiple channel photonic band gap based filter for WDM technology.     

Effect of thermodiffusion on pH‐regulated surface charge properties of nanoparticle

Surface properties of nanoparticle are of high importance in the field of biotechnology, drug delivery and micro/nanofabrication. In this article, we developed a comprehensive theoretical model and subsequently solved that numerically to study the effect of thermodiffusion of ions on surface charge properties of nanoparticle. The theoretical study has been done considering silica nanoparticle for two aqueous solutions NaCl and KCl. The effect of solution pH in conjunction with nanoparticle temperature on surface charge density has been obtained for different salt concentrations (1, 10 and 100 mM) and nanoparticle size (diameter of 2 and 100 nm). It is observed from the results that with increasing temperature of the nanoparticle, the negative surface charge density gets higher due to increasing thermodiffusion effect. It is also found out that the magnitude of surface charge density is higher for KCl solution than NaCl solution under same condition which is attributed mostly due to less thermodiffusion of counterions for KCl than NaCl. Present study also shows that magnitude of surface charge density decreases with increasing nanoparticle size until it reaches a limiting value (called critical size) above which the effect of nanoparticle size on surface charge density is insignificant.     

Synthesis, photophysical and electrochemical properties of perfluoroisopropyl substituted binuclear phthalocyanine conjugated with a butadiyne linker

Synthesis of 1,3-butadiyne-bridged perfluoroisopropyl binuclear phthalocyanine 2 has been successfully achieved from unsymmetrical A₃B-type iodo-perfluoroisopropyl phthalocyanine by palladium-catalyzed cross-coupling with trimethylsilylacetylene and copper-catalyzed Glaser homo-coupling as key reactions. The dyad 2 essentially remains non-aggregated irrespective of solvent and concentration. Electrochemical analysis suggests oxidation is not possible whereas the molecule is more easily reduced. All the results are advantages for photodynamic therapy (PDT).     

Natural Small Molecules in Gastrointestinal Tract and Associated Cancers: Molecular Insights and Targeted Therapies

Gastric cancer is one of the most common cancers of the gastrointestinal tract. Although surgery is the primary treatment, serious maladies that dissipate to other parts of the body may require chemotherapy. As there is no effective procedure to treat stomach cancer, natural small molecules are a current focus of research interest for the development of better therapeutics. Chemotherapy is usually used as a last resort for people with advanced stomach cancer. Anti-colon cancer chemotherapy has become increasingly effective due to drug resistance and sensitivity across a wide spectrum of drugs. Naturally-occurring substances have been widely acknowledged as an important project for discovering innovative medications, and many therapeutic pharmaceuticals are made from natural small molecules. Although the beneficial effects of natural products are as yet unknown, emerging data suggest that several natural small molecules could suppress the progression of stomach cancer. Therefore, the underlying mechanism of natural small molecules for pathways that are directly involved in the pathogenesis of cancerous diseases is reviewed in this article. Chemotherapy and molecularly-targeted drugs can provide hope to colon cancer patients. New discoveries could help in the fight against cancer, and future stomach cancer therapies will probably include molecularly formulated drugs.     

Facile One‐Pot Multicomponent Synthesis of β‐Acetamido Ketones with Amberlyst‐15 as Heterogeneous Catalyst

The one‐pot multicomponent coupling of an aromatic aldehyde, an enolizable ketone or keto ester, acetonitrile, and acetyl chloride at room temperature in the presence of Amberlyst‐15 as catalyst affords β‐acetamido ketones in high yields. The inexpensive catalyst works under heterogeneous conditions and can be readily reused.     

The skeletal rearrangement of gold- and platinum-catalyzed cycloisomerization of cis-4,6-dien-1-yn-3-ols: pinacol rearrangement and formation of bicyclo[4.1.0]heptenone and reorganized styrene derivatives

With gold and platinum catalysts, cis-4,6-dien-1-yn-3-ols undergo cycloisomerizations that enable structural reorganization of cyclized products chemoselectively. The AuCl3-catalyzed cyclizations of 6-substituted cis-4,6-dien-1-yn-3-ols proceeded via a 6-exo-dig pathway to give allyl cations, which subsequently undergo a pinacol rearrangement to produce reorganized cyclopentenyl aldehyde products. Using chiral alcohol substrates, such cyclizations proceed with reasonable chirality transfer. In the PtCl2-catalyzed cyclization of 7,7-disubstituted cis-4,6-dien-1-yn-3-ols, we obtained exclusively either bicyclo[4.1.0]heptenones or reorganized styrene products with varied substrate structures. On the basis of the chemoselectivity/structure relationship, we propose that bicyclo[4.1.0]heptenone products result from 6-endo-dig cyclization, whereas reorganized styrene products are derived from the 5-exo-dig pathway. This proposed mechanism is supported by theoretic calculations.