莫来石轻质球形料结构与性能

对以铝矾土为主要原料制备获得的莫来石轻质球形料进行了系统的结构与性能研究,研究结果表明:轻质莫来石球形料的主要化学成分为Al2O3和SiO2,物相为莫来石相,球形颗粒表面莫来石柱状结晶交织排布,内部含有大量气孔,堆积密度为1.60 g/cm3,颗粒体积密度为1.75 g/cm3,显气孔率为38;,耐火度大于1790℃,800℃下导热系数为0.245 W/(m· K),热震5次后球形保持率大于95;.     

THE LINEAR ELIASHBERG EQUATION

Fn the present paper, the linear Eliashberg equation is converted into a new integral equation and from it, the following T_C formula is derived analytically in the weak coupling limit:T_c=28/πωlog·(πlog/π_c)μ^*/λ^*-μ^* exp{-1+λ/λ-μ^*}, where In γ=C=0.5772 is the Eater constant.     

树脂分离-氢化物发生-原子荧光光谱法测定中草药中不同形态的砷

本文建立了应用离子交换树脂分离技术结合氢化物发生 原子荧光光谱法测定中草药方剂原生药、残渣、悬浮态及可溶态中的三价及五价砷的方法。研究了树脂静态分离和动态分离的最佳条件 ,利用两种方法成功地对黄连解毒汤中的三价及五价砷进行了分离。考察了仪器的工作条件、试剂浓度、增感剂的选择及共存离子的干扰及消除方法。方法检出限为 89 1ng·L- 1 ,RSD为 1 4 % ,样品加标回收率为 91 1%～10 9 3%。     

氢化物发生-双道原子荧光光谱法同时测定中药中不同形态的砷和锑

建立了一种氢化物发生-双道原子荧光光谱法同时测定中药中As(Ⅲ),As(Ⅴ),Sb(Ⅲ)和Sb(Ⅴ)的方法。对实验条件进行了优化,在最佳工作条件下,砷和锑的检出限分别为0.090 3和0.057 8 μg·L-1,RSD分别为2.01%和1.39%。将本法成功应用于中药样品的形态分析,As(Ⅲ)和As(Ⅴ)的回收率分别为90.8%～98.2%和89.2%～102.0%,Sb(Ⅲ)和Sb(Ⅴ)的回收率分别为89.7%～102.0% 和90.3%～110.0%。     

Determination of trace inorganic selenium in organoselenium (selenosugar) oral nutrition liquids by graphite furnace atomic absorption spectrometry with hydride generation

 A method has been proposed for the determination of trace levels of inorganic selenium in organoselenium (selenosugar) oral nutrition liquids using hydride generation-graphite furnace atomic absorption spectrometry (HG-GFAAS), taking advantage of the fact that this organic selenium compound did not generate volatile hydride upon reduction. K₂S₂O₈ was selected for the decomposition of the compound in a boiling water bath. Selenium was found to give a sharp analytical signal upon reduction with NaBH₄ in 1.0 mol L^-1HCl medium. The characteristic mass giving an integrated absorbance of 0.0044 s was 21 pg. An absolute detection limit (3s) of 36 pg was obtained. The recovery was in the range of 94.2–102.1%. Less than parts per million levels of inorganic Se in the presence of organic selenium can be determined. Received: 7 November 1996/Revised: 13 January 1997/Accepted: 29 January 1997     

A型超导体的近似临界温度公式(Ⅱ)——μ*≠0情形

本文把作者在前一篇文章中对Eliashberg方程数值解进行的分析以及所得到的A型超导体的近似临界温度公式推广到μ^{*≠0情形。 关键词：}     

蒸气发生-原子荧光光谱法测定中草药中不同形态的汞

建立了蒸气发生-原子荧光光谱法测定中草药复方方剂原生药、残渣、悬浮态、可溶态的无机汞和有机汞的方法。研究了仪器的工作条件、试剂浓度、增感剂对汞原子荧光强度的影响及有机汞的氧化条件,探讨了共存离子对汞测定的干扰和消除方法,利用本方法成功地对万氏牛黄清心方剂中的汞进行了形态分析。方法检出限为7.6 ng·L-1,RSD为1.56%～3.28%,回收率为90.3%～110.3%。     

Determination of mercury in biological tissues by graphite-furnace atomic absorption spectrometry with an in-situ concentration technique.

A method has been described for the determination of total mercury by graphite-furnace atomic absorption spectrometry (GFAAS) using an in-situ concentration technique with a Pd-Zr coating and a chemical modifier. The characteristic mass, which gives an integrated absorbance of 0.0044 s, was found to be 42 pg and an absolute detection limit (3sigma) of 33 pg was obtained with the proposed modifier. The total mercury values in standard reference materials, including Mussel (GBW08571), Bovine liver (GBW08306), Peach leaf (GBW08501) and Tea leaf (GBW080001), were determined using the proposed method, and the results were consistent with reference values. The method had been successfully applied to the determination of mercury in biological tissue samples with a recovery range of 94-105%.     

基于分层引导滤波与最近邻正则化子空间的高光谱图像分类

针对高光谱图像中同质异谱现象造成的分类精度较低以及边缘像元在联合空间光谱信息分类时特征易混淆的问题,提出了基于分层引导滤波与最近邻正则化子空间的分类方法.利用主成分分析获得高光谱图像的第一主成分.以第一主成分为引导图像对高光谱图像执行分层引导滤波操作,引导滤波的边缘保护特性,有效阻隔了边缘处类间光谱信息的混淆,并减小了局部区域类内光谱的差异,最后将预处理后的高光谱图像送至最近邻正则化子空间分类器进行分类识别.在Indian Pines,Salinas以及GRSS_DFC_2013高光谱数据集上与现有的方法进行对比实验.结果表明,本文提出的方法在三个数据集上分别取得了98.63%,99.13%与99.42%的总体分类准确率,有着更优的分类精度与可视化效果.     

红球菌对煤中硫的脱除及对煤溶胀和抽提性质的影响

中国能源工业是以煤为主、多能互补的能源生产体系。为适应国民经济的发展速度,中国能源工业仍将保持快速发展的势头。煤炭的生产和利用中缺乏对污染物的有效控制将引起大气污染、酸雨等区域性环境问题,以及气候变化等全球环境问题。中国煤炭资源中约15％的原煤硫的质量分数高于2％;高硫煤利用所导致的环境问题已经成为制约中国经济和社会发展的因素之一。因此,开发有效而经济的煤炭脱硫方法具有重要的现实意义。