Spectroscopic imaging display and analysis.

A system for display of magnetic resonance (MR) spectroscopic imaging (SI) data is described which provides for efficient review and analysis of the multidimensional spectroscopic and spatial data format of this technique. Features include the rapid display of spectra from selected image voxels, formation of spectroscopic images, spectral and image data processing operations, methods for correlating spectroscopic image data with high resolution 1H MR images, and hardcopy facilities. Examples are shown for 31P and 1H spectroscopic imaging studies obtained in human and rat brain.     

Inertia-preserving secant updates

Corrections to the last two equations of Ref. 1 are given.     

Short-range order in miscible polymer blends: A monte carlo study

Local ordering in miscible binary polymer blends with strong attractive interactions between the two types of chains was investigated by computer simulation of allowable conformations on an incompressible cubic lattice. A tendency toward maximum ordering (in which chains pack in alternate parallel rows) is shown by the calculation of pair correlations and in “snapshots” of the mixtures. A specific directional interaction is not necessarily required for ordering. A comparison of these results with those recently obtained using mean-field theory is presented. The heat capacity of mixing was also calculated and found to be positive, with a value close to that reported experimentally.     

Models of linear logic

We engage a study of nonmodal linear logic which takes times ⊗ and the linear conditional ⊸ to be the basic connectives instead of times and linear negation ()^⊥ as in Girard's approach. This difference enables us to obtain a very large subsystem of linear logic (called positive linear logic) without an involutionary negation (if the law of double negation is removed from linear logic in Girard's formulation, the resulting subsystem is extremely limited). Our approach enables us to obtain several natural models for various subsystems of linear logic, including a generic model for the so-called minimal linear logic. In particular, it is seen that these models arise spontaneously in the transition from set theory to multiset theory. We also construct a model of full (nonmodal) linear logic that is generic relative to any model of positive linear logic. However, the problem of constructing a generic model for positive linear logic remains open. Bibliography: 2 titles. Published inZapiski Nauchnykh Seminarov POMI, Vol. 220, 1995, pp. 23–35. Original     

A projective criterion to the coordinate partitioning method for multibody dynamics

Summary The paper discusses some developments in the coordinate partitioning method for the dynamic analysis of constrained/closed-loop multibody systems. First, the method is reformulated to a more compact form. Then, a simple and reliable projective criterion for choosing the best coordinates from the redundant ones is proposed, and some advantages are pointed out that may arise in the method by applying inverse kinematics algorithms. Finally, the problem of determination ofphysical reactions of constraints and closing conditions is discussed. A four-bar linkage mechanism serves for an illustration of some aspects of the paper.

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Ein Projektionskriterium zur Koordinatenwahl bei Mehrkörpersystemen mit kinematischen Schleifen

Übersicht Bei der Simulation der Bewegunsgleichungen von Mehrkörpersystemen mit kinematischen Schleifen in Minimalform stellt sich die Frage nach der Wahl günstiger verallgemeinerter Koordinaten. Hierfür wird ein Projektionskriterium vorgeschlagen, welches die Trennung der systembeschreibenden redundanten Koordinaten in die verallgemeinerten und davon abhängige Koordinaten gestattet. Durch Anwendung eines Verfahrens zur Rückwärtstransformation der kinematischen Beschreibung lassen sich in diesen explizite Schließbedingungen formulieren, was sich bei der Simulation vorteilhaft auswirkt; diese kann ohne Verletzung der Schließbedingungen erfolgen. Es wird auch gezeigt, wie auch bei Verwendung verallgemeinerter Koordinatenphysikalisch interpretierbare Reaktionen ermittelt werden können. Als Anwendungsbeispiel dient ein ebenes Viergelenk.

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On leave from the Department of Mechanics, Technical University of Radom, ul. Malczewskiego 29, 26-600 Radom, Poland     

Intercalated smectic-A structures in a new class of laterally branched substances

X-ray, DSC and optical studies of a new class of substances with aromatic rings in the lateral branches are reported. The thermal behaviour of the substances is discussed. The X-ray measurements lead to a structural model of the SA phases consisting of layer structures with intercalating molecules.     

Raman spectroscopy of carbon fibres

Investigations of coated carbon fibres are reported using Raman spectroscopy. Relationships between different process parameters (for example precursor concentration, reactor temperature and various precursors) and the resulting types of carbon fibres are discussed.     

Structural changes in discotic samples during transition from crystal to discotic mesophase as revealed by electron microscopy and diffraction

Classical methods of structural analysis cannot be applied to liquid crystals because higher order reflections disappear during the transition from crystal to liquid crystal due to the reduction in long range orientational and translational correlations. However, in order to relate physical properties to the molecular architecture, it is essential to have information about molecular positions and orientations in the crystalline state as well as in the liquid crystalline state. In this work, the transition from crystalline to liquid crystalline phase is carefully monitored and the relationship between the original lattice and the new molecular positions found using electron diffraction. In addition to this, a new high resolution electron-microscopic technique is described in which the positions of molecules in the crystalline and the quenched discotic phase are directly imaged and the defects observed in the crystalline and LC phase compared and quantitatively analysed.     

Dibutyltin-3-hydroxyflavone titrates a dissociable component (cofactor) of mitochondrial ATP synthase: An energy-transfer component linked to the ubiquinone pool

Dibutyltin-3-hydroxyflavone, Bu₂Sn(of), is a new fluorescence probe inhibitor of F₁F₀-ATPase and oxidative phosphorylation which inhibits by titration of an unidentified component of F₀. Its site of action is closely related to that of the trialkyltins and of venturicidin. This F₀ component is part of a pool of this component which is present in the heart mitochondrial inner membrane at levels of 5–7 nmol (mg protein)^?1 [18 ± 3 Bu₂Sn(of) sites per mol F₁F₀-ATPase]. However, ATPase activity in submitochondrial particles is near maximally inhibited by titration of approx. three Bu₂Sn(of) sites per mol F₁F₀-ATPase. Over 60% (60–80%) of the Bu₂Sn(of) interaction sites can be lost during the purification of F₁F₀-ATPase from submitochondrial particles. The number of Bu₂Sn(of) interaction sites in various F₁F₀-ATPase preparations is variable. The high numbers of Bu₂Sn(of) sites per mol F₁F₀-ATPase for heart mitochondria (18–21) and submitochondrial particles (15–19.5) decline in ATP synthase (11–15) to the low values obtained in Complex V (7–10.5) and the minimal values observed in highly purified F₁F₀?ATPase (3.5–5.6), thus indicating a variable dissociable component or cofactor of ATP synthase. The Bu₂Sn(of) interaction site, a component of ATP synthase, is responsive to the redox status of the respiratory chain and the interaction with Bu₂Sn(of) is with the reduced form of this component. Fluorescence titration studies show that this component is in redox equilibrium with the ubiquinone pool of the respiratory chain. It is proposed that this redox component serves as an inhibitor titratable cofactor pool which cycles through an F₀ interaction site (or sites) via a system which serves as an energy-transfer link between the respiratory chain and ATP synthase.