Classical, phenomenological analysis of the kinetics of reactions at the gas-exposed surface of mixed ionic electronic conductors

The kinetics of reactions occurring at the gas-exposed surfaces of charged mixed ionic electronic conductors (MIECs) are examined from theoretical first principles. Analysis based on the classical electrochemical potential-transition state theory model reveals that the nature of the reactions is electrochemical in general. However, the influence of the surface potential on the reaction rate is opposite for adsorption and incorporation reactions. Two-dimensional finite volume models of an MIEC as working electrode in a half-cell configuration are presented. The results for a simple, two-step reduction process show that the effect of the surface potential on the rate of reactions is minimal for incorporation-limited reactions but more influential for adsorption-limited reactions. An erratum to this article is available at .     

Nonvanishing cohomology and classes of Gorenstein rings

We give counterexamples to the following conjecture of Auslander: given a finitely generated module M over an Artin algebra Λ, there exists a positive integer n_M such that for all finitely generated Λ-modules N, if Ext_Λⁱ(M,N)=0 for all i?0, then Ext_Λⁱ(M,N)=0 for all i?n_M. Some of our examples moreover yield homologically defined classes of commutative local rings strictly between the class of local complete intersections and the class of local Gorenstein rings.     

Effect of diffraction on the electrodynamic characteristics of two-dimensional coaxial Bragg resonators

The electrodynamic properties of coaxial two-dimensional Bragg resonators with two-dimensional distributed feedback are analyzed. These resonators are made of coaxial waveguide sections with doubly periodic corrugation, which provides coupling and mutual scattering of four partial waves. Two of them propagate along the waveguide, while the other two propagate in the transverse (azimuthal) direction. It is shown that the high azimuthal index selectivity of two-dimensional Bragg resonators may be related to a qualitative difference in topology of the dispersion characteristics of azimuth-symmetric and asymmetric normal waves propagating in infinite waveguides of such a geometry. For the finite-length systems used as two-dimensional Bragg resonators, the eigenmode spectrum is found for two types of boundary conditions that correspond to the limiting cases of perfectly matched (open) systems and, conversely, of systems closed for the extraction of transverse electromagnetic fluxes. Perimeter-to-length ratios of the resonator at which the Q factor of the fundamental azimuth-symmetric mode is greater than those of the other modes are determined. The applicability domain of the geometrical approach, which was earlier applied to two-dimensional Bragg resonators, is discussed.     

Broadening the scope of 1,2,4-triazine synthesis by the application of microwave technology

By the application of microwave technology, a general protocol has been developed for the rapid synthesis of diverse 3,5,6-trisubstituted 1,2,4-triazines in excellent yield and purity, including many previously unknown 3-heterocyclic-1,2,4-triazines.     

Vojta's Main Conjecture for blowup surfaces

In this paper, we prove Vojta's Main Conjecture for split blowups of products of certain elliptic curves with themselves. We then deduce from the conjecture bounds on the average number of rational points lying on curves on these surfaces, and expound upon this connection for abelian surfaces and rational surfaces.

     

Parametric multiple sequence alignment and phylogeny construction

Bounds are given on the size of the parameter-space decomposition induced by multiple sequence alignment problems where phylogenetic information may be given or inferred. It is shown that many of the usual formulations of these problems fall within the same integer parametric framework, implying that the number of distinct optima obtained as the parameters are varied across their ranges is polynomially bounded in the length and number of sequences.     

Stark's conjecture over complex cubic number fields

Systematic computation of Stark units over nontotally real base fields is carried out for the first time. Since the information provided by Stark's conjecture is significantly less in this situation than the information provided over totally real base fields, new techniques are required. Precomputing Stark units in relative quadratic extensions (where the conjecture is already known to hold) and coupling this information with the Fincke-Pohst algorithm applied to certain quadratic forms leads to a significant reduction in search time for finding Stark units in larger extensions (where the conjecture is still unproven). Stark's conjecture is verified in each case for these Stark units in larger extensions and explicit generating polynomials for abelian extensions over complex cubic base fields, including Hilbert class fields, are obtained from the minimal polynomials of these new Stark units.

     

An optical fibre pH sensor based on dye doped mesostructured silica

This paper describes the synthesis and optical pH sensing properties of a pH indicator dye activated mesostructured silica coated optical fibre. The pH-sensitive dye bromothymol blue was incorporated into the mesostructure sol precursor and thin films/coatings were used for pH-sensing applications without prior removal of the surfactant. The pH sensitivity range and operating wavelength were analysed by absorption measurements on layer dip-coated on glass slides. The pH sensing properties of coated optical fibre were tested by evanescent wave method. Experiments were carried out by using a series of solutions of known pH. No leaching was observed (except at very high pH) and an excellent reversibility was obtained between pH=2 and 5.     

An experimental investigation of Curle's theory of aerodynamic noise generation by a stationary body in a turbulent air stream

Bies et al. (J. Sound Vib. 204(4) (1997) 631) investigated Curle's theory (Proc. R. Soc. Ser. A 231 (1955) 505) published in 1955 over a wide range of flow speeds from about 50-200 m/s and found only partial agreement with the experimental data. Here the experimental investigation has been repeated allowing the data to be recorded in a format amenable to analysis, which was not previously possible.Reintroduction of a term neglected by Curle has been found necessary as Curle's compact source condition ensures so low a radiation impedance that the effect cannot be detected in the jet background noise. The reintroduction of the term, which has been neglected, allows his analysis to include radiation from sources not compact but less than half a wavelength in characteristic dimension. It is shown that the power ratio defined as the measured sound power divided by Curle's amended prediction converges to about 3 whereas Curle predicts that the power ratio should converge to 1 as the wave number converges to zero. The introduction of the empirically determined constant 3 into Curle's prediction brings the measurements into very good agreement with prediction over the entire range of the non-dimensional wave numbers from about 0.4 to 3.2.     

Optimized Pump Power Ratio on 2nd Order Pumping Discrete Raman Amplifier

By optimizing pump power ratio between 1st order backward pump and 2nd order forward pump on discrete Raman amplifier, we demonstrated over 2dB noise figure improvement without excessive non-linearity degradation.