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101.
David S. McGuinness Edward L. Marshall Vernon C. Gibson Jonathan W. Steed 《Journal of polymer science. Part A, Polymer chemistry》2003,41(23):3798-3803
Hetero‐bimetallic Fe(II) alkoxide/aryloxides were evaluated as initiators for the ring‐opening polymerization of rac‐lactide. [(THF)NaFe(OtBu)3]2 ( 1 ) and [(THF)4Na2Fe(2,6‐diisopropylphenolate)4] ( 2 ) (THF = tetrahydrofuran) both polymerized lactide efficiently at room temperature, with complex 1 affording better control over the molecular weight parameters of the resultant polymer. At conversions below 70%, a linear increase in molecular weight with conversion was observed, indicative of a well‐controlled polymerization process. Complex 2 is the first example of a dianionic Fe(II) alkoxide and has been structurally characterized to reveal a distorted square planar FeO4 array in which both Na counterions bridge two aryloxide ligands and are further complexed by two THF ligands. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 3798–3803, 2003 相似文献
102.
We consider the differential operators Ψ
k
, defined by Ψ1(y) =y and Ψ
k+1(y)=yΨ
k
y+d/dz(Ψ
k
(y)) fork ∈ ℕ fork∈ ℕ. We show that ifF is meromorphic in ℂ and Ψ
k
F has no zeros for somek≥3, and if the residues at the simple poles ofF are not positive integers, thenF has the formF(z)=((k-1)z+a)/(z
2+β
z+γ) orF(z)=1/(az+β) where α, β, γ ∈ ℂ. If the residues at the simple poles ofF are bounded away from zero, then this also holds fork=2. We further show that, under suitable additional conditions, a family of meromorphic functionsF is normal if each Ψ
k
(F) has no zeros. These conditions are satisfied, in particular, if there exists δ>0 such that Re (Res(F, a)) <−δ for all polea of eachF in the family. Using the fact that Ψ
k
(f
′/f) =f
(k)/f, we deduce in particular that iff andf
(k) have no zeros for allf in some familyF of meromorphic functions, wherek≥2, then {f
′/f :f ∈F} is normal.
The first author is supported by the German-Israeli Foundation for Scientific Research and Development G.I.F., G-643-117.6/1999,
and INTAS-99-00089. The second author thanks the DAAD for supporting a visit to Kiel in June–July 2002. Both authors thank
Günter Frank for helpful discussions. 相似文献
103.
For ϕ a δ-subharmonic function, sharp results are obtained that connectA(r, ϕ), B(r, ϕ) andT(r, ϕ), whereA(r, ϕ)=inf|z|=r
ϕ(z),B(r, ϕ)=sup|z|=r
ϕ(z), andT(r, ϕ) is the Nevanlinna characteristics. 相似文献
104.
Lihong Wang 《Annals of the Institute of Statistical Mathematics》2004,56(2):251-264
The purpose of this paper is to investigate the asymptotic properties of the least squares estimates (L
2-estimates) and the least absolute deviation estimates (L
1-estimates) of the parameters of a nonlinear regression model subject to a set of equality and inequality restrictions, which
has a long-range dependent stationary process as its stochastic errors. Then we will compare the asymptotic relative efficiencies
of the above estimators. 相似文献
105.
106.
107.
108.
The vibrational dynamics of protein folding is analyzed in the framework of Tsallis statistics. We employ exact expressions
for classical harmonic oscillators by considering the unnormalized constraints. As q→1, we show that these approximations agree with the result of Gaussian network model. 相似文献
109.
Vinod Kumar Pragya Das R.P. Singh S. Muralithar R.K. Bhowmik 《The European Physical Journal A - Hadrons and Nuclei》2003,17(2):153-157
The fusion evaporation reaction 122Sn(14N, 4n)132La was used to populate the high-spin states of 132La at the beam energy of 60 MeV. A new band consisting of mostly E2 transitions has been discovered. This band has the interesting links to the ground state 2- and the isomeric state 6-. A new transition of energy 351 keV connecting the low-spin states of the positive-parity band based on the πh
11/2 ⊗ νh
11/2 particle configuration, has been found. This has played a very important role in resolving the existing ambiguities and inconsistencies
in the spin assignment of the band head.
Received: 12 August 2002 / Accepted: 18 March 2003 / Published online: 7 May 2003 相似文献
110.
The results of a numerical study are described in which the interactions of a primary shock wave with a secondary diaphragm
in expansion tubes are taken into account. The developing wave pattern in the interacting process of the shock with a secondary
diaphragm are visualized by many kinds of figures (e.g., the time-distance diagrams of the wave phenomena on the axis, the
acoustic impedance contours, and the time histories of the pitot pressure on the axis), and the influences of the shape and
rupture process of the diaphragm on the quality of the test gas are explored. 相似文献