全文获取类型
收费全文 | 900篇 |
免费 | 30篇 |
国内免费 | 2篇 |
专业分类
化学 | 589篇 |
晶体学 | 1篇 |
力学 | 25篇 |
数学 | 143篇 |
物理学 | 174篇 |
出版年
2024年 | 3篇 |
2023年 | 13篇 |
2022年 | 25篇 |
2021年 | 39篇 |
2020年 | 19篇 |
2019年 | 21篇 |
2018年 | 16篇 |
2017年 | 14篇 |
2016年 | 34篇 |
2015年 | 30篇 |
2014年 | 32篇 |
2013年 | 53篇 |
2012年 | 59篇 |
2011年 | 74篇 |
2010年 | 34篇 |
2009年 | 33篇 |
2008年 | 45篇 |
2007年 | 46篇 |
2006年 | 42篇 |
2005年 | 55篇 |
2004年 | 40篇 |
2003年 | 27篇 |
2002年 | 21篇 |
2001年 | 11篇 |
2000年 | 12篇 |
1999年 | 13篇 |
1998年 | 6篇 |
1997年 | 10篇 |
1996年 | 14篇 |
1995年 | 4篇 |
1994年 | 2篇 |
1993年 | 6篇 |
1992年 | 2篇 |
1991年 | 5篇 |
1990年 | 2篇 |
1988年 | 8篇 |
1987年 | 5篇 |
1986年 | 2篇 |
1985年 | 5篇 |
1984年 | 8篇 |
1983年 | 4篇 |
1982年 | 4篇 |
1981年 | 3篇 |
1980年 | 5篇 |
1978年 | 3篇 |
1977年 | 2篇 |
1974年 | 4篇 |
1960年 | 2篇 |
1897年 | 1篇 |
1887年 | 1篇 |
排序方式: 共有932条查询结果,搜索用时 15 毫秒
61.
V. Mattoli V. Pensabene T. Fujie S. Taccola A. Menciassi S. Takeoka P. Dario 《Procedia Chemistry》2009,1(1):28-31
Polymeric ultra-thin films, so called nanosheets, show peculiar properties making them potentially useful for several applications in biomedicine. Moreover, the possibility to functionalize these films by using different agents opens new and partially unexplored scenarios, including micro/nano sensing and actuation. This paper compares two different methods for the preparation of free-standing nanosheets, loaded with magnetic particles for no-contact manipulation in liquid environment. Morphology and functionalities of the two types of nanosheets have been characterized and compared. These magnetic nanosheets could find applications as free-standing carriers to be released and controlled in endoluminal surgery or as plasters with nanometric thickness to be delivered in situ on surgical incisions. 相似文献
62.
63.
64.
This paper describes a coupling framework for parallel execution of different solvers for multi-physics and multi-domain simulations with an arbitrary number of adjacent zones connected by different physical or overlapping interfaces. The coupling architecture is based on the execution of several instances of the same coupling code and relies on the use of smart edges (i.e., separate processes) dedicated to managing the exchange of information between two adjacent regions. The collection of solvers and coupling sessions forms a flexible and modular system, where the data exchange is handled by independent servers that are dedicated to a single interface connecting two solvers’ sessions. Accuracy and performance of the strategy is considered for turbomachinery applications involving Conjugate Heat Transfer (CHT) analysis and Sliding Plane (SP) interfaces. 相似文献
65.
Dario Delgado Manickam Minakshi Dong-Jin Kim Chung Kyeong W 《Analytical letters》2017,50(15):2386-2401
The influence of oxides in the hydrogen evolution on Raney nickel electrocatalysts was characterized by electrochemical impedance measurements. In addition, these materials show competitive overpotentials for hydrogen evolution with a modified Watts bath as a binder for the Raney nickel. The optimum result was ?190?mV of overpotential at 100?mA?cm?2. Oxygen in the Raney Ni catalyst affects its electroactivity toward hydrogen evolution. The source of oxygen is related to the presence of chloride ions in the modified Watts bath. A Watts bath binds Raney Ni particles to the surface of the catalysts and chloride regulates the oxygen content in the nickel binder during electrodeposition. High oxygen content increases the hydrogen evolution overpotential of the electrode. The electroactivity of the synthesized porous coatings was evaluated by polarization curves and impedance plots. In addition, surface characterization by X-ray diffraction, field emission–scanning electron microscopy equipped with energy-dispersive analysis, and X-ray photoelectron spectroscopy is reported. 相似文献
66.
Eliete Marçal Guimarães Raso Maria Esperanza Cortes Karina Imaculada Teixeira Milton Batista Franco Nelcy Della Santina Mohallem Ruben Dario Sinisterra 《Journal of inclusion phenomena and macrocyclic chemistry》2010,67(1-2):159-168
The purpose of this study was to prepare and characterize a controlled release system based on porous silica loaded with chlorhexidine (Cx) and its inclusion compounds in β-cyclodextrin (βcd), and to evaluate its antimicrobial activity. Acetate chlorhexidine (CxA), gluconate chlorhexidine (CxG), βcd:chlorhexidine acetate 2:1 (βcd:CxA) and βcd:chlorhexidine gluconate 2:1 (βcd:CxG) were incorporated into porous silica. Drug loading was characterized by FTIR, powder X-ray diffraction, thermal analysis and BET, and was shown to be in an amorphous state and porous matrix. The kinetics release parameter of the drug was established, which showed that the Cx systems release profile followed zero order release until 400 h and Higuchi model release until 750 h, after the burst effect at the first 8 h. Chlorhexidine therapeutic range was reached near first hour for all systems. The chlorhexidine porous silica system was biologically active against Enterococcus faecalis and Candida albicans in vitro. The systems showed an efficient Cx controlled release modulated by the presence of the β-cyclodextrin and by the porous silica matrices, providing effective antimicrobial activity. 相似文献
67.
Silvia Tavazzi Dr. Leonardo Silvestri Dr. Luciano Miozzo Dr. Antonio Papagni Prof. Peter Spearman Dr. Sandra Ianelli Dr. Alberto Girlando Prof. Andrea Camposeo Dr. Marco Polo Dr. Dario Pisignano Dr. 《Chemphyschem》2010,11(2):429-434
Blue amplified spontaneous emission at room temperature is demonstrated from the exposed face of the strongly emitting organic semiconductor 1,1,4,4‐tetraphenyl‐1,3‐butadiene in single crystal form. The symmetry of the crystal and calculation of lattice sums indicate the J‐type organization of the molecular transition moments. The minimum in the lowest exciton dispersion branch, from which emission takes place, is found at the edge of the Brillouin zone leading to a dominant vibronic emission since the zero‐phonon line is forbidden. The observed gain narrowed line is attributed to the vibronic replica which becomes amplified with increased pumping. The reported emission is along the normal to the exposed crystal face, important for the development of vertical cavity geometry lasers based on organic single crystals. The threshold excitation fluence of 400 μJ cm?2 is comparable to other organic crystalline systems, even if the amplification path is much reduced as a consequence of the vertical geometry. Considering these relevant aspects, the optical characterization of this material is provided. The polarized absorption spectra are reported and the properties of the lowest‐energy excitonic state investigated. Calculation of the electronic transitions for the isolated molecule, lattice sums for the transition at lowest energy, and the symmetry of the crystal allow attributing the largest face of the samples and the observed optical bands in the spectra. Polarized time‐resolved spectra are also reported allowing to identify the intrinsic excitonic emission. 相似文献
68.
By using ab initio molecular dynamics calculations, we show that even where the graphene lattice constant contracts, as previously reported for freestanding graphene below room temperature, the average carbon-carbon distance increases with temperature, in both free and supported graphene. This results in a larger corrugation at higher temperature, which can affect the interaction between graphene and the supporting substrate. For a weakly interacting system as graphene/Ir(111), we confirm the results using an experimental approach which gives direct access to interatomic distances. 相似文献
69.
Danilo Babusci Giuseppe Dattoli Dario Sacchetti 《Central European Journal of Physics》2011,9(6):1381-1386
The Airy transform is an ideally suited tool to treat problems in classical and quantum optics. Even though the relevant mathematical
aspects have been thoroughly investigated, the possibilities it offers are wide and some features, such as the link with special
functions and polynomials, still contain unexplored aspects. In this note we will show that the so called Airy polynomials
are essentially the third order Hermite polynomials. We will also prove that this identification opens the possibility of
developing new conjectures on the properties of this family of polynomials. 相似文献
70.
Ademir Aparecido Constantino Dario Landa-Silva Everton Luiz de Melo Candido Ferreira Xavier de Mendonça Douglas Baroni Rizzato Wesley Romão 《Annals of Operations Research》2014,218(1):165-183
This paper tackles a Nurse Scheduling Problem which consists of generating work schedules for a set of nurses while considering their shift preferences and other requirements. The objective is to maximize the satisfaction of nurses’ preferences and minimize the violation of soft constraints. This paper presents a new deterministic heuristic algorithm, called MAPA (multi-assignment problem-based algorithm), which is based on successive resolutions of the assignment problem. The algorithm has two phases: a constructive phase and an improvement phase. The constructive phase builds a full schedule by solving successive assignment problems, one for each day in the planning period. The improvement phase uses a couple of procedures that re-solve assignment problems to produce a better schedule. Given the deterministic nature of this algorithm, the same schedule is obtained each time that the algorithm is applied to the same problem instance. The performance of MAPA is benchmarked against published results for almost 250,000 instances from the NSPLib dataset. In most cases, particularly on large instances of the problem, the results produced by MAPA are better when compared to best-known solutions from the literature. The experiments reported here also show that the MAPA algorithm finds more feasible solutions compared with other algorithms in the literature, which suggest that this proposed approach is effective and robust. 相似文献