全文获取类型
收费全文 | 1190篇 |
免费 | 48篇 |
国内免费 | 7篇 |
专业分类
化学 | 787篇 |
晶体学 | 2篇 |
力学 | 36篇 |
数学 | 220篇 |
物理学 | 200篇 |
出版年
2024年 | 3篇 |
2023年 | 14篇 |
2022年 | 23篇 |
2021年 | 45篇 |
2020年 | 20篇 |
2019年 | 28篇 |
2018年 | 19篇 |
2017年 | 21篇 |
2016年 | 43篇 |
2015年 | 31篇 |
2014年 | 45篇 |
2013年 | 64篇 |
2012年 | 85篇 |
2011年 | 93篇 |
2010年 | 49篇 |
2009年 | 44篇 |
2008年 | 64篇 |
2007年 | 65篇 |
2006年 | 60篇 |
2005年 | 73篇 |
2004年 | 56篇 |
2003年 | 50篇 |
2002年 | 31篇 |
2001年 | 20篇 |
2000年 | 19篇 |
1999年 | 16篇 |
1998年 | 8篇 |
1997年 | 11篇 |
1996年 | 18篇 |
1995年 | 5篇 |
1994年 | 2篇 |
1993年 | 9篇 |
1992年 | 4篇 |
1991年 | 8篇 |
1990年 | 4篇 |
1989年 | 3篇 |
1988年 | 7篇 |
1987年 | 4篇 |
1985年 | 12篇 |
1984年 | 7篇 |
1983年 | 10篇 |
1982年 | 6篇 |
1981年 | 2篇 |
1980年 | 10篇 |
1978年 | 7篇 |
1977年 | 2篇 |
1975年 | 2篇 |
1974年 | 6篇 |
1960年 | 2篇 |
1887年 | 1篇 |
排序方式: 共有1245条查询结果,搜索用时 15 毫秒
81.
Braga D Maini L de Sanctis G Rubini K Grepioni F Chierotti MR Gobetto R 《Chemistry (Weinheim an der Bergstrasse, Germany)》2003,9(22):5538-5548
Mechanical mixing of solid dicarboxylic acids of variable chain length HOOC(CH(2))(n)COOH (n = 1-7) with solid 1,4-diazabicyclo[2.2.2]octane generates the corresponding salts or co-crystals of the formula [N(CH(2)CH(2))(3)N]-H-[OOC(CH(2))(n)COOH] (n=1-7). Preparation of the same systems from solution has been instrumental for a full characterization of the mechanochemical products by means of single-crystal and powder-diffraction X-ray analyses, as well as by solid-state NMR. The acid-base adducts, whether involving proton transfer from the COOH group to the N-acceptor, that is having ((-))O...H-N((+)) interactions, or the formation of neutral O-H...N hydrogen bonds, show a melting point alternation phenomenon analogous to that shown by the neutral carboxylic acids. The carbon chemical shift tensors of the COOH group obtained from the sideband intensity of low speed spinning NMR spectra provide a reliable criterion for assigning the protonation state of the adducts. 相似文献
82.
A theozyme for antibody aldolases has been studied at the MP2/6-31G** computational level. Formation of two cooperative hydrogen-bonds between the acidic hydrogen atoms of the enamine and of a methanol molecule with the oxygen atom of the aldol acceptor markedly favors the C-C bond-formation associated with the aldol reaction. A comparative analysis of the geometry, the charge distribution and the shape of the molecular electrostatic potential of the transition structure (TS) with the covalent adduct, resulting from the reaction of methylamine and the beta-diketone used as a hapten allows us to characterize the transition-state analogue (TSA) generated at immunization. This finding allows us to propose a hapten based on a chiral beta-ketosulfoxide that could give the formation of a TSA that addresses the tetrahedral geometry of the TS. 相似文献
83.
84.
Dario Pierotti 《Journal of Differential Equations》2008,244(9):2350-2371
We consider the problem of the steady flow of an ideal heavy fluid around a submerged beam. The problem is obtained from the free-boundary problem of the flow past a submerged obstacle in the limit of bodies of vanishing thickness. We introduce a special Sobolev space formulation of the problem in term of a perturbed stream function and prove its unique solvability for every value of the unperturbed flow velocity, with the possible exception of a discrete set depending on the geometry of the domain. The asymptotic properties of the solutions are discussed. 相似文献
85.
María D. Acosta Richard M. Aron Domingo García Manuel Maestre 《Journal of Functional Analysis》2008,254(11):2780-2799
We prove the Bishop-Phelps-Bollobás theorem for operators from an arbitrary Banach space X into a Banach space Y whenever the range space has property β of Lindenstrauss. We also characterize those Banach spaces Y for which the Bishop-Phelps-Bollobás theorem holds for operators from ?1 into Y. Several examples of classes of such spaces are provided. For instance, the Bishop-Phelps-Bollobás theorem holds when the range space is finite-dimensional, an L1(μ)-space for a σ-finite measure μ, a C(K)-space for a compact Hausdorff space K, or a uniformly convex Banach space. 相似文献
86.
87.
V. Mattoli V. Pensabene T. Fujie S. Taccola A. Menciassi S. Takeoka P. Dario 《Procedia Chemistry》2009,1(1):28-31
Polymeric ultra-thin films, so called nanosheets, show peculiar properties making them potentially useful for several applications in biomedicine. Moreover, the possibility to functionalize these films by using different agents opens new and partially unexplored scenarios, including micro/nano sensing and actuation. This paper compares two different methods for the preparation of free-standing nanosheets, loaded with magnetic particles for no-contact manipulation in liquid environment. Morphology and functionalities of the two types of nanosheets have been characterized and compared. These magnetic nanosheets could find applications as free-standing carriers to be released and controlled in endoluminal surgery or as plasters with nanometric thickness to be delivered in situ on surgical incisions. 相似文献
88.
89.
90.
This paper describes a coupling framework for parallel execution of different solvers for multi-physics and multi-domain simulations with an arbitrary number of adjacent zones connected by different physical or overlapping interfaces. The coupling architecture is based on the execution of several instances of the same coupling code and relies on the use of smart edges (i.e., separate processes) dedicated to managing the exchange of information between two adjacent regions. The collection of solvers and coupling sessions forms a flexible and modular system, where the data exchange is handled by independent servers that are dedicated to a single interface connecting two solvers’ sessions. Accuracy and performance of the strategy is considered for turbomachinery applications involving Conjugate Heat Transfer (CHT) analysis and Sliding Plane (SP) interfaces. 相似文献