全文获取类型
收费全文 | 1202篇 |
免费 | 41篇 |
国内免费 | 7篇 |
专业分类
化学 | 791篇 |
晶体学 | 2篇 |
力学 | 36篇 |
数学 | 220篇 |
物理学 | 201篇 |
出版年
2024年 | 3篇 |
2023年 | 15篇 |
2022年 | 27篇 |
2021年 | 45篇 |
2020年 | 20篇 |
2019年 | 28篇 |
2018年 | 19篇 |
2017年 | 21篇 |
2016年 | 43篇 |
2015年 | 31篇 |
2014年 | 45篇 |
2013年 | 64篇 |
2012年 | 85篇 |
2011年 | 93篇 |
2010年 | 49篇 |
2009年 | 44篇 |
2008年 | 64篇 |
2007年 | 65篇 |
2006年 | 60篇 |
2005年 | 73篇 |
2004年 | 56篇 |
2003年 | 50篇 |
2002年 | 31篇 |
2001年 | 20篇 |
2000年 | 19篇 |
1999年 | 16篇 |
1998年 | 8篇 |
1997年 | 11篇 |
1996年 | 18篇 |
1995年 | 5篇 |
1994年 | 2篇 |
1993年 | 9篇 |
1992年 | 4篇 |
1991年 | 8篇 |
1990年 | 4篇 |
1989年 | 3篇 |
1988年 | 7篇 |
1987年 | 4篇 |
1985年 | 12篇 |
1984年 | 7篇 |
1983年 | 10篇 |
1982年 | 6篇 |
1981年 | 2篇 |
1980年 | 10篇 |
1978年 | 7篇 |
1977年 | 2篇 |
1975年 | 2篇 |
1974年 | 6篇 |
1960年 | 2篇 |
1887年 | 1篇 |
排序方式: 共有1250条查询结果,搜索用时 0 毫秒
31.
Imidazolium-based ionic liquids (ILs) containing ester moieties in the side chain were successfully used as an alternative to traditional ILs in the Beckmann rearrangement of ketoximes catalyzed by 2,4,6-trichloro[1,3,5]triazine. The procedure is mild and suitable for both aromatic and cycloaliphatic substrates affording the rearrangement products in good to quantitative yields. The process is eco-sustainable since these ILs are biodegradable and in addition they can be recovered and reused. 相似文献
32.
33.
34.
Tarek Benameur Giulia Giacomucci Maria Antonietta Panaro Melania Ruggiero Teresa Trotta Vincenzo Monda Ilaria Pizzolorusso Dario Domenico Lofrumento Chiara Porro Giovanni Messina 《Molecules (Basel, Switzerland)》2022,27(1)
Curcumin, the dietary polyphenol isolated from Curcuma longa (turmeric), is commonly used as an herb and spice worldwide. Because of its bio-pharmacological effects curcumin is also called “spice of life”, in fact it is recognized that curcumin possesses important proprieties such as anti-oxidant, anti-inflammatory, anti-microbial, antiproliferative, anti-tumoral, and anti-aging. Neurodegenerative diseases such as Alzheimer’s Diseases, Parkinson’s Diseases, and Multiple Sclerosis are a group of diseases characterized by a progressive loss of brain structure and function due to neuronal death; at present there is no effective treatment to cure these diseases. The protective effect of curcumin against some neurodegenerative diseases has been proven by in vivo and in vitro studies. The current review highlights the latest findings on the neuroprotective effects of curcumin, its bioavailability, its mechanism of action and its possible application for the prevention or treatment of neurodegenerative disorders. 相似文献
35.
36.
Dr. Philipp Holtkamp Dario Poier Beate Neumann Dr. Hans-Georg Stammler Prof. Dr. Norbert W. Mitzel 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(11):3793-3798
The reactivity of the geminal frustrated Lewis pair (FLP) (F5C2)3SnCH2P(tBu)2 ( 1 ) was explored by reacting it with a variety of small molecules (PhOCN, PhNCS, PhCCH, tBuCCH, H3CC(O)CH=CH2, Ph[C(O)]2Ph, PhN=NPh and Me3SiCHN2), featuring polar or non-polar multiple bonds and/or represent α,β-unsaturated systems. While most adducts are formed readily, the binding of azobenzene requires UV-induced photoisomerization, which results in the highly selective complexation of cis-azobenzene. In the case of benzil, the reaction does not lead to the expected 1,2- or 1,4-addition products, but to the non-stereoselective (tBu)2PCH2-transfer to a prochiral keto function of benzil. All adducts of 1 were characterised by means of multinuclear NMR spectroscopy, elemental analyses and X-ray diffraction experiments. 相似文献
37.
38.
Francesca Goldoni Dario Iarossi Adele Mucci Luisa Schenetti 《Journal of heterocyclic chemistry》1997,34(6):1801-1804
3,4′-Dibromo-2,2′-bithiophene was converted, in high yield, into the corresponding dibutoxy derivative. The 1H 13C and nmr data are discussed in comparison with those of 3,3′- and 4,4′-dibutoxy-2,2′-bithiophene in relation to regiochemistry. 相似文献
39.
Dounia Elfadil Abderrahman Lamaoui Flavio Della Pelle Aziz Amine Dario Compagnone 《Molecules (Basel, Switzerland)》2021,26(15)
Detection of relevant contaminants using screening approaches is a key issue to ensure food safety and respect for the regulatory limits established. Electrochemical sensors present several advantages such as rapidity; ease of use; possibility of on-site analysis and low cost. The lack of selectivity for electrochemical sensors working in complex samples as food may be overcome by coupling them with molecularly imprinted polymers (MIPs). MIPs are synthetic materials that mimic biological receptors and are produced by the polymerization of functional monomers in presence of a target analyte. This paper critically reviews and discusses the recent progress in MIP-based electrochemical sensors for food safety. A brief introduction on MIPs and electrochemical sensors is given; followed by a discussion of the recent achievements for various MIPs-based electrochemical sensors for food contaminants analysis. Both electropolymerization and chemical synthesis of MIP-based electrochemical sensing are discussed as well as the relevant applications of MIPs used in sample preparation and then coupled to electrochemical analysis. Future perspectives and challenges have been eventually given. 相似文献
40.
Tedesco E Della F Favaretto L Barbarella G Albesa-Jové D Pisignano D Gigli G Cingolani R Harris KD 《Journal of the American Chemical Society》2003,125(40):12277-12283
The "rigid-core" material 3,5-dimethyl-2,3'-bis(3-methylthiophene)-dithieno[3,2-b:',3'-d]thiophene-4,4-dioxide (DTTOMe4) has the highest photoluminescence ever reported for thiophene-based molecules in the solid state. We report the structure of this material, determined directly from powder X-ray diffraction data using the Genetic Algorithm method for structure solution, followed by Rietveld refinement, and the structural properties are discussed in relation to the structures of the corresponding subsystems DTTO and DTTOMe. While the crystal structures of the latter compounds contain cofacial dimers, the crystal structure of DTTOMe4 comprises layers of molecules aligned in an antiparallel fashion. Intermediate neglect of differential overlap with single configuration interaction (INDO/SCI) calculations on the intermolecular interactions in the three crystal structures show that the different solid-state photoluminescence efficiencies of DTTOMe4, DTTOMe, and DTTO cannot be correlated with the different types of dipole-dipole alignment in the solid state. Instead, photoluminescence efficiencies correlate well with the rate of formation of nonradiatively decaying charge-transfer pairs upon photoexcitation. Because of larger intermolecular distances in DTTOMe4, the photoluminescence is less effectively quenched by charge-transfer processes than in DTTOMe and DTTO. 相似文献